某油田油井采出水腐蚀因素研究

我国油田油井生产中采油井管柱腐蚀现象十分普遍,所以在注CO_2驱进行开采过程中要进行采出水的质量分析。对现阶段的油田生产腐蚀及防腐技术进行论述,提出相对应的防腐措施,进一步为油田生产作业提高产量。     

Inorganic–organic hybrid materials with zirconium oxoclusters as protective coatings on aluminium alloys

Inorganic–organic hybrid materials are attracting a strong scientific interest mainly for their outstanding inherent mechanical and thermal properties, which can be traced back to the intimate coupling of both inorganic and organic components. By carefully choosing the experimental parameters used for their synthesis, chemically and thermally stable acrylate-based hybrid material embedding the zirconium oxocluster Zr₄O₄(OMc)₁₂, where OMcCH₂C(CH₃)C(O)O, can be deposited as UV-cured films on aluminium alloys.

In particular, the molar ratios between the oxocluster and the monomer, the polymerisation time, the amount of photo-initiator and the deposition conditions, by using an home-made spray-coating equipment, were optimised in order to obtain the best performing layers in terms of transparency and hardness to coat aluminium alloy (AA1050, AA6060 and AA2024) sheets. Furthermore, it was also evaluated whether the hybrid coatings behave as barrier to corrosion.

Several coated samples were prepared and characterised. Environmental scanning electronic microscopy (ESEM) and scratch test were used to investigate the morphology of the films and to evaluate their scratch resistance, respectively. Electrochemical impedance spectroscopy (EIS) was performed in order to evaluate if the coatings actually protect the metallic substrate from corrosion.

In order to measure shear storage modulus (G′) and loss modulus (G″) of the materials used for coatings, bulk samples were also obtained by UV-curing of the precursors solution. Dynamical mechanical thermal analysis (DMTA) was performed in shear mode on cured disks of both the hybrid materials and pristine polymer for comparison. The values of T_g were read off as the temperatures of peak of loss modulus. The length and mass of all the samples were measured before and after the DMTA analysis, so that the shrinkage of the materials in that temperature range was exactly evaluated.     

200kt／a蒸馏装置硫腐蚀典型事例分析

通过对200kt/a蒸馏装置几起硫腐蚀典型事例的分析,提出了改进措施,消除了腐蚀泄漏隐患,确保了装置安全、平稳、长周期运行。     

聚苯硫醚的性能及在防腐蚀涂层上的应用

较详细地介绍了聚苯硫醚(PPS)的性能、发展概况及在防腐蚀领域的应用前景。根据实践经验叙述了PPS的喷涂工艺，总结分析了影响PPS涂层施工质量的主要因素及解决办法。     

管道三层结构聚烯烃防腐蚀技术及应用现状

介绍了管道三层结构聚烯烃外防护技术的基本特点和技术要求，以及该技术在目前的应用情况。输气管道对耐蚀材料的需求量巨大，开发配套的粉末涂料和性能更好的改性聚烯烃树脂，是涂料市场新的增长点。     

镍对热镀锌耐蚀性的影响

对Q235和Q345两种材料表面热浸镀纯Zn和Zn－Ni合金，研究Ni对热镀锌耐蚀性的影响。采用中性盐雾试验对镀层耐蚀性测试，将纯Zn镀层和Zn-Ni合金镀层进行对比，并用电子天平称量试样重量变化。结果表明Zn－Ni合金镀层比纯Zn镀层更耐腐蚀。     

新型钢筋阻锈剂的合成及其阻锈性能的研究

合成了一种舍有氨基和菝基的有机阻锈刑，并用硬化砂浆法研究了该阻锈剂在砂浆中含有氯离子的条件下对钢筋锈蚀的抑制作用，同时与常用的亚硝酸盐的阻锈效果进行了比较。结果表明，该新型阻锈剂能够有效地阻止钢筋表面钝化膜的破坏，比亚硝酸盐具有更好的阻锈效果。     

Durable,self-cleaning and superhydrophobic bamboo timber surfaces based on TiO2 films combined with fluoroalkylsilane

Decorative materials, including bamboo timber, have been proposed to exploit their superhydrophobic and self-cleaning properties, but a comprehensive appraisal of their environmental adaptability is still deficient. In this paper, a robust and durable superhydrophobic surface was formed on bamboo timber substrate through a process combining chemical solution deposition and chemical modification. The superhydrophobic surface resulted from micro-nanoscale binary-structured TiO₂ films and the assembly of low-surface-energy fluorinated components, which exhibited a water contact angle of 163±1° and a sliding angle of 3±1°. The surface maintained superhydrophobicity after mechanical abrasion against 1500 mesh SiC sandpaper for 800 mm at the applied pressure of 1.2 kPa, indicating good mechanical stability. Moreover, the superhydrophobic surface exhibited good chemical stability against both acidic and basic aqueous solutions (e.g., simulated acid rain). After exposure to atmosphere for more than 180 days, the obtained surface still maintained a contact angle of 155±2° and a sliding angle of 6±2°, revealing good long-term stability. In addition, the as-prepared superhydrophobic surface exhibited almost complete wet self-cleaning of dirt particles with water droplets. It is believed that the method presented in this study can provide a straightforward and effective route to fabricate a large-area, mechanically robust, anticorrosive and self-cleaning superhydrophobic surface on woody materials for a great number of potential applications.     

杜巴油腐蚀原因分析及防腐蚀对策

对原油中掺炼杜巴油后装置腐蚀情况进行了腐蚀原因分析,总结了存在问题,提出了改进措施。     

有色冶金电解槽的腐蚀与防护

电解槽是有色冶金的关键设备之一,目前较多地采用了玻璃钢衬里的防腐蚀手段。该文由铜、镍等精炼工艺的实际腐蚀介质出发,从防腐蚀树脂选材、新型乙烯基酯树脂性能、工程质量控制等方面介绍了金川公司电解槽的腐蚀防护工程及实施情况。