增韧聚丙烯三元共混体阻燃性能的研究

研究了多种阻燃剂，包括Ｓｂ２Ｏ３、Ａｌ（ＯＨ）３、ＣＰＣ、ＤＢＤＰＯ对聚丙烯／高密度聚乙烯／乙丙橡胶（ＰＰ／ＨＤＰＥ／ＥＰＲ）三元共混体—增韧聚丙烯—阻燃性能的影响；阻燃剂间的协同作用；并探讨了阻燃机理。结果表明：１、ＡＬ（ＯＨ）３的重量含量超过４０％时，阻燃效果显著；２、三种阻燃剂（Ｓｂ２Ｏ３、ＤＢＤＰＯ、ＣＰＥ）并用，阻燃效果明显提高，含卤化合物（ＤＢＤＰＯ与ＣＰＥ）是Ｓｂ２Ｏ３重量的四倍时，阻燃性能最佳；３、Ｓｂ２Ｏ３与ＤＢＤＰＯ并用时，当Ｂｒ／Ｓｂ的摩尔比为３∶１时阻燃效果最好     

缓凝剂对水泥与减水剂相容性的影响及其作为助磨剂组分的试验研究

以水泥净浆流动度为评价指标,试验研究了多种常用缓凝剂对水泥与减水剂相容性的影响,结果表明,多数缓凝剂都能不同程度改善水泥与减水剂的相容性,其中白糖和＂六偏磷酸钠＋葡萄糖酸钠（1∶1）＂的效果最好。选取几种相容性效果较好的缓凝剂作为助磨剂组分之一配制的复合助磨剂,试验表明,3种复合助磨剂均能改善水泥与减水剂的相容性且助磨效果优异,其中0.05%型复合助磨剂还显著提高水泥各龄期抗压强度。     

固硫灰做水泥混合材及缓凝剂的研究

研究固硫灰做水泥混合材及缓凝剂,其细度和掺量对水泥性能的影响.试验结果表明,10％～30％不同细度的固硫灰掺入硅酸盐水泥熟料中后,所制备的水泥安定性合格、凝结时间正常;强度随着细度的增加而增加,随着掺量的增加先增加后降低;磨细处理有利于降低水泥的总膨胀能.同时通过研究发现,固硫灰的掺量和细度对水泥早期水化产物的形成有较大的影响,掺磨细固硫灰水泥所形成的AFt是粗大的针棒状结构,而掺未磨细固硫灰水泥形成细小的AFt和大量的AFm.     

缓凝剂对建筑石膏强度性能影响的试验

利用抗折试验机和抗压试验机对建筑石膏试件进行强度测试试验,系统深入地研究了不同掺入量的缓凝剂对建筑石膏的抗压强度、抗折强度、压折比等强度特性,分析了建筑石膏的抗压强度、抗折强度等与不同掺量的缓凝剂之间的关系。试验结果表明:建筑石膏的抗压强度、抗折强度随着缓凝剂掺量的增加而降低,压折比则相反,它是随着缓凝剂掺量的增加而增加的。     

一种对入射角不敏感的λ/4消色差相位延迟器

通过合理选择光学材料和器件结构角,设计了一种对入射角不敏感的菲涅耳菱体型消色差相位延迟器.它是单元结构λ/4延迟器.计算表明:入射角变化±2.5°时,引起的相位延迟量的偏差约为0.3°,是常规菲涅耳菱体相位延迟器在同等情况下延迟量变化的1/6.     

A comparison of fatigue crack growth performance of two aerospace grade aluminium alloys reinforced with bonded crack retarders

To improve the fail‐safety performance of integral metallic structures, the bonded crack retarder concept has been developed in recent years. This paper presents an experimental investigation on the effectiveness of bonded crack retarder on fatigue crack growth life in two aerospace aluminium alloys: 2624‐T351 and 7085‐T7651. M(T) specimens bonded with a pair of straps made of GLARE fibre‐metal laminate were tested under the constant amplitude load. Although the bonded crack retarders increased the crack growth life in both alloys, the magnitude of life improvement is very different between them. Compared to unreinforced specimens, application of crack retarders has resulted in 90% increase in fatigue life in AA7085, but only 27% increase in AA2624. The significant difference in fatigue life improvement is owing to the material's intrinsic fatigue crack growth rate property, ie, the Paris law constants C and n. Value of n for AA7085 is 1.8 times higher than that for AA2624. Therefore, AA7085 is much more sensitive to reductions in the effective stress intensity factor brought by the crack retarders, hence better life improvement.     

In situ investigation of phosphonate retarder interaction in oil well cements at elevated temperature and pressure conditions

The effect of a high-performance retarding additive in oil well cements was investigated under elevated temperature (165°C) and pressure (1000 psi) conditions via in situ synchrotron-based X-ray diffraction (XRD) and quasielastic neutron scattering (QENS) techniques. Under these temperature and pressure conditions, crystalline calcium silicate hydrates (C–S–H) are formed through the cement hydration process. From in situ XRD experiments, the retardation effect was observed by a change in the rate of the appearance of 11 Å tobermorites as well as a change in the rate of the α-C₂SH generation and depletion. QENS analysis revealed that the retardation effect was related to the non-conversion of free water to chemical and constrained water components. A high presence of free water components was attributed to a decrease in 11 Å tobermorites along with slower consumption of the quartz and portlandite phases. Furthermore, QENS results infer that the water molecules experienced confinement in the restricted pore spaces. The retarder inhibited this initial water confinement by slowing the bulk diffusion of free water in the confined region.     

缓凝剂与高效减水剂对水泥水化性能的影响

系统地研究了葡萄糖酸钠与三种高效减水剂复合对水泥水化性能的影响,结果表明:与空白水泥相比,缓凝剂与高效减水剂无论是单掺还是复合使用,对水泥的水化及其水化产物均有不同程度的影响;缓凝剂与高效减水剂复合后的协同效应与单掺缓凝剂、单掺高效减水剂时温峰出现时间有关.     

Fail-safe design of integral metallic aircraft structures reinforced by bonded crack retarders

This paper presents an investigation on the effectiveness of crack growth retarders bonded to integral metallic structures. The study was performed by both numerical modelling and experimental tests. It focuses on aluminium alloy panels reinforced by bonded straps made of carbon-epoxy, glass-epoxy composite materials or a titanium alloy. The goal was to develop a fail-safe design for integrally stiffened skin-stringer panels applicable to aircraft wing structures. The modelling strategy and finite element models are presented and discussed. The requirements that the models should meet are also discussed. The study has focused on establishing the extent of crack retarder benefits, in terms of fatigue crack growth life improvement, by numerical simulation and experimental tests of various crack retarders. The results of predicted fatigue crack growth retardation have been validated by tests of laboratory samples. This study concludes that by bonding discrete straps to an integral structure, the fatigue crack growth life can be significantly improved.     

Photo‐aligned anisotropic optical thin films

Abstract— Photo‐alignment of anisotropic optical thin films enables realization of novel optical elements, which were not feasible up until now. Photo‐aligned anisotropic thin films can be applied to rigid or flexible substrates, which may be flat or curved. The optical performance of such films can be tailored to application‐specific requirements by introducing tilt profiles of the optical axis and/or generate patterned retarders with continuous or periodical in‐plane variation of the optical axis.