碲酸盐系统玻璃组成和结构对非线性光学性能的影响

碲酸盐系统重金属氧化物玻璃是一种优秀的非线性光学玻璃材料，具有较大的三阶非线性光学效应、超快光学响应、较宽红外透过范围、较好稳定性以及广泛应用前景。碲酸盐系统玻璃中的中间离子和网络外离子的加入会改变组成网络的配位多面体组成、键性和能带结构，进而影响玻璃的非线性光学性能。探讨了碲酸盐系统玻璃的网络结构，阐述了玻璃组成、结构以及纳米簇和非线性光学性能之间的相互关系。     

聚腈分子的飞秒时间分辨光克尔效应

本文利用飞秒时间分辩光克尔效应，对主链为Ｃ＝Ｎ结构的两种共轭聚腈高分子的溶液和薄膜进行研究，所测得的时间分辨光克尔信号均表现为超快响应。     

Synthesis and optical properties of polyacetylenes containing nonlinear optical chromophores

High molecular weight polyacetylenes bearing nonlinear chromophoric pendants poly[4-ethynyl-4′-(N,N-diethylamino)azobenzene-co-phenylacetylene]s [poly(EAAB-co-PA)s] were synthesized in moderate yields by [Rh(nbd)Cl]₂-Et₃N. The azo unit in the copolymers can be effectively controlled by the monomer feed ratio. Whereas the homopolymer of EAAB possessed low solubility, all the copolymers, however, dissolved readily in common organic solvents when the poly(EAAB) molar content was less than 41.7%. The structures and properties of the polymers were characterized and evaluated by UV, NMR, optical limiting, and nonlinear optical analyses. All the copolymers possessed high stereoregularity and thermal stability (≥300 °C). They can attenuate intense laser pulses, with solutions of high concentrations showing better performances. The third-order nonlinear susceptibility of the copolymers was as high as 4.62×10⁻¹¹ esu, which are two orders of magnitude larger than those of poly(PA), and larger than that of poly(N-carbazoylacetylene), and poly(1-naphthylacetylene).     

Interpretation of quasi-elastic light scattering data for flexible chains: model dependence

The autocorrelation functions and corresponding relaxation times obtained from the forward depolarized quasi-elastic light scattering experiment are exhibited for two quite similar models of flexible polymer chains in solution. A very small change in the chain dynamics is found to be sufficient to change the relaxation time from a relatively short time independent of chain length, with an autocorrelation function suggestive of an unweighted sum of contributions from all the relaxation times in the spectrum of chain motion, to a long time with an autocorrelation function identical with that for the end-to-end vector, strongly dependent upon chain length and dominated by the longest relaxation time in the spectrum. These results raise the question whether widely-used models in which information about short-range chain structure and motion is deliberately omitted can be expected to be appropriate for the interpretation of depolarized scattering experiments.     

基于数字线性化技术的高性能光载无线链路

针对光载无线(Radio over fiber, ROF)链路中的固有非线性,研究了多种数字线性化技术,来提高链路性能。下行链路针对多频段多制式场景,提出采用多维数字预失真技术,最大输入射频功率增加了3 dB,进而提高了下行链路的射频功率传送效率。同时,提出了多维预失真在2倍过采样率,考虑5阶非线性,无记忆时有最佳的链路性能改善。上行链路采用基于输出截断点获取的数字后补偿技术,仅需确定系统三阶截断点(Output third-order intercept point,OIP3)即可完成非线性补偿函数的确定与失真的补偿,无杂散动态范围(Spurious free dynamic range,SFDR)可提高到128.3 dB·Hz2/3;上行链路针对多频段多 制式架构采用盲估计数字后补偿技术,动态范围提高了3 dB。     

