在二(2-乙基己基)磷酸钠的微乳液中金属萃合物对水增溶的影响

测算了由二（2－乙基己基）磷酸钠，金属盐（CoSO4,NiSO4,ZnSO4,MgCl2或Cr(NO3)3)水溶液，正辛醇和正辛烷组成的微乳液中正辛醇从连续油相到界面的ΔGo→i^o和水的极限增容量φ'H2O。用金属萃取络合物反胶束的形成及其亲油性解释了金属离子对φ'H2O和ΔGo→i^o的影响。     

高水头船闸输水廊道反弧门水弹性振动试验研究

本文简要介绍水弹性振动模型试验的相似准则，用近似满足水弹性相似准则的有机玻璃模型对－高水头船闸反弧形阀门进行流激振动试验研究．试验表明阀门的振动是随机振动，不仅有质量振动而且有结构振动，有若干阶模态被激发参与振动。在开门和关门过程中，阀门面板脉动压力和阀门振动是不大的，与葛洲坝船闸类似阀门间歇开启的振动水平相当。由于常压模型不能正确模拟空化现象，对于廊道内可能产生的空泡溃灭所引起的阀门振动尚需通过减压模型进行研究。     

Chromatographic performance of monodisperse–macroporous particles produced by “modified seeded polymerization.” I: Effect of monomer/seed latex ratio

In this study, the monodisperse–macroporous particles produced by a relatively new polymerization protocol, the so‐called, “modified seeded polymerization,” were used as column‐packing material in the reversed phase chromatography (RPC) of proteins. The particles were synthesized in the form of styrene‐divinylbenzene copolymer approximately 7.5 μm in size. In the first stage of the synthesis, the monodisperse polystyrene particles 4.4 μm in size were obtained by dispersion polymerization and used as the “seed latex.” The seed particles were swollen by a low‐molecular‐weight organic agent and then by a monomer mixture. The monodisperse–macroporous particles were obtained by the polymerization of monomer mixture in the seed particles. In the proposed polymerization protocol, the number of successive swelling stages was reduced with respect to the present techniques by the use of sufficiently large particles with an appropriate average molecular weight as the seed latex. A series of particles with different porosity properties was obtained by varying the monomer/seed latex ratio. The separation behavior of HPLC columns including the produced particles as packing material was investigated in the RPC mode using a protein mixture including albumin, lysozyme, cytochrome c, and ribonuclease A. The chromatograms were obtained with different flow rates under an acetonitrile–water gradient. The theoretical plate number increased and chromatograms with higher resolutions were obtained with the particles produced by using a lower monomer/seed latex ratio. The separation ability of the column could be protected over a wide range of flow rates (i.e., 0.5–3 mL/min) with most of the materials tested. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 607–618, 2004     

Monodisperse‐porous poly(styrene‐co‐divinylbenzene) beads providing high column efficiency in reversed phase HPLC

A multistage polymerization protocol, the so‐called “modified seeded polymerization,” was developed for the production of monodisperse‐porous poly(styrene‐co‐divinylbenzene) providing high column efficiency as a packing material in reversed phase high performance liquid chromatography (RPLC). In the first stage of the multistage production, uniform polystyrene seed particles, produced by dispersion polymerization, were swollen by an organic agent (i.e., the diluent) and then by a monomer mixture containing styrene and divinylbenzene. The final porous particles were obtained in the monodisperse form by the polymerization of monomer mixture in the seed particles. By the use of a small size seed latex with low molecular weight and by the selection of the appropriate diluent, relatively small monodisperse‐porous particles with suitable pore structure could be achieved. In the reversed phase separation of alkylbenzenes, under isocratic conditions, theoretical plate numbers up to 40,000 plates/m were achieved by using 5.2 μm porous particles, obtained by a toluene‐dibutyl phthalate mixture as the diluent. No significant decrease in the resolution power was observed by the fourfold increase in the mobile phase flow rate. The column efficiency and the resolution observed with 5.2 μm monodisperse‐porous particles were significantly higher with respect to the currently available polymer based packing materials used in the reversed phase HPLC. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1430–1438, 2005     

REVERSED RESIDUALS IN AUTOREGRESSIVE TIME SERIES ANALYSIS

Abstract. Both linear and non-linear time series can have directional features which can be used to enhance the modelling and investigation of linear or non-linear autoregressive statistical models. For this purpose, reversed p th-order residuals are introduced. Cross-correlations of residuals and squared reversed residuals allow extensions of current model identification ideas. Quadratic types of partial autocorrelation functions are introduced to assess dependence associated with non-linear models which nevertheless have linear autoregressive correlation structures. The use of these residuals and their cross-correlation functions is exemplified empirically on some deseasonalized river flow data for which a first-order autoregressive model is a satisfactory second-order fit. Parallel theoretical computations are undertaken for the non-linear first-order random coefficient autoregressive model and comparisons are made. While the data are shown to be strongly non-linear, their correlational signatures are found to be convincingly different from those of a first-order autoregressive model with random coefficients.     

下喷自吸环流反应器中气-液局部相际传质模型

引言 下喷自吸环流反应器是在结合喷射、环流、自吸等优点基础上而开发出的一种新型高效反应器,开展该反应器内局部气液传质模型的研究,对于该反应器的优化设计及放大具有极重要的理论意义.多年来,经典传质理论的不足与局限都在经历不断的修正与改进.其中,激光多普勒测试在传质研究中的应用使得人们对湍流在传质中的重要性有了     

香豆素系列荧光染料的液相色谱分析

本文运用反相高效液相色谱法,以6只香豆素染料为研究对象,研究了流动相组成对它们色谱保留行为的影响,通过调整流动相的种类和组成比例,最终选用C18色谱柱为分析柱,乙腈-水为流动相,紫外吸收检测器为检测手段,建立了既适用于这6只香豆素系荧光染料的单一分析又适用于它们混拼分析的方法,解决了这6只染料混拼时的分析问题.     

Preparation and protein adsorption of hydrogel polysucrose microspheres

A series of novel hydrogel polysucrose microspheres with the mean size ranging from 200 to 500 μm were prepared via two‐step method. First, soluble polysucrose was synthesized by solution polymerization between sucrose and epichlorohydrin; second, a reversed phase suspension crosslinking reaction was performed to prepare polysucrose microspheres. The SEM images indicated that these spherical beads had smooth surface and hydrogel interior structure. FTIR was used to characterize the chemical structure of the beads. The hydrated and dry densities, equilibrium water content, and hydroxyl content of polysucrose microspheres were also investigated. The characteristic of high hydroxyl content (15.48–19.04 mmol/g) make these microspheres suitable for protein adsorption. Meanwhile, bovine serum albumin was used to examine the adsorption capacity of the microspheres. These microspheres had a capacity as high as 49.28 mg/g. The adsorption kinetics and recycling of the beads were also investigated. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5934–5940, 2006     

消能支撑框架结构的研究与应用

对几种型式的消能器进行了减震机理分析 ,对消能支撑框架模型进行了低周反复荷载试验和振动台试验 ,编制了非线性有限元分析程序和弹塑性时程分析程序 ,并将研究结果应用于实际工程     

啮合同向双螺杆挤出过程非啮合开槽螺纹元件组合流道三维流场分析

应用ANSYS有限元分析软件对啮合同向双螺杆挤出过程包括非啮合多过程螺纹元件（NI-MPE）组合流道进行了等温非牛顿三维流场模拟分析，得到了包括NI-MPE元件的组合流道的压力场、速度场、剪切速率场和剪切应力场，并与包括非啮合常规螺纹元件的组合流道的模拟结果进行了对比。