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Alena Yarysheva Dmitry Strel'tsov Sergey Malakhov Olga Arzhakova Larisa Yarysheva Alexandr Volynskii 《Polymer International》2020,69(7):627-634
This work addresses the phenomenon of the development of a patterned surface relief on polymer films via different modes of environmental crazing. Commercial films of semicrystalline poly(tetrafluoroethylene) (PTFE) and amorphous glassy poly(ethylene terephthalate) (PET) were subjected to tensile drawing in the presence of physically active liquid environments (carbon tetrachloride or aliphatic alcohols). The structure parameters and wettability of the modified films were studied by AFM, SEM, profilometer measurements and contact angle measurements. Environmental intercrystallite crazing of PTFE is accompanied by the development of an unstable structure with a high free surface, which experiences marked strain recovery upon unloading. As a result of the relief formation, PTFE hydrophobicity is enhanced (the water contact angle increases by 25°). Classical environmental crazing of PET films is accompanied by the formation of an anisotropic surface relief which is an assembly of crazes oriented perpendicular to the direction of tensile drawing, thus leading to the phenomenon of anisotropic wetting. The proposed approach for structural surface modification makes it possible to use the advantages of surface instability and spontaneous self‐organization of the polymer towards the development of a unique surface microrelief. © 2020 Society of Chemical Industry 相似文献
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《International Journal of Hydrogen Energy》2021,46(69):34356-34361
This study investigates the ability of hydrogen (H2) to wet clay surfaces in the presence of brine, with implications for underground hydrogen storage in clay-containing reservoirs. Rather than measuring contact angles directly with hydrogen gas, a suite of other gases (carbon dioxide (CO2), argon (Ar), nitrogen (N2), and helium (He)) were employed in the gas-brine-clay system under storage conditions (moderate temperature (333 K) and high pressures (5, 10, 15, and 20 MPa)), characteristic of a subsurface environment with a shallow geothermal gradient. By virtue of analogies to H2 and empirical correlations, wettabilities of hydrogen on three clay surfaces were mathematically derived and interpreted. The three clays were kaolinite, illite, and montmorillonite and represent 1:1, 2:1 non-expansive, and 2:1 expansive clay groups, respectively. All clays showed water-wetting behaviour with contact angles below 40° under all experimental set-ups. It follows that the presence of clays in the reservoir (or caprock) is conducive to capillary and/or residual trapping of the gas. Another positive inference is that any tested gas, particularly nitrogen, is suitable as cushion gas to maintain formation pressure during hydrogen storage because they all turned out to be more gas-wetting than hydrogen on the clay surfaces; this allows easier displacement and/or retrieval of hydrogen during injection/production. One downside of the predominant water wettability of the clays is the upstaged role of biogeochemical reactions at the wetted brine-clay/silicate interface and their potential to affect porosity and permeability. Water-wetting decreased from kaolinite as most water-wetting clay over illite to montmorillonite as most hydrogen-wetting clay. Their wetting behaviour is consistent with molecular dynamic modelling that establishes that the accessible basal plane of kaolinite's octahedral sheet is highly hydrophilic and enables strong hydrogen bonds whereas the same octahedral sheet in illite and montmorillonite is not accessible to the brine, rendering these clays less water-wetting. 相似文献
4.
高温酸化助排剂HC2-1的研究 总被引:12,自引:2,他引:10
为了满足高温油藏和深井酸化作业残酸返排的需要,通过表面活性剂的筛选和复配研究,得到了高温酸化助排剂HC2—1。其性能评价结果表明,HC2—1具有使用浓度低、表面活性高的特点,在20%的HCI溶液中,当其浓度为50mg/L时,表面张力为20.7mN/m;具有良好的耐温性能,在180℃下恒温48h,HC2—1仍保持较高的表面活性;具有良好的耐盐能力,加有HC2—1的20%HCl溶液和CaCO3反应至HCl完全消耗,整个反应过程体系无新相生成且表面张力基本不变;可增大酸液体系的润湿角,进一步降低毛细管阻力,使酸液返排率由46%提高到97%,在促进酸液返排的同时与原油不发生乳化反应。 相似文献
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M.E. Enyiegbulam 《International Journal of Adhesion and Adhesives》1985,5(4):207-210
Increased wetting of the coupling agent/epoxy resin interface was observed when γ-glycidoxypropyltrimethoxysilane, polyfunctional aminosilane and γ-aminopropyltriethoxysilane were applied respectively from methyllethylketone, dimethylformamide and water on woven glass cloths which had been cleaned at 300°C. However, when factory-applied coupling agents were burnt off the woven cloths and fresh coupling agents re-applied, it was found that the nature of the factory-applied coupling agent influenced subsequent wetting. Thinner glass fibres showed a greater improvement in wetting rate than thicker fibres in those solvents identified to be good for improved wettability, irrespective of the heat-cleaning temperature. 相似文献
7.
Titanium Dioxide, TiO2, is a photocatalyst with a unique characteristic. A surface coated with TiO2 exhibits an extremely high affinity for water when exposed to UV light and the contact angle decreases nearly to zero. Inversely, the contact angle increases when the surface is shielded from UV. This superhydrophilic nature gives a self-cleaning effect to the coated surface and has already been applied to some construction materials, car coatings and so on. We applied this property to the enhancement of boiling heat transfer. An experiment involving the pool boiling of pure water has been performed to make clear the effect of high wettability on heat transfer characteristics. The heat transfer surface is a vertical copper cylinder of 17 mm in diameter and the measurement has been done at saturated temperature and in a steady state. Both TiO2-coated and non-coated surfaces were used for comparison. In the case of the TiO2-coated surface, it is exposed to UV light for a few hours before experiment and it is found that the maximum heat flux (CHF) is about two times larger than that of the uncoated surface. The temperature at minimum heat flux (MHF) for the superhydrophilic surface is higher by 100 K than that for the normal one. The superhydrophilic surface can be an ideal heat transfer surface. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
8.
A test has been devised that allows one to determine the work of adhesion and wettability in a system composed of aluminum nitride ceramics with a liquid metal without the need for experimental examination. A correlation is examined between the work of adhesion on the one hand and that criteria or others on the other that have been proposed by various researchers. Forecasts are made for the work of adhesion and wetting angle for a series of metals that have not been examined previously. An experimental check has been made on the forecast adhesion activity for some elements. 相似文献
9.
聚丙烯共混表面改性剂的研究 总被引:5,自引:0,他引:5
由不同链长的甲基丙烯酸长链醇酯。少量改性剂与聚丙烯共混,能大幅增加聚丙烯表面润湿性与粘接性,而拉伸强度与熔点却变化不大。通过ESCA与接触角分析,发现极性基团大表面富集,添加不同改性剂使材料表面富集的极性基浓度与粘接强度产生差异。 相似文献
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