Removal of As(V) Ions from Solution by Akaganeite bgr-FeO(OH) Nanocrystals

The original method is developed for producing the new inorganic sorption material of akaganeite bgr-FeO(OH). The material in question is characterized relative to arsenic contained in aqua. The possibility is established for removing arsenate ions from water by contemporary physicochemical methods.     

膨润土在废水处理中的应用综述

随着环境保护标准的日益严格，开发新型、廉价、高效的水处理材料也日趋紧迫。首先简要地介绍了非金属矿物材料——膨润土的矿物学特征。这些特征使得膨润土具有许多优良的基本特性，如电负性、离子交换性能等等。如果进一步针对膨润土的一种或者某些特性加以改性，膨润土就非常有可能在实际工程中被广泛应用。其次较为详细地综述了膨润土在废水处理中应用的现状，主要是作为制备吸附剂和絮凝剂的原料。而且，由膨润土改性所制成的吸附剂或絮凝剂对废水中的无机、有机污染物都有较为理想的去除率。最后，对膨润土的应用前景进行了展望。     

Effects of multiple weak interactions on the binding of phenolic compounds by polymeric adsorbents

To investigate the effects of multiple weak interactions on the binding of phenolic compounds by polymeric adsorbents, macroporous polystyrene (PS) resin and PS‐based adsorbents with different hydrogen‐bond acceptor atoms (PS CH₂( OCH₂CH₂)_n OCH₃, n = 0, 1, 2, and 3, denoted as PS‐EG₀, PS‐EG₁, PS‐EG₂, and PS‐EG₃) were prepared. The phenol adsorption strength order on these adsorbents was PS/PS‐EG₀ < PS‐EG₁ < PS‐EG₂ < PS‐EG₃, indicating that the adsorption on PS and PS‐EG₀ was driven by hydrophobic and π–π interactions, and the adsorption on PS‐EG₁, PS‐EG₂, and PS‐EG₃ was driven by a hydrogen bond in addition to hydrophobic and π–π interactions. PS‐EG₂ may adsorb a second phenol molecule on each binding site and PS‐EG₃ may adsorb second and third ones. The adsorption strength of resorcinol increased in the order of PS, PS‐EG₁, and PS‐EG₂, indicating that the adsorption was driven by 0, 1, and 2 hydrogen bonds in addition to hydrophobic and π–π interactions. Similarly, the adsorption of phloroglucinol on PS, PS‐EG₁, PS‐EG₂, and PS‐EG₃ was driven by 0, 1, 2, and 3 hydrogen bonds in addition to hydrophobic and π–π interactions because the adsorption strength increased in this order. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4652–4658, 2006     

吸附法脱除乙烯中少量氧气的吸附剂研究

采用重量法在电子天平上研究了Ｃ２Ｈ４和Ｏ２单组份在５Ａ、１３Ｘ、丝光沸石和碳分子筛等不同吸附剂上的吸附平衡性质和扩散动力学性质。结果表明，在沸石类吸附剂上，Ｃ２Ｈ４的平衡吸附量远大于Ｏ２的平衡吸附量，Ｃ２Ｈ４的吸附扩散速率也大于Ｏ２的扩散速率；在碳分子筛吸附剂上Ｃ２Ｈ４的平衡吸附量大于Ｏ２的平衡吸附量，但Ｏ２的吸附扩散速率远大于Ｃ２Ｈ４的扩散速率，其扩散系数是Ｃ２Ｈ４的２３９倍。单柱评价结果表明，Ｃ２Ｈ４－Ｏ２混合组份通过该碳分子筛吸附剂时，Ｏ２的破点时间长，Ｃ２Ｈ４的纯度可达１００％。加压有利于选择吸附Ｏ２，而且加压吸附、常压脱附再生性能好。该碳分子筛是脱除高浓度乙烯中少量氧气的理想吸附剂。     