四叔丁基萘酞菁氧钒非线性及光限幅特性

为提高酞菁化合物的非线性光学性能,以1,8-二氮杂双环[5.4.0]十一碳烯-7(DBU)为催化剂,采用液相法合成了四叔丁基萘酞菁氧钒((t-Bu)4NcVO)化合物.利用元素分析、红外光谱、核磁共振氢谱方法,验证了化合物的分子结构.应用调Q倍频ns/ps Nd∶YAG脉冲激光系统,在波长为532nm下,研究了化合物的非线性和光限幅特性.测得化合物的非线性折射率n2和三阶非线性极化率χ(3)分别为2.51×10-11esu和8.54×10-12esu,通过计算得到分子极化率γ’为3.7×10-29esu.在透过率69%时限幅阈值为1608mJ/cm2,箝位值为585mJ/cm2,有效激发态与基态吸收截面比为3.66.     

花菁染料聚乙烯醇延伸膜的三阶非线性光学极化率的各向异性

采用飞秒共振简并四波混频技术,检测了花菁染料的聚乙烯醇延伸膜平行和垂直于延伸方向的三阶非线性光学极化率.结果表明:单向延伸的花菁染料的聚乙烯醇膜具有较高的三阶非线性光学极化率的各向异性.     

Mean polarizabilities and second optical and density virial coefficients of CH3OH and CCl2F2 between 300 and 355 K

Mean dipole polarizabilities ₀(, T) as well as second optical (or refractive index) virial coefficients b _R(, T) and second density virial coefficients B(T) of gaseous CH₃OH and CCl₂F₂ have been determined by precise measurements of the refractive index n(, T, p) [543 nm 633 nm, 300 K T 355 K, p<0.25 bar (CH₃OH) and p<3 bar (CCl₂F₂)]. ₀ critically compared with the few data in literature. The b _R of these gases was measured for the first time with the cyclic-expansion method. The values of ¦B¦ and b _R=3160(25) cm³ · mol^–1 measured for CH₃OH are considerably greater than the values calculated by Buckingham's statistical-mechanical expressions for a Stockmayer interaction potential. This difference is discussed by assuming dimerization via H bonds, with result H ₂ ⁰ –(28 ... 33) kJ · mol^–1 and S ₂ ⁰ –(116 133) J · mol^–1 · K^–1 for the dimerization enthalpy and entropy for standard conditions, respectively. On the other hand, Buckingham's formulae can be used with success to estimate b _R and B of CCl₂F₂.Dedicated to Prof. Dr. F. Kohler on the occasion of his 65th birthday     

2～5GHz 0.18μm CMOS宽带低噪声放大器设计

本文设计实现了一个2～5GHz的两级CMOS低噪声放大器(LNA),可应用在超宽带的下半频段(3.1～5GHz)。LNA由两级组成,第一级是一个共栅级,保持良好的线性度并完成较好的输入匹配;第二级是一个共源级堆叠一个电流源,在保持低噪声系数的同时降低功耗。通过级联共栅和共源结构进行增益补偿,所设计的LNA具有近似恒定的增益和噪声系数。采用0.18μm CMOS工艺实现后,模拟结果表明,增益和噪声系数在2～5GHz频率范围内分别为11.5dB和5.1dB,输入反射系数低于-22dB。在4GHz时,模拟得到的三阶交调点为-10dBm。在1.8V电源电压下,LNA的功耗约为11mW。     

弱电网下直驱风机网侧换流器建模及稳定运行控制策略分析

直驱风机网侧换流器可能因与弱电网动态交互引发系统失稳问题。为探究系统的交互机理,保证系统的稳定运行,首先对直驱风机并网模型进行了合理简化,建立了弱电网下直驱风机网侧换流器与电网交互的单输入单输出传递函数模型,并应用经典频域判据进行稳定性分析,探究电气与控制环节对于系统稳定性的影响。其次在分析锁相环导致系统失稳的原因基础上,提出了一种新型3阶锁相环控制结构设计方案,并对锁相环参数进行了多目标优化设计。结果表明,3阶锁相环具有更好的谐波衰减效果,在短路比为2的极弱电网下仍可以保持稳定运行。最后基于MATLAB/Simulink仿真平台验证了所提设计方案的有效性。