含-NCO双组分水性木器漆的应用研究

介绍了以-NCO交联的双组分水性木器漆常用的树脂、固化剂类型，对其在木器涂装过程中的施工时限、泡沫控制等影响生产应用的因素进行了分析研究，并提出了一些解决方案。     

Simultaneous chromizing-aluminizing coating of austenitic stainless steels

Chromium and aluminum were simultaneously co-deposited by diffusion into austenitic stainless steel substrates, by a single-step, pack-cementation process. The mechanism for the formation of diffusion-coated products on 304 and 316 stainless steels and on Incoloy 800 is discussed. The morphologies of the phases formed at the surface, i.e., an external beta layer and an underlying multiphase interdiffusion zone, are presented. The formation of the brittle, , outer layer was minimized by variations in the pack composition and activator. The coated 304 and 316 steels exhibited excellent scaling resistance upon oxidation in air at 1000°C.     

Formation of a chromium-carbide conversion coating on silicon carbide

The formation of a chromium-carbide conversion coating on SiC was achieved using the pack-cementation technique. The conversion coating is intended to improve the corrosion resistance of SiC and its derivatives, such as SiC-base continuous fibers and composites, by forming a protective Cr₂O₃ scale upon exposure to high-temperature corrosive environments. Different pack chemistry and processing parameters were evaluated in the laboratory. Results indicated that the coating morphologies and compositions achieved were significantly affected by variation of these processing factors. In this paper, the conversion coating obtained from one of the systems investigated is reported. The coating consists of a multilayered structure with each of the sublayers containing a high-Cr concentration. In addition, the coating surface is relatively dense and pore free compared to the underlying SiC substrate material. A dense and pore-free morphology is highly desirable for coating applications, especially on porous substrates. The multilayered coating structure consists of the following sublayers: Cr₂₃C₆/Cr₇C₃/Cr₇C₃+Cr₃Si/Cr₅Si₃C_x/SiC substrate.     

快速低温固体S—C—N三元共渗工艺研究

以木炭、尿素和硫化铁为渗剂,用稀土化合物CeCl_3作催渗剂,于570℃进行固体S-C-N三元共渗。试验结果表明,在相同时间内加催渗剂的渗层深度比不加催渗剂的有大幅度提高,且硬度及耐磨性亦有较大提高,硬度梯度较平缓。离子探针分析表明,稀土元素Ce亦被渗入钢的表面,它不仅起到活化渗剂的作用,同时在提高钢的性能方面还起到微合金化的作用。     

粗TiCl4除钒工艺探讨

研究了粗TiCl4除钒的工艺过程，通过试验比较了各种有机物除钒的效果，结果表明矿物油除钒性能优异。1t粗TiCl4加矿物油2～4kg，反应温度135～138℃，反应时间60min，收率大于95％，质量达到企业产品标准要求。     

纳米间隙润滑剂季戊四醇四酯的压缩性能分子动力学模拟

季戊四醇四酯(Pentaerythritol tetra(2-ethylhexanoate),PETE)是良好的环境友好润滑剂。采用聚合物一致性力场(PCFF),分别在2种温度、3种初始油膜厚度和8种压力下对纳米间隙中PETE的压缩性能进行分子动力学模拟,研究润滑剂分子和密度的分布规律,并与经典宏观压缩试验得出的Tait方程计算值进行比较。结果表明,随着初始油膜厚度的增加,分子动力学模拟结果越接近Tait方程计算值,当初始油膜厚度为9.17 nm时,相对误差小于5%。在压缩过程中,油膜厚度和润滑剂的可压缩性能随着压力的增大而减小。对于不同初始油膜厚度的油膜,其压缩性能相近。由于PETE的分子结构中有较多且较长的支链,各方向尺度没有太大差异,受压缩后,除了接近固体壁面处有润滑剂原子聚集,其他地方不存在分层现象,且润滑剂与固体壁面之间不存在明显的空隙。     

VB含用户子目录安装程序设计

介绍了VB自带工具“打包和展开向导”的工作原理和过程,提出了用这个工具打包含有用户子目录程序时出现的问题,并针对这些问题设计了一个算法,通过修改“打包和展开向导”中setup1.exe的源程序,使得“打包和展开向导”在打包含用户子目录程序的过程简单而且不出现问题。     

