全文获取类型
收费全文 | 7788篇 |
免费 | 357篇 |
国内免费 | 130篇 |
专业分类
电工技术 | 31篇 |
综合类 | 308篇 |
化学工业 | 5578篇 |
金属工艺 | 45篇 |
机械仪表 | 40篇 |
建筑科学 | 94篇 |
矿业工程 | 11篇 |
能源动力 | 56篇 |
轻工业 | 226篇 |
水利工程 | 1篇 |
石油天然气 | 680篇 |
武器工业 | 11篇 |
无线电 | 98篇 |
一般工业技术 | 1002篇 |
冶金工业 | 26篇 |
原子能技术 | 42篇 |
自动化技术 | 26篇 |
出版年
2024年 | 15篇 |
2023年 | 40篇 |
2022年 | 64篇 |
2021年 | 99篇 |
2020年 | 92篇 |
2019年 | 104篇 |
2018年 | 106篇 |
2017年 | 167篇 |
2016年 | 168篇 |
2015年 | 157篇 |
2014年 | 308篇 |
2013年 | 339篇 |
2012年 | 441篇 |
2011年 | 466篇 |
2010年 | 415篇 |
2009年 | 392篇 |
2008年 | 373篇 |
2007年 | 489篇 |
2006年 | 479篇 |
2005年 | 462篇 |
2004年 | 374篇 |
2003年 | 376篇 |
2002年 | 384篇 |
2001年 | 337篇 |
2000年 | 287篇 |
1999年 | 267篇 |
1998年 | 234篇 |
1997年 | 169篇 |
1996年 | 115篇 |
1995年 | 106篇 |
1994年 | 90篇 |
1993年 | 76篇 |
1992年 | 70篇 |
1991年 | 58篇 |
1990年 | 30篇 |
1989年 | 21篇 |
1988年 | 16篇 |
1987年 | 8篇 |
1986年 | 6篇 |
1985年 | 16篇 |
1984年 | 18篇 |
1983年 | 19篇 |
1982年 | 22篇 |
排序方式: 共有8275条查询结果,搜索用时 15 毫秒
1.
In this research, maleic anhydride-α-octadecene copolymer and its derivative with phenylethylamine was synthesized and its effect on the crystallization of paraffins was investigated. This derivative, when added into second cut of vacuum gas oil and forth cut of vacuum gas oil, increases the size and improves aggregation of paraffin crystals observed by polarizing light microscopy, increases onset temperature and enthalpy of paraffin crystallization determined by differential scanning calorimetry, improves the dewaxing efficiency with dosage of 100?ppm explored by MEK-toluene dewaxing. 相似文献
2.
Global decrease in crude oil resources and frequent crude oil leaks cause the energy crisis and ecological pollution. The absorption and release of leaked crude oil through absorption materials are a necessary process for environmental protection and recycling. In this article, a CO2-responsive olefin copolymer was obtained by copolymerization of styrene and an amine-containing olefin monomer. The structure of resultant copolymer was characterized by FTIR; thermal properties and CO2-responsive morphology changes were determined by DSC/TGA and SEM, respectively. Copolymers had certain absorption capacity for toluene with absorption rate up to 180.0%. The absorbed toluene could be released upon CO2 stimulation with desorption rate up to 84.6%. The CO2-responsive copolymer could be regenerated through a simple heating process and showed stable absorption–desorption performance even after being recycled for 4 times. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47439. 相似文献
3.
A highly transparent and thermally stable copolymer of 1‐adamantyl methacrylate and styrene
下载免费PDF全文
![点击此处可从《Polymer International》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Thermal and optical properties of copolymers of 1‐adamantyl methacrylate (AdMA) and styrene (St) prepared by free radical polymerization in the bulk are investigated. The copolymer forms an azeotrope when the composition is AdMA/St = 55/45 mol%. The glass transition temperature and decomposition temperature of the azeotropic copolymer are 170 and ca 340 °C, respectively. The refractive index increases nonlinearly with St content from 1.522 to 1.591. The light scattering loss at 633 nm is 28.1 dB km?1, which is less than half of that of polystyrene. The total optical loss including molecular vibrational absorption, which is evaluated using a copolymer‐based optical fiber, is 292–645 dB km?1 at 500–700 nm. These values correspond to transmittances of 86–93% for a 1 m optical path length. © 2014 Society of Chemical Industry 相似文献
4.
