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排序方式: 共有2239条查询结果,搜索用时 15 毫秒
1.
Since the discovery in 1922 of 2,2-diphenyl-1-(2,4,6-trinitrophenyl) hydrazyl stable free radical (DPPH·), the chemistry of such open-shell compounds has developed continuously, allowing for both theoretical and practical advances in the free radical chemistry area. This review presents the important, general and modern aspects of the chemistry of hydrazyl free radicals and the science behind it.  相似文献   
2.
Lithium‐rich disordered rock‐salt oxides have attracted great interest owing to their promising performance as Li‐ion battery cathodes. While experimental and theoretical efforts are critical in advancing this class of materials, a fundamental understanding of key property changes upon Li extraction is largely missing. In the present study, single‐crystal synthesis of a new disordered rock‐salt cathode material, Li1.3Ta0.3Mn0.4O2 (LTMO), and its use as a model compound to investigate Li concentration–driven evolution of local cationic ordering, charge compensation, and chemical distribution are reported. Through the combined use of 2D and 3D X‐ray nanotomography, it is shown that Li removal accompanied by oxygen oxidation is correlated with the development of morphological defects such as particle cracking. Chemical heterogeneity, quantified by subparticle level distribution of Mn valence state, is minimal during Mn redox, which drastically increases upon the formation of cracks during oxygen redox. Density functional theory and bond valence sum mismatch calculations reveal the presence of local short‐range ordering in the pristine oxide, which gradually disappears along with the extraction of Li. The study suggests that with cycling the transformation into true cation–disordered state can be expected, which likely impacts the voltage profile and obtainable energy density of the oxide cathodes.  相似文献   
3.
Excessive energy intake may evoke complex biochemical processes characterized by inflammation, oxidative stress, and impairment of mitochondrial function that represent the main factors underlying noncommunicable diseases. Because cow milk is widely used for human nutrition and in food industry processing, the nutritional quality of milk is of special interest with respect to human health. In our study, we analyzed milk produced by dairy cows fed a diet characterized by a high forage:concentrate ratio (high forage milk, HFM). In view of the low n-6:n-3 ratio and high content of conjugated linoleic acid of HFM, we studied the effects of this milk on lipid metabolism, inflammation, mitochondrial function, and oxidative stress in a rat model. To this end, we supplemented for 4 wk the diet of male Wistar rats with HFM and with an isocaloric amount (82 kJ, 22 mL/d) of milk obtained from cows fed a diet with low forage:concentrate ratio, and analyzed the metabolic parameters of the animals. Our results indicate that HFM may positively affect lipid metabolism, leptin:adiponectin ratio, inflammation, mitochondrial function, and oxidative stress, providing the first evidence of the beneficial effects of HFM on rat metabolism.  相似文献   
4.
介绍了目前国内外引发剂的使用及开发方向,并对引发剂的选择及其对树脂质量的影响进行了讨论。  相似文献   
5.
高分子量丙烯酰胺-DAC共聚物的研制   总被引:7,自引:0,他引:7  
采用复合引发体系 ,以丙烯酰胺 (AM)和阳离子单体丙烯酰氧乙基三甲基氯化铵(DAC)为共聚体 ,进行水溶液绝热聚合 ,研制了一种DAC单体含量为 4 0 %~ 5 0 %、相对分子质量大于 1× 10 7的阳离子型聚丙烯酰胺。  相似文献   
6.
通过元素分析、红外光谱分析、光电子能谱分析以及扫描电子显微镜分析等手段,证实含正丙胺基吸附剂与Au3+的氧化还原反应过程中,氮原子邻近的羟基碳或C-H键被氧化,而氮原子并未参与氧化还原反应;吸附态Au(3+)最终部分被还原成单质金;在非水介质中吸附在吸附剂上的金聚集成颗粒状。  相似文献   
7.
磷酸盐激光玻璃中铂颗粒密度与氧化还原平衡关系的研究   总被引:1,自引:1,他引:0  
姜淳  卓敦水  张俊洲 《中国激光》1996,23(11):1047-1052
用吸收光谱法研究了R2O—BaO—P2O5系统磷酸盐激光玻璃中铂颗粒密度与铭的氧化还原平衡的关系。结果表明,玻璃中铂颗粒密度随平衡向右移动而减小;玻璃中平衡随熔炼气氛中氧分压增大、熔炼温度升高而向右移动,当足够大时,铂颗粒不能形成。  相似文献   
8.
介绍了在高压环形反应器上采用连续聚合工艺进行的VAE(醋酸乙烯-乙烯共聚物)乳液新品种的开发。通过在普通型VAE乳液配方基础上调整保护胶体的品种和用量,并采用新型氧化-还原引发体系,生产出高固含(6S%)低粘度的VAE乳液,具有优异的粘接强度和干燥速度。用于包装行业的快速粘接和配制成木材拼板胶,效果优异。  相似文献   
9.
Gas-phase selective oxidation of toluene has been carried out on vanadium oxide systems (5–20 wt.% of V2O5, equivalent to 0.4–1.7 theoretical monolayers) supported on TiO2–sepiolite (with titania loading around the theoretical monolayer, 12 wt.%) and on sepiolite. A study has been made on both the influence of vanadia loading and of the support on the catalytic behaviour of the supported vanadium systems. The reducibility by H2 TPR was also studied as well as the acid and basic/redox sites from the results of conversion of the 2-propanol test reaction of the solids. Benzaldehyde, benzoic acid and several coupling products were the main ones detected, attaining over 50% selectivity towards the benzaldehyde and benzoic acid products at a total conversion around 10%. The activity and selectivity to the selective products exhibited by vanadium systems supported on mixed support were superior to those exhibited by the systems supported on sepiolite and increased notably in both series with the increase in vanadium loading. The best catalytic behaviour exhibited by the vanadium systems supported on mixed support, which also exhibited the highest density of sites capable of being reduced (as well as their reducibility) and of those responsible for propanone formation, could be attributed not only to the different balance of the vanadia species existing in the two supports (monomeric + oligomeric/polymeric), but also to such other factors as the nature of the support and, concretely, its chemical composition.  相似文献   
10.
研究了电爆炸箔起爆系统起爆回路初始电阻对爆发电流和冲击片雷管飞片速度的影响规律,分析了影响电爆炸箔起爆系统体系的因素,为在可靠发火条件下降低起爆系统体积提供设计参考。  相似文献   
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