Morphology, structure and formation mechanism of silicide coating by pack cementation process

The MoSi2 coating on C 103 niobium based alloy was prepared by pack cementation method. The formative mechanism, morphology and structure of coating were investigated. The silicide coating was formed by reactive diffusion obeying parabolic rule during pack cementation process. It is found that the composite structural coating is composed of three inferior layers as follows. The main layer is composed of MoSi2, the two phases＇ transitional layer consists of NbSi2 and a few NbsSi3 and the diffuse layer is composed of NbsSi3. The dense amorphous glass layer formed on the surface at high temperature oxidation circumstance can effectively prevent the diffusion of oxygen into coating.     

Codeposited chromium and silicon diffusion coatings for Fe-Base alloys via pack cementation

The simultaneous deposition of Cr and Si into plain carbon, low-alloy, and austenitic steels using a halide-activated pack-cementation process is described. Equilibrium partial pressures of gaseous species have been calculated using the STEPSOL computer program to aid in designing specific processes for codepositing the desired ratios of Cr and Si into a given alloy. The calculations indicate that NaCl-activated packs are chromizing, while NaF-activated packs deposit more Si with less Cr. The use of a dual activator (e.g., NaF+NaCl) allows for the deposition of both Cr and Si in the desired amounts. Single-phase ferritic coatings (150–250 microns thick) with a surface concentration of 20–35 wt.% Cr and 2–4% Si have been grown on AISI 1018, Fe-2.25 Cr-1.0Mo-0.15C, and Fe-0.5 Cr-0.5 Mo-0.2C steels using packs containing a 90 wt.% Cr-10Si binary source alloy, a NaF+NaCl activator, and a silica filler. Two-phase coatings (approximately 75 microns thick) containing 20–25 wt.% Cr and 2.0–2.4% Si have been obtained on 304 stainless steel using packs containing a 90 wt.% Cr-10Si binary source alloy, a NaF activator, and an alumina filler. The same pack chemistry allowed the diffusion of Cr and Si into the austenitic Incoloy 800 alloy without a phase change. A coated Fe-2.25 Cr-1.0 Mo-0.15 C coupon with a surface concentration of Fe-34 wt.% Cr-3Si was cyclically oxidized in air at 700°C for over four months and 47 cycles. The weight gain was very low (<0.2 mg/cm²) with no scale spalling detected. Coated coupons of AISI 1018 steel, and Fe-0.5 Cr-0.5 Mo-0.2C steel have shown excellent oxidation-sulfidation resistance in reducing, sulfur-containing atmospheres at temperatures from 400 to 700°C and in erosion and erosion-oxidation testing in air at 650 and 850°C.     

全球铝轧制工业概览系列综述之十九——中国铝箔工业回眸与现状

全面系统地回顾了中国铝箔工业的发展历程,概述了现状。介绍了中国1983～2002年的铝箔产量、进出口量与消费量。中国铝箔工厂的建设始于1932年,但批量工业生产却在1933年。1960～1980年中国建设了20余家小铝箔厂,遍布全国各地,但仍20世纪30年代的装机与技术水平。1980年东北轻合金有限责任公司从德国阿申巴赫公司引进的中国首台现代化铝箔轧机(1200mm4辊不可逆式万能轧机)的投产,标志着中国铝箔工业进入了一个新的阶段。截止到2002年底,中国保有的铝箔企业93家,总生产能力493.4kt/a,居世界第二位,产量可达325kt/a(估测),仅次于美国,居世界第二位;有现代化的辊面宽度超过1000mm的4辊铝箔轧机66台,还有可生产厚箔及单零箔的4辊万能冷轧机39台。中国已是世界铝箔大国,但还不是一个铝箔强国,仍是铝箔净进口国。铝箔的某些性能与生产的技术经济指标,与发达国家的相比仍有一些差距。从2000年起中国铝箔工业进入了一个向世界铝箔强国迈进的新阶段,可能要持续到2010年或更长一些时间。