A novel way to treat refractory waste: Sonication followed by wet oxidation (SONIWO)

The effectiveness of the hybrid system sonication followed by wet oxidation (SONIWO) to treat otherwise refractory waste has been demonstrated. In such a hybrid system homogeneous CuSO₄ catalyst was found to be very efficient.     

Kinetics of phenol oxidation in a trickle bed reactor over active carbon catalyst

The wet air oxidation of phenol over a commercial active carbon catalyst was studied in a trickle bed reactor (TBR) in the temperature and oxygen partial pressure ranges of 120–160 °C and 0.1–0.2 MPa, respectively. The performance of the active carbon was compared in terms of phenol and COD destruction. The weight change of active carbon due to reaction was also measured. Finally, oxic phenol adsorption isotherms were assessed in batch conditions at 25, 125 and 160 °C. In order to use the conversion data obtained from the TBR for a kinetic study, special care was taken to check the kinetic control in the TBR experiments. Several kinetic models including power law or Langmuir–Hinshelwood expressions were considered to describe the catalytic oxidation of phenol over active carbon. The simple power law model with first order dependence on both phenol and oxygen concentration predicted satisfactorily the experimental data not only over the entire range of operating conditions studied, but also outside its validity range. Copyright © 2005 Society of Chemical Industry     

湿法磷酸装置三废治理新进展

湿法磷酸装置排放的三废对环境危害较大 ,尤其是废水治理长期以来尚未得到全面控制。阐述了某新建的湿法磷酸装置从工艺流程上通盘考虑 ,采用多次串级利用 ,实现污水全封闭、零排放的流程 ,达到了由清到浊、由冷到热 ,多次利用、自身消化 ,实现平衡、避免污染的目的 ,并介绍了废气和废渣治理的新措施。指出应坚持精心操作和维护 ,巩固已取得的三废治理成果     

Impedance spectroscopy study of hardened Portland cement paste

In this paper, the differential impedance analysis (DIA) has been applied to the study of the dielectric properties of hardened Portland cement paste. Two time constants are found in the impedance spectra obtained in the frequency region form 100 kHz to 15 MHz. One time constant has been attributed to the solid matrix and the other one to the liquid phase filling the pores. The effect of the cement paste-electrodes interface has been quantified using two different experimental set-ups. Measurements using direct contact between electrodes and cement paste have been compared with measurements using an air gap technique in which the specimen “floats” between the electrodes. The two referred time constants have been found in both types of measurements. The influence of drying on the dielectric parameters is also studied.     

2010年长江流域暴雨洪水初步分析

分析2010年长江流域暴雨洪水,有利于更全面认识长江流域暴雨洪水特性,可为今后更好开展长江流域防汛水情保障工程。从主汛期长江流域暴雨及气候特征、干支流主要洪水过程及洪水特性等方面,进行了初步的总结和分析。2010年长江主汛期洪水发生范围广、持续时间长且局部地区洪水量级大,通过与三峡水库蓄水前后几次大的历史洪水分析对比,初步认为,2010年长江流域主汛期出现的洪水为长江上中游区域性较大洪水。     

The rim zone of cement-based materials – Barrier or fast lane for chemical degradation?

Sophisticated evaluation models for the long-term stability of cement-based systems demand a precise knowledge of the mechanisms of deterioration reactions, particularly respecting a permanent exposure to aqueous environments. Commonly, insights into these mechanisms are deduced from long-term investigations. However, these chemical reactions start immediately after exposure to aggressive environments causing rapid changes of composition and structure. Consequently, properties of its rim zone change, which affects transport processes in aqueous solutions. In laboratory experiments, the influence of these surface processes on the stability of cement-based materials exposed to different chloride solutions was studied as a function of time and temperature. Analysis of compositional and structural changes beneath the surface reveal the role of crystalline covering layers for chemical resistance. Such layers are often described as protective barriers. However, these processes in the rim zone can accelerate chemical degradation and subsequently reduce the resilience of the cement-based materials to aggressive aqueous environments.     

湿法相分离不对称超滤膜形成机理

本文选择了憎水的极怀非普质子性聚砜和亲水的极性质子怀聚砜酰胺两种膜材料，从铸膜液组成和凝胶过程两方面，用气相色谱和高效液相色谱研究了表征膜材料－溶剂－添加剂－水作用力的混合自由焓，平衡分配常数，及其与膜性能，不同溶剂特性粘度，雾点值和溶解度参数的关系，提出了铸膜液中有机溶剂的作用机理，及不对称超滤膜形成的一些规律。     

Effect of polycarboxylate-type superplasticizer on the paste fluidity based on the water film thickness of flocs

The excess water film theory and the properties of flocs are integrated to examine the effect of the polycarboxylate-type superplasticizer on the paste fluidity.The theory states that excess water can surround the flocs rather than the particles and that the cell consists of a floc and a superficial water film.Experiments on limestone powder pastes were conducted to verify the theory.The superplasticizer dosage(sp%)and the water–powder ratio by volume(Vw/Vp)were systematically varied.A sedimentation balance method was used to measure the size distribution of the flocs in the limestone powder pastes.The water film thickness(WFT)of flocs was then calculated and shown to determine the paste fluidity.Based on this WFT of flocs,the effect of the sp on the paste fluidity was determined and then compared with the effect of water.     

相似点区段负责制的改进区域生长法及其应用

区域生长法被广泛应用于对特定目标的选取,但其生长速度缓慢的特点又限制了其在某些领域的应用.为此,提出一种基于相似点区段负责制的像素点进出堆栈管理方法,有效的提高了区域生长的效率.在此基础上,结合链码法边界跟踪对生长过程中区域内部出现的孔洞实现区域补偿,建立了针对链状藻细胞分析统计的有效应用系统.