Diluted chemical bath deposition of CdZnS as prospective buffer layer in CIGS solar cell

In this study, dilute chemical bath deposition technique has been used to deposit CdZnS thin films on soda-lime glass substrates. The structural, morphological, optoelectronic properties of as-grown films have been investigated as a function of different Zn²⁺ precursor concentrations. The X-ray diffractogram of CdS thin-film reveals a peak corresponding to (002) plane with wurtzite structure, and the peak shift has been observed with the increase of the Zn²⁺ concentration upon formation of CdZnS thin film. From morphological studies, it has been revealed that the diluted chemical bath deposition technique provides homogeneous distribution of film on the substrate even at a lower concentration of Zn²⁺. Optical characterization has shown that the transparency of the film is influenced by Zn²⁺ concentration and when the Zn²⁺ concentration is varied from 0 M to 0.0256 M, bandgap values of resulting films range from 2.42 eV to 3.90 eV while. Furthermore, electrical properties have shown that with increasing zinc concentration the resistivity of the film increases. Finally, numerical simulation validates and suggests that CdZnS buffer layer with composition of 0.0032 M Zn²⁺ concentration would be a promising candidate in CIGS solar cell.     

基于状态观测器的电镀液温度状态反馈控制系统

针对电镀液温度控制系统,引入状态反馈控制。相对于传统的反馈控制,本方法可以获得更优异的性能。另外,考虑到镀液温度控制具有纯迟延的特点,提出了一种消去纯迟延的方法。仿真验证结果显示,控制效果良好。     

钢样成分化验分析结果网络传输系统的开发与应用

钢样成分化验分析结果网络传输系统将碳硫分析仪、光谱分析仪和相应的计算机控制系统按以太网络结构组联,形成"炉前分析网络",采用分析网主服务器系统软件和网络分析系统软件实现网络传输。该系统可将炉前钢样化验分析结果实时传输到炉前大屏,具有传输速度快、准确率高的特点,提高了工作效率和产品合格率,降低了生产成本。     

一种基于GE90-30PLC的飞剪自动控制系统

本文介绍了调整线材轧线精轧机前专用于切头的启停式飞剪的自动控制系统。该系统以GE90—30PLC为控制核心，辅以热金属HMD、光电编码器等元件，能很好地完成飞剪的剪切及定位。其中着重阐述了飞剪控制中各个重要参数的计算原理和方法。     

Silver electrodeposition from air and water-stable ionic liquid: An environmentally friendly alternative to cyanide baths

The influence of temperature on the kinetics and the morphology of silver deposits obtained from an air and water-stable ionic liquid (the 1-butyl-3-methyl imidazolium tetrafluoroborate) was studied by means of cyclic voltammetry and chronoamperometry. The nucleation and growth mechanisms have been investigated and the effect of temperature evaluated up to 200 °C. Dense, pure and very thin (about 0.3 μm) silver coatings, with decorative properties, have been obtained on commercial copper electrodes at different temperatures. The characterization of the deposits morphology has been performed by visual investigation and SEM microscopy. Data about thickness were acquired by Calotest® measurements. The deposits result constituted by pure silver as determined by combination of EDX microanalysis and Auger Electron Spectroscopy (AES). The deposition method promises to be a new, environmentally friendly, method for silver electrodeposition which is the reason for the absence of cyanide and volatile toxic solvents in the electroplating bath.     

毛/涤纱分散/酸性(媒染)染料一浴法筒子染色工艺

毛/涤纱分散/酸性(媒染)染料一浴法筒子染色工艺,在100℃条件下能满足毛、涤两种纤维同时上染,染色产品具有着色深浓鲜艳,色泽一致,各项牢度符合要求,对纤维无损伤等优点,从而缩短生产时间,降低成本,提高经济效益。     

Analytical characterization of cadmium cyanamide in CdS thin films and bulk precipitates produced from CBD process in pilot plant

CdS thin films and bulk precipitates were obtained by chemical bath deposition (CBD) in a well-closed reactor. X-ray diffraction spectroscopy, Fourier transform infrared spectroscopy, thermal analysis, elemental analysis and leaching have been used to characterize solids and thin films. It has been shown that the proportion of cadmium cyanamide in solids may vary from about 50% to 2% according to physicochemical conditions in solution (time after CBD, ammonia concentration) and that CdO results from CdCN₂ after air annealing of thin films. This last step also increases the crystallinity of the films.     

高水头弧形闸门伸缩式水封的黏弹性仿真计算方法

认为止水材料的蠕变和应力松弛是由于材料参数的变化而引起的，把描述橡胶类材料应变能密度函数中的物理参数假设成与时间有关的黏弹性函数。在此基础上改进材料应力张量与应变张量的关系式，得到了改进的Mooney-Rivlin公式，给出了一种考虑止水材料黏弹性性质的伸缩式水封仿真计算方法。分析得出，止水材料由于受周边结构的限制，材料黏弹性阶段除顶点垂直位移不变，关键结点的其它位移并没有因材料的蠕变而显著变化，材料的蠕变有提高封头顶点接触应力的趋势，不会降低水封的水密性。通过工程实例，给出了140m水头下、封头与面板间隙控制在30mm内的可行并较优的伸缩式水封的断面。     

微酸性光亮锡铅合金镀液分析方法

提出锡铅合金液中Ｓｎ＾２＋，Ｓｎ（ＩＶ），ＰＢ＾２＋、ＥＤＴＱＡ、柠檬酸三钠的分析方法。     

中性固色剂NF在分散／活性一浴热溶染色中的应用

本文对涤棉混纺织物在分散/活性染料同浴染色中采用碱固工艺与中性固色工艺作了较详细的对比试验,同时对中性固色剂及双氰胺的用量进行了优选组合,并对中性固色剂的效果进行了讨论。