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1.
A novel finger‐sensing nanocomposite with remarkable and reversible piezoresistivity is successfully fabricated by dispersing homogeneously conductive graphite nanosheets (GNs) in a silicone rubber (SR) matrix. Because of the high aspect ratio of the graphite nanosheets, the nanocomposite displays a very low percolation threshold. The SR/GN nanocomposite with a volume fraction of conductive nanosheets closest to that for the percolation threshold presents a sharp positive‐pressure coefficient effect of the resistivity under very low pressure, namely, in the finger‐pressure range (0.3–0.7 MPa), whereby the abrupt transition could be attributed to compressive‐stress‐induced deformation of the conducting network. The super‐sensitive piezoresistive behavior of the nanocomposite is accounted for by an extension of the tunneling conduction theory which provides a good approximation to the piezoresistive effect. 相似文献
2.
Pierre Hadaya 《Electronic Commerce Research》2006,6(2):173-185
Based on the literature dealing with the diffusion of innovation and with information systems, and building on the emerging
concepts in electronic commerce (e-commerce), this paper aims at assessing the influence of various factors on firms’ future
level of use of electronic marketplaces (e-marketplaces). This theoretical model is tested on data collected from 1,200 senior
managers in Canadian firms. Findings indicate that a firm’s past experience in e-commerce, as well as the factors relating
to its business relationships ultimately affect its future use of e-marketplaces. Results of TOBIT regressions also show that
the complexity of sophisticated e-commerce implementations is negatively correlated with the future level of use of e-marketplaces,
and that consultants and other experts play an essential role in encouraging and facilitating the use of this new type of
electronic platform. Finally, our survey data demonstrate that the relative influence of some determinants differs according
to the firms’ size.
Pierre Hadaya is an assistant professor of MIS at the Faculté d’administration of the Université de Sherbrooke (Canada). He holds a Ph.D.
in Management of Technology from the école Polytechnique de Montréal. His research interests lie at the intersection of information
technology management, business strategy and interorganizational design. 相似文献
3.
Lopez Frederick G.; Fons-Scheyd Alia; Morúa Wendy; Chaliman Rebecca 《Canadian Metallurgical Quarterly》2006,53(4):543
This study examined the nature and impact of dyadic perfectionism over a 3-month interval within a sample of 116 college students who were currently involved in an intimate heterosexual relationship. Dyadic perfectionism scores were stable and correlated as expected with scores on concurrent measures of adult attachment orientations and relationship satisfaction. Logistic regression analyses revealed that, controlling for initial commitment status and adult attachment orientations, Time 1 dyadic perfectionism scores significantly and uniquely predicted relationship continuity 3 months later. Lastly, controlling for social desirability, relationship commitment status, and Time 1 adult attachment orientation scores, Time 1 dyadic perfectionism scores also uniquely predicted Time 2 relationship distress. Findings provide additional evidence that dyadic perfectionism is a risk factor for relationship dysfunction. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
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Bruno Gabel Denis Thiéry Vaclav Suchy Frédéric Marion-Poll Peter Hradsky Pavel Farkas 《Journal of chemical ecology》1992,18(5):693-701
The European grapevine moth (EGVM),Lobesia botrana, is a major pest of grapes in Europe. Females are attracted to a nonhost plant: tansy (Tanacetum vulgare L.), which is a common weed in Slovakian vineyards. A steam distillate extract of tansy flowers was analyzed by means of a GC-EAG technique to screen constituents detected by the olfactory receptors of EGVM females. From more than 200 GC peaks, nine peaks corresponding to monoterpenoids released an EAG response in more than 70% of the females (N=15):p-cymene,d-limonene,-thujene,-thujone,-thujone, thujyl alcohol, terpinene-4-ol, (Z)-verbenol, and piperitone. The steam distillate of tansy as well as a synthetic blend of identified compounds released consistent attraction in a field cage. The use of nonhost plants and host plant odors in integrated pest management is discussed. 相似文献
7.
Dr. Armin Welker Dr. Christian Kersten Dr. Christin Müller Dr. Ramakanth Madhugiri Collin Zimmer Patrick Müller Robert Zimmermann Stefan Hammerschmidt Hannah Maus Prof. John Ziebuhr Prof. Christoph Sotriffer Prof. Tanja Schirmeister 《ChemMedChem》2021,16(2):340-354
Inhibition of coronavirus (CoV)-encoded papain-like cysteine proteases (PLpro) represents an attractive strategy to treat infections by these important human pathogens. Herein we report on structure-activity relationships (SAR) of the noncovalent active-site directed inhibitor (R)-5-amino-2-methyl-N-(1-(naphthalen-1-yl)ethyl) benzamide ( 2 b ), which is known to bind into the S3 and S4 pockets of the SARS-CoV PLpro. Moreover, we report the discovery of isoindolines as a new class of potent PLpro inhibitors. The studies also provide a deeper understanding of the binding modes of this inhibitor class. Importantly, the inhibitors were also confirmed to inhibit SARS-CoV-2 replication in cell culture suggesting that, due to the high structural similarities of the target proteases, inhibitors identified against SARS-CoV PLpro are valuable starting points for the development of new pan-coronaviral inhibitors. 相似文献
8.