High‐performance thermosets with tailored properties derived from methacrylated eugenol and epoxy‐based vinyl ester
下载免费PDF全文
![点击此处可从《Polymer International》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Yuehong Zhang Yuzhan Li Vijay Kumar Thakur Zhenhua Gao Jiyou Gu Michael R Kessler 《Polymer International》2018,67(5):544-549
A renewable chemical, eugenol, is methacrylated to produce methacrylated eugenol (ME) employing the Steglich esterification reaction without any solvent. The resulting ME is used as a low‐viscosity co‐monomer to replace styrene in a commercial epoxy‐based vinyl ester resin (VE). The volatility and viscosity of ME and styrene are compared. The effect of ME loading and temperature on the viscosity of the VE–ME resin is investigated. Moreover, the thermomechanical properties, curing extent and thermal stability of the fully cured VE–ME thermosets are systematically examined. The results indicate that ME is a monomer with low volatility and low viscosity, and therefore the incorporation of ME monomer in VE resins allows significant reduction of viscosity. Moreover, the viscosity of the VE–ME resin can be tailored by adjusting the ME loadings and processing temperature to meet commercial liquid molding technology requirements. The glass transition temperatures of VE–ME thermosets range from 139 to 199 °C. In addition, more than 95% of the monomer is incorporated and fixed in the crosslinked network structure of VE–ME thermosets. Overall, the developed ME monomer exhibits promising potential for replacing styrene as an effective low‐viscosity co‐monomer. The VE–ME resins show great advantages for use in polymer matrices for high‐performance fiber‐reinforced composites. This work is of great significance to the vinyl ester industry by providing detailed experimental support. © 2018 Society of Chemical Industry 相似文献
5.
研究了具有新型结构的双膦胺镍配合物N,N-双(二苯膦基)-对甲氧基苯胺二氯化镍-甲基铝氧烷(PNP-N i-MAO)催化体系对苯乙烯聚合的催化性能,考察了聚合温度、n(A l)∶n(PNP-N i)、PNP-N i的浓度和苯乙烯的浓度对催化活性、苯乙烯转化率、聚苯乙烯相对分子质量及其分布的影响,并用核磁共振和凝胶色谱对聚苯乙烯的结构进行了表征。实验结果表明,在聚合温度25℃、聚合时间1h、n(A l)∶n(PNP-N i)=300、c(苯乙烯)=2.3m ol/L、c(PNP-N i)=0.4mm ol/L、甲苯为溶剂的适宜条件下,苯乙烯的转化率可达95%以上,催化活性达到5×105g/(m ol.h)左右。核磁共振和凝胶色谱表征结果显示,所得聚苯乙烯为无规结构,重均相对分子质量约为1×104,相对分子质量分布Mw/Mn约为2。 相似文献
6.
7.
8.
高分子表面活性剂对超声辐照下苯乙烯乳液聚合的影响 总被引:1,自引:0,他引:1
在超声辐照引发苯乙烯乳液聚合中加入一种新型的以羧甲基纤维素为基础的高分子表面活性剂(CMC—A9),讨论了高分子表面活性剂对反应动力学的影响。实验表明,超声辐照下初级自由基并非由通常认为的高分子表面活性剂产生,而是十二烷基硫酸钠在超声辐照下断裂,产生自由基。通过对反应动力学的研究,发现超声辐照下乳液聚合机理不同于常规乳液聚合,聚合反应过程只有两个阶段,即加速期和减速期,不存在恒速期。加入CMC—A9高分子表面活性剂,可以在较短的时间内和较低的超声功率下达到较高的单体转化率。 相似文献
9.
碳黑对苯乙烯自由基聚合反应影响的研究 总被引:1,自引:0,他引:1
研究了碳黑对苯乙烯单体聚合物反应的影响,结果表明,用过氧化苯甲酰作引发剂,普通碳黑子对苯乙烯的聚合有强烈的阻聚作用,而用偶氮二异丁腈引发聚合物时,普通碳黑的阻聚性很小,当时碳黑进行接枝处理后,接枝碳黑对苯乙烯自由基聚合的影响程度与接枝方法有关,其中过氧化苯甲酰 自由基枝枝碳黑的聚性变化较大。 相似文献
10.
HDPE/PS/HDPE-g-PS合金的相容性和力学性能研究 总被引:1,自引:0,他引:1
用自制接枝共聚物GR-Ⅰ、GR-Ⅱ相容剂研究其对HDPE/PS共混物相容性和力学性能的影响。通过SEM、DMA、DSC和力学性能测试表征,表明在HDPE/PS共混中加入这些相容剂其相容性和力学性能有一定提高 相似文献