Design of Ti4+-doped Li3V2(PO4)3/C fibers for lithium energy storage

In this work, we propose a facile approach to fabricate Ti⁴⁺-doped Li₃V₂(PO₄)₃/C (abbreviated as C-LVTP) nanofibers using an electrospinning route followed by a high temperature treatment. In this designed nanocomposite, the ultrafine LVTP dots are homogeneously dispersed into one-dimensional carbon nanofibers and the Ti⁴⁺ doping does not destroy the crystal structure of monoclinic Li₃V₂(PO₄)₃. Compared to the undoped Li₃V₂(PO₄)₃/C (abbreviated as C-LVP), the as-fabricated C-LVTP fibers present higher reversible capacity, superior high-rate capability as well as better cyclic property. Especially, the C-LVT_7%P cathode delivers not only high capacities of 187.2 and 160.3 mAh g^?1 at 0.5 and 10 C respectively, but also stable cyclic property with the reversible capacity of 135.8 mAh g^?1 at 20 C following 500-cycle spans. The good battery characteristics of C-LVT_7%P can be mainly ascribed to Ti⁴⁺ doping, which can increase the electrical conductivity and Li⁺ diffusion coefficient.     

A new numerical algorithm to check the observability and bad-data processing ability of the metering scheme

This paper provides a unified approach for the optimization of measurements placements employed for power system online monitoring through state estimation. The proposed methodology, which can be suitable for the mixed measure system, preserves state estimation observability and bad-data processing capability by employing numerical algorithms for observability checking, critical measurements and critical couple identification. First, node injection radix measurements and measurement categories are defined. According to the above definitions, the coefficient matrix can be solved. The analysis on the column vectors of the coefficient matrix can determine each measurement classification. Furthermore, the numbers of each measurement class contains can determine bad-data processing capability. The observability can be checked by the type number of measurements. The proposed method is illustrated with the IEEE39-bus system and the IEEE118-bus system. Results from the case studies are presented to demonstrate that the approach adequately fulfills the desired properties related to observability, bad-data processing, cost, and robustness.     

Unique CNTs-chained Li4Ti5O12 nanoparticles as excellent high rate anode materials for Li-ion capacitors

Composite anode materials with a unique architecture of carbon nanotubes (CNTs)-chained spinel lithium titanate (Li₄Ti₅O₁₂, LTO) nanoparticles are prepared for lithium ion capacitors (LICs). The CNTs networks derived from commercial conductive slurry not only bring out a steric hindrance effect to restrict the growth of Li₄Ti₅O₁₂ particles but greatly enhance the electronic conductivity of the CNTs/LTO composites, both have contributed to the excellent rate capability and cycle stability. The capacity retention at 30 C (1 C = 175 mA g^?1) is as high as 89.7% of that at 0.2 C with a CNTs content of 11 wt%. Meanwhile, there is not any capacity degradation after 500 cycles at 5 C. The LIC assembled with activated carbon (AC) cathode and such a CNTs/LTO composite anode displays excellent energy storage properties, including a high energy density of 35 Wh kg^?1 at 7434 W kg^?1, and a high capacity retention of 87.8% after 2200 cycles at 1 A g^?1. These electrochemical performances outperform the reported data achieved on other LTO anode-based LICs. Considering the facile and scalable preparation process proposed herein, the CNTs/LTO composites can be very potential anode materials for hybrid capacitors towards high power-energy outputs.     

某油田油井采出水腐蚀因素研究

我国油田油井生产中采油井管柱腐蚀现象十分普遍,所以在注CO_2驱进行开采过程中要进行采出水的质量分析。对现阶段的油田生产腐蚀及防腐技术进行论述,提出相对应的防腐措施,进一步为油田生产作业提高产量。     

协同作战能力简析

协同作战能力(CEC)是一种充分利用网络技术的新型海岸防空技术，给系统的作战能力带来了革命性的交破。本文对协同作战能力的产生、功能、组成以及未来的发展趋势作了详细的介绍，阐述了CEC系统的总体设计思想。在此基础上，将CEC系统与传统的作战系统的性能和设计思想在各方面进行了比较，交出了CEC系统各方面的优越性能。协同作战能力是现代和未来作战系统的发展方向，CEC系统的发展必将成为衡量各国国防科技现代化的重要指标。     

现代电子工业Cpk评价中的特殊问题

现代电子工业生产具有许多新的特点，如果不针对具体情况，均采用传统工业生产中广泛使用的常规方法计算其工序能力指数，评价生产工艺水平，将可能导致错误的结论。总结了电子工业生产中工艺参数的典型特点，并讨论了工序能力指数的正确计算方法。     

绝缘涂敷制件的加工工艺研究与应用

主要论述了电工绝缘粉末的性能及其在高压电器设备应用中的有关试验项目。     

对成油体系临界时刻的思考

在分析Magoon和Dow对临界时刻研究的基础上 ,从事件持续时间的长短对油气最终生成的影响这一角度 ,通过对成油体系中各事件发生的过程进行分析 ,指出原成油体系事件分析图表的不合理之处 ;建立成油体系临界时刻分析模型 ,探索临