全文获取类型
收费全文 | 30722篇 |
免费 | 3223篇 |
国内免费 | 1531篇 |
专业分类
电工技术 | 2853篇 |
技术理论 | 1篇 |
综合类 | 2485篇 |
化学工业 | 9362篇 |
金属工艺 | 1935篇 |
机械仪表 | 1511篇 |
建筑科学 | 1384篇 |
矿业工程 | 1477篇 |
能源动力 | 2977篇 |
轻工业 | 880篇 |
水利工程 | 988篇 |
石油天然气 | 1660篇 |
武器工业 | 147篇 |
无线电 | 1695篇 |
一般工业技术 | 2616篇 |
冶金工业 | 1355篇 |
原子能技术 | 289篇 |
自动化技术 | 1861篇 |
出版年
2024年 | 81篇 |
2023年 | 364篇 |
2022年 | 577篇 |
2021年 | 724篇 |
2020年 | 817篇 |
2019年 | 796篇 |
2018年 | 711篇 |
2017年 | 934篇 |
2016年 | 1037篇 |
2015年 | 1007篇 |
2014年 | 1701篇 |
2013年 | 1916篇 |
2012年 | 1952篇 |
2011年 | 2224篇 |
2010年 | 1684篇 |
2009年 | 1729篇 |
2008年 | 1715篇 |
2007年 | 2018篇 |
2006年 | 1786篇 |
2005年 | 1527篇 |
2004年 | 1443篇 |
2003年 | 1343篇 |
2002年 | 1248篇 |
2001年 | 1136篇 |
2000年 | 919篇 |
1999年 | 778篇 |
1998年 | 665篇 |
1997年 | 516篇 |
1996年 | 430篇 |
1995年 | 361篇 |
1994年 | 300篇 |
1993年 | 205篇 |
1992年 | 176篇 |
1991年 | 128篇 |
1990年 | 125篇 |
1989年 | 80篇 |
1988年 | 64篇 |
1987年 | 78篇 |
1986年 | 44篇 |
1985年 | 43篇 |
1984年 | 32篇 |
1983年 | 18篇 |
1982年 | 10篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1974年 | 2篇 |
1959年 | 2篇 |
1956年 | 2篇 |
1954年 | 1篇 |
1951年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
《International Journal of Hydrogen Energy》2022,47(100):41956-41973
Due to stringent environmental regulations and the limited resources of fossil-based fuels, there is an urgent demand for clean and eco-friendly energy conversion devices. These criteria appear to be met by hydrogen proton exchange membrane fuel cells (PEMFCs). PEMFCs have attracted tremendous attention on account of their excellent performance with tunable operability and good portability. Nonetheless, their practical applications are hugely influenced by the scarcity and high cost of platinum (Pt) used as electrocatalysts at both cathode and anode. Pt is also susceptible to easy catalyst poisoning. Herein, this paper reviews the progress of the research regarding the development of electrocatalysts practically used in hydrogen PEMFCs, where the corner-stone reactions are cathodic oxygen reduction reaction (ORR) and anodic hydrogen oxidation reaction (HOR). To reduce the costs of PEMFCs, lessening or eliminating the use of Pt is of prime importance. For current and forthcoming laboratory/large-scale PEMFCs, there is much interest in developing substitute catalysts based on cheaper materials. As such are non-platinum (non-Pt), non-platinum group metals (non-PGMs), metal oxides, and non-metal electrocatalysts. Hence, high-performance, state-of-the-art, and novel structured electrocatalysts as replacements for Pt are needed. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(11):6975-6985
A technology for cyclic generation of hydrogen and oxygen using electrodes made of variable valency material that does not need the use of separating ion-exchange membranes is presented. The technological solution enables to fabricate electrolyzers for uninterrupted producing high-pressure hydrogen with reduced energy intensity of the production. The total work for compressing 1 m3 of hydrogen and 0.5 m3 of oxygen has been estimated. Results of investigation of influence of discrete supply of DC current to the electrolysis cell, in order to improve the processes of gas evolution and to simplify the power systems of the electrolysis plant, have been considered. There is also considered an electrolysis installation equipped with a thermosorption compressor in which LaNi5 is used as a hydride-forming compound. The comparative characteristics of the developed electrolyzer and the currently used hydrogen generators are given. 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(12):7915-7931
This paper carefully evaluates the electrocatalytic activity of Sr2FeMo0.5Mn0.5O6 (SFMM) double perovskite as a candidate to substitute the state-of-the-art Ni/YSZ fuel electrode. The electrochemical performance of a 40% SFMM/CGO composite electrode was studied in CO/CO2 and H2 with different oxygen partial pressure. Two different cell configurations are prepared at a relatively low temperature of 800 °C to increase the electrochemically active surface area. The cell was supported with a 150 μm 10Sc1CeSZ electrolyte in the first configuration. The cell in the second configuration was made by applying a 400 nm thin 8YSZ layer on 150 μm CGO electrolyte to improve the electrolyte ionic conductivity. Improving catalytic activity with increasing oxygen partial pressure is a key characteristic of the developed electrode. The polarization resistance of about 0.34 and 0.56 Ω cm2 at 750 °C in 3%H2O + H2 and 60% CO/CO2 makes this electrode a promising candidate for SOCs application. 相似文献
5.
