用于PET薄膜回收的螺杆设计

根据PET薄膜的特点和高分子熔融态流动理论，分析了挤出回收用螺杆的各段结构，及螺杆参数选择，设计出大长径比、深槽、双排气、高效专用螺杆。     

Green and self-lubricating polyoxymethylene composites filled with low-density polyethylene and rice husk flour

Polyoxymethylene (POM) composites filled with low-density polyethylene (LDPE) and rice husk flour (RHF) were prepared by injection molding. The POM/5 wt % LDPE/7.5 wt % RHF composite exhibited the lowest wear rate, whereas the coefficient of friction remained low, and the POM/5 wt % LDPE/5 wt % RHF composite had the best mechanical properties. X-ray diffraction analysis was carried out, and the worn surfaces were examined with scanning electron microscopy. The results showed that the addition of the filler reduced the crystallinity degree of the POM composites. The main wear mechanism for unfilled POM was adhesion, whereas for the POM composites, wear seemed to occur mainly by fatigue and abrasion. It was experimentally confirmed that the POM composite filled with LDPE and RHF, which is well-performing, low-cost, and environmentally friendly, could be a potential material for tribological applications. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Distribution and Fate of Escherichia coli in Lake Michigan Following Contamination with Urban Stormwater and Combined Sewer Overflows

Escherichia coli distribution and persistence in nearshore Lake Michigan were assessed following heavy rains and sanitary sewer overflow (SSO) and combined sewer overflow (CSO) events over a 5-year period, including an 18-day period following 25.4 cm of rainfall in which intensive studies were conducted following multiple CSO and SSO events. E. coli levels in the Milwaukee estuary and harbor following SSO and CSO events ranged from 10⁴ to nearly 10⁵ CFU/100 mL, which were significantly higher (p ≤ 0.05) than levels following rainfall alone. Sites outside of the breakwall but within the contamination plume (e.g., within 2 km of the harbor) were an order of magnitude lower. Locations 2–5 km from the harbor ranged from below detection limits, of < 1 to 5 CFU/100 mL. E. coli levels corrected for dilution based on specific conductivity measurements were lower than what would be expected for loss due to dilution alone, suggesting a combination of die-off and dilution, were responsible for the rapid disappearance of these organisms outside of the harbor. E. coli and fecal coliforms measured concurrently demonstrated that fecal coliforms could be recovered longer than E. coli in the open waters of the lake. E. coli isolated directly from sewage treatment plant influent were found to have a marked increase in antibiotic resistance traits for ten antibiotics commonly used in the human population compared with isolates from two animal sources of fecal pollution. However, E. coli obtained from sewage impacted water (n = 2,513) and from stormwater impacted water (n = 1,465) collected the previous year when there were no sewage overflows, were found to have no significant difference (p < 0.05) in the frequency of resistance when comparing the two conditions. E. coli survival characteristics and population dynamics are most likely influenced by multiple factors in complex systems such as the watershed/estuarine/lake environments of the Great Lakes.     

探讨回收污水中有用的物质

重油催化裂化等的污水含汽油、硫和氨，将汽油、硫和氨回收是哈尔滨石化分公司具有发展前景的项目。     

Uptake of Pb(II) and Cd(II) by a new phenolformaldehyde polymer resin derived by the insertion of sulfur ligands in the form of xanthate

A new phenolformaldehyde polymer resin containing potential soft‐type donor atoms (sulfur atoms) was synthesized by the reaction of sodium salt of 2,4‐dihydroxyacetophenone formaldehyde resin with carbon disulfide. The resin was characterized by elemental analysis, IR, and ¹H‐NMR spectral studies. Because of its insolubility in aqueous media, the resin was successfully used in the removal of Pb(II) and Cd(II). Parameters such as the effect of pH, the effect of time, competitive studies, the effect of initial metal‐ion concentration, and the recyclability of the polymer resin were studied. The amount of metal removed by the resin was determined with atomic absorption spectrophotometry. The retention properties were strongly dependent on pH. The elution of metal ions was investigated in acid media. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1932–1936, 2004     

钛纳米改性聚合物防腐涂料的研究

为保护大庆油田三元复合液中油管,以钛纳米改性聚合物为主要原料,研制了钛纳米改性聚合物重防腐涂料.采用透射电子显微镜(TEM)研究了钛纳米改性聚合物平均粒径.采用正交试验法,确定最佳原料配比.采用扫描电子显微镜(SEM)研究了漆膜腐蚀.采用金相显微镜研究了钛纳米改性聚合物在漆膜中的分布.探讨了油管的腐蚀机理和钛纳米涂料的防护机理.实验结果表明:钛纳米含量为6%时,涂料具有最佳的防腐蚀效果,能很好的保护大庆油田三元复合液中的油管,并具有优异的抗化学药品介质的腐蚀性能.     

城市污水的层流换热特性理论

为有效利用城市污水热能,以污水源热泵系统中的流动工质——城市污水为研究对象,通过理论分析的方法,对其层流状态下的换热特性进行理论推导和实验验证.结果表明:污水作为热泵的冷热源,有良好的换热特性,推导得出的换热准则关联式h=4.53λ/D,为污水源热泵系统设计提供依据,同时为应用污水余热技术提供理论基础.     

我国南方农村生活污水处理技术的研发现状

针对农村生活污水直接排放已经成为影响我国农村水环境质量主要因素之一的现状,从适合我国农村的以村落或居民点为单位进行生活污水分散式处理的思维入手,介绍了我国现今主要的分散式生活污水处理技术的原理、特点、不足及其应用现状;继而综合比较了这些技术的技术经济指标,提出了适合我国农村的分散式生活污水处理技术的设计原则;最后提出发展有较高水力负荷,并具备小规模设备化特征和多种生物处理单元复合的创新技术是我国农村生活污水处理技术发展的主要方向。     

冷再生结构层力学响应分析

通过研究冷再生结构层受力分析,在室内试验数据基础上,采用有限元BISAR软件对冷再生结构层以及常规半刚性路面结构层进行力学响应分析,得出了常规半刚性基层与冷再生基层力学响应的差异、冷再生层合理厚度、冷再生基层路面铣刨深度以及冷再生基层路面的使用条件.该研究对冷再生结构层设计与施工具有一定的借鉴作用.     

Melt‐processable rubber: Chlorinated waste tire rubber‐filled polyvinyl chloride

Chlorinated ground rubber tire (Cl‐GRT) particles were used as filler in a plasticized polyvinylchloride (PVC) to develop a melt‐processable rubber composition. Physical properties of the Cl‐GRT‐filled PVC compound showed improvement compared to the nonchlorinated counterpart. Interaction between Cl‐GRT and PVC was examined on the basis of results of stress relaxation, dynamic mechanical thermal analysis, and solvent swelling studies. The Cl‐GRT could be loaded upto 40 parts per hundred parts of PVC, and the composition still retains the elastomeric characteristics. The Cl‐GRT‐filled composite was found to be reprocessable like the unfilled PVC compound. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 622–631, 2002; DOI 10.1002/app.10352