Sean R. Tachibana Longteng Tang Liangdong Zhu Yuka Takeda Keiji Fushimi Yoshibumi Ueda Takahiro Nakajima Yuto Kuwasaki Moritoshi Sato Rei Narikawa Chong Fang 《International journal of molecular sciences》2021,22(10)
Cyanobacteriochromes (CBCRs) are promising optogenetic tools for their diverse absorption properties with a single compact cofactor-binding domain. We previously uncovered the ultrafast reversible photoswitching dynamics of a red/green photoreceptor AnPixJg2, which binds phycocyanobilin (PCB) that is unavailable in mammalian cells. Biliverdin (BV) is a mammalian cofactor with a similar structure to PCB but exhibits redder absorption. To improve the AnPixJg2 feasibility in mammalian applications, AnPixJg2_BV4 with only four mutations has been engineered to incorporate BV. Herein, we implemented femtosecond transient absorption (fs-TA) and ground state femtosecond stimulated Raman spectroscopy (GS-FSRS) to uncover transient electronic dynamics on molecular time scales and key structural motions responsible for the photoconversion of AnPixJg2_BV4 with PCB (Bpcb) and BV (Bbv) cofactors in comparison with the parent AnPixJg2 (Apcb). Bpcb adopts the same photoconversion scheme as Apcb, while BV4 mutations create a less bulky environment around the cofactor D ring that promotes a faster twist. The engineered Bbv employs a reversible clockwise/counterclockwise photoswitching that requires a two-step twist on ~5 and 35 picosecond (ps) time scales. The primary forward Pfr → Po transition displays equal amplitude weights between the two processes before reaching a conical intersection. In contrast, the primary reverse Po → Pfr transition shows a 2:1 weight ratio of the ~35 ps over 5 ps component, implying notable changes to the D-ring-twisting pathway. Moreover, we performed pre-resonance GS-FSRS and quantum calculations to identify the Bbv vibrational marker bands at ~659,797, and 1225 cm−1. These modes reveal a stronger H-bonding network around the BV cofactor A ring with BV4 mutations, corroborating the D-ring-dominant reversible photoswitching pathway in the excited state. Implementation of BV4 mutations in other PCB-binding GAF domains like AnPixJg4, AM1_1870g3, and NpF2164g5 could promote similar efficient reversible photoswitching for more directional bioimaging and optogenetic applications, and inspire other bioengineering advances. 相似文献
9.
《Computer Speech and Language》2014,28(1):224-239
Language is being increasingly harnessed to not only create natural human–machine interfaces but also to infer social behaviors and interactions. In the same vein, we investigate a novel spoken language task, of inferring social relationships in two-party conversations: whether the two parties are related as family, strangers or are involved in business transactions. For our study, we created a corpus of all incoming and outgoing calls from a few homes over the span of a year. On this unique naturalistic corpus of everyday telephone conversations, which is unlike Switchboard or any other public domain corpora, we demonstrate that standard natural language processing techniques can achieve accuracies of about 88%, 82%, 74% and 80% in differentiating business from personal calls, family from non-family calls, familiar from unfamiliar calls and family from other personal calls respectively. Through a series of experiments with our classifiers, we characterize the properties of telephone conversations and find: (a) that 30 words of openings (beginnings) are sufficient to predict business from personal calls, which could potentially be exploited in designing context sensitive interfaces in smart phones; (b) our corpus-based analysis does not support Schegloff and Sack's manual analysis of exemplars in which they conclude that pre-closings differ significantly between business and personal calls – closing fared no better than a random segment; and (c) the distribution of different types of calls are stable over durations as short as 1–2 months. In summary, our results show that social relationships can be inferred automatically in two-party conversations with sufficient accuracy to support practical applications. 相似文献
10.
The effects of aging time of Cr(III) solutions on the structural, thermal, magnetic, and morphological properties of chromium polyacrylate complexes were studied. Chromium retention was found to increase with longer aging periods. IR spectra revealed the formation of polychelate structures with noticeable changes on aging. The interaction of multivalent, polynuclear Cr(III) species with the polymer backbone resulted in a decrease in thermal stability for the complexes prepared from olated chromium solutions. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 490–493, 2005 相似文献