A 2D computational fluid dynamics (Eulerian–Eulerian) multiphase flow model coupled with a population balance model (CFD-PBM) was implemented to investigate the fluidization structure in terms of entrance region in an industrial-scale gas phase fluidized bed reactor. The simulation results were compared with the industrial data, and good agreement was observed. Two cases including perforated distributor and complete sparger were applied to examine the flow structure through the bed. The parametric sensitivity analysis of time step, number of node, drag coefficient, and specularity coefficient was carried out. It was found that the results were more sensitive to the drag model. The results showed that the entrance configuration has significant effect on the flow structure. While the dead zones are created in both corners of the distributors, the perforated distributor generates more startup bubbles, heterogeneous flow field, and better gas–solid interaction above the entrance region due to jet formation. 相似文献
6.
本文以云杉八齿小蠹Ips typographus Linnaeus为例,经标本选取,观察虫体整体形态,绘制整体结构草图,电子显微镜观察局部、得到局部数字图像,分别建立虫体每一部分的高精度细节。把模型每部分拼装在一起组成整体模型,构建出了云杉八齿小蠹三维虚拟昆虫数字化模型。 相似文献
7.
《Advanced Powder Technology》2020,31(12):4598-4618
Simulation based on discrete element method (DEM) coupled with computational fluid dynamics (CFD), coupled DEM-CFD, is a powerful tool for investigating the details of dense particle–fluid interaction problems such as in fluidized beds and pneumatic conveyers. The addition of a mechanical vibration to a system can drastically alter the particle and fluid flows; however, their detailed mechanisms are not well understood. In this study, a DEM-CFD model based on a non-inertial frame of reference is developed to achieve a better understanding of the influence of vibration in a vibrated fluidized bed. Because the high computational cost of DEM-CFD calculations is still a major problem, an upscaled coarse-graining model is also employed. To realize similar behaviors with enlarged model particles, non-dimensional parameters at the particle scale were deduced from the governing equations. The suitability and limitations of the proposed model were examined for a density segregation problem of a binary system. To reduce the computational costs, we show that the ratio between the bed width and model particle size can be reduced to a minimum value of 100; to obtain similar segregation behaviors, the ratio between the bed height and model particle size is considered unchanged. 相似文献
8.
We propose all printed and highly stable organic resistive switching device (ORSD) based on graphene quantum dots (G-QDs) and polyvinylpyrrolidone (PVP) composite for non-volatile memory applications. It is fabricated by sandwiching G-QDs/PVP composite between top and bottom silver (Ag) electrodes on a flexible substrate polyethylene terephthalate (PET) at ambient conditions through a cost effective and eco-friendly electro-hydrodynamic (EHD) technique. Thickness of the active layer is measured around 97 nm. The proposed ORSD is fabricated in a 3 × 3 crossbar array. It operates switching between high resistance state (HRS) and low resistance state (LRS) with OFF/ON ratio ∼14 for more than 500 endurance cycles, and retention time for more than 30 days. The switching voltage for set/reset of the devices is ±1.8 V and the bendability down to 8 mm diameter for 1000 cycles are tested. The elemental composition and surface morphology are characterized by XPS, FE-SEM, and microscope. 相似文献
9.
《International Journal of Hydrogen Energy》2020,45(57):32856-32864
The electrode ionomer is a key factor that significantly affects the catalyst layer morphology and fuel cell performance. Herein, sulfonated poly(arylene ether sulfone)-based electrode ionomers with polymers of various molecular weights and alcohol/water mixtures were prepared, and those comprising the alcohol/water mixture showed a higher performance than the ones prepared using higher boiling solvents, such as dimethylacetamide; this is owing to the formation of the uniformly dispersed ionomer catalyst layer. The relation between ionomer molecular weight for the same polymer structure and the sulfonation degree was investigated. Because the chain length of polymer varies with molecular weight and chain entanglement degree, its molecular weight affects the electrode morphology. As the ionomer covered the catalyst, the agglomerates formed were of different morphologies according to their molecular weight, which could be deduced indirectly through dynamic light scattering and scanning electron microscopy. Additionally, the fuel cell performance was confirmed in the current-voltage curve. 相似文献
10.
Combination of X-ray Digital Industrial Radiography (DIR) and Particle Tracking Velocimetry (PTV) techniques for local liquid velocity measurement (VLL) has been newly developed and successfully applied for trickle bed reactor (TBR). The technique was validated against newly developed fiber optical probe technique. This work attempts to highlight the applicability of this newly developed technique on a liquid–solid packed bed reactor. In this work, liquid was represented by water and solids were represented by EPS beads. The EPS beads were chosen because of its low density property. Three superficial liquid velocities (VSL) were applied to the system. The experiment was replicated four times. The digital industrial radiography (DIR) consists of a complementary metal oxide semiconductor (CMOS) digital detector and X-ray source. Results of this work suggest that the technique has been successfully applied and comparable with previous work that has been done in the literature. It also suggests that there will be a maximum measurable interstitial liquid velocity when it travel inside the packed bed. The measured VLL can have a maximum range that is between 4 and 4.7 times that of its VSL. For VSL=0.42±±2%, the VLL-Max is in between 1.7 cm/s and 1.9 cm/s, VSL=0.84±±2%, the VLL-Max is in between 3.6 cm/s and 4.0 cm/s, and for VSL=1.11±±2%, the VLL-Max is in between 4.3 cm/s and 4.8 cm/s. 相似文献