Study of Desorption Agent for LADS Process

This article refers to the procedure for selection, evaluation and development of the LADS-D desorption agent associated with the LADS-A adsorbent used in the non-hydroprocessing adsorptive desulfurization (LADS) process for FCC naphtha developed by LPEC Refining Research Institute. The LADS-D desorption agent can effectively remove the sulfides adsorbed on the LADS-A adsorbent. The saturated LADS-A adsorbent can be instantly regenerated by the LADS-D desorption agent to recover its adsorption activity. The LADS-D desorption agent can not only effectively remove all impurities adsorbed on the adsorbent, but also has strong ability to dissolve the impurities to keep a stable desorption efficiency of adsorbent to be basically commensurate with fresh adsorbent after extended use.     

钛掺杂硅胶块体吸附剂

以陶瓷纤维纸片为基材,顺次经水玻璃、酸性钛盐溶液浸渍共沉淀制得新型陶瓷基钛掺杂硅胶块体吸附剂.多孔介质表面分析显示:掺杂硅胶孔径在0.5～6 nm范围,以中孔为主.Fourier变换红外谱在波数954 cm 1处的特征吸收峰表明吸附剂中形成了Si-O-Ti键.根据掺杂前后固体魔角核磁共振硅谱中硅原子化学位移的变化(向高场方向移动)及X射线光电子能谱中各原子结合能的变化(Ti2p3/2的结合能随钛含量的增加而增加,而Si2p,O1s的结合能则呈相反趋势)进一步表明:钛原子替代硅原子进入硅胶网络.热重分析及烧结实验结果显示:钛掺杂吸附剂具有更好的热稳定性.新型吸附剂优异的吸附性能除了与其高的比表面积相关外,还与Ti-O键对水分子的亲合力紧密相关,其耐热性能增强与形成高热稳定性Ti-O Si键及材料表面导热性能提高有关.     

层析法分离提取葡萄籽原花青素的进一步研究

以吸附量和解吸率为指标,比较了7种大孔吸附树脂对原花青素的静态吸附解吸性能并考查了AB—8树脂对原花青素的吸附特性及机理。实验结果表明:AB—8树脂是较理想的吸附剂;在溶液中AB—8树脂对原花青素的吸附达到平衡的时间为240 min,吸附行为符合Langmuir等温方程;最佳动态吸附参数原花青素提取液浓度4.0 mg/mL,吸附流速2 BV/h(1BV=13.03 mL)用40%乙醇溶液洗脱。AB—8树脂适合于柱层析操作分离原花青素。     

超高交联树脂吸附对硝基苯乙酮和对硝基苯甲酸的研究

研究了NDA-150、NDA-99、NDA-88、Amberlite XAD-4．4种吸附树脂对对硝基苯乙酮和对硝基苯甲酸的静态吸附行为。结果表明NDA—150树脂对硝基化合物的吸附效果较好。并研究NDA-150树脂的动态吸附和脱附行为．结果显示：NDA-150树脂对对硝基苯甲酸的吸附容量为2．32mmol／g干树脂，对对硝基苯乙酮的吸附容量为3．06mmol／g干树脂。NDA—150树脂易于脱附，吸附对硝基苯甲酸后．用2％NaOH：乙醇(体积比1：1)作脱附剂，温度313K；吸附对硝基苯乙酮后，用甲醇作脱附剂，温度333K，体积6BV，脱附率均接近100％。     

变压吸附(PSA)空分制氧技术进展

论述了 PSA法空分制氧分子筛的开发现状和制氧工艺的进展 ,为 PSA法空分制氧今后的发展提出了研究方向     

常温微量氯气吸附剂的制备及其性能研究

本实验用一次等量浸渍法制备氯气吸附剂,通过分光光度法测定进出口的微量Cl2并重点分析了影响氯气吸附剂性能的一些评价参数,对于改进测定方法,准确测定微量氯气,提高Cl2吸附剂的净化性能都具有十分重要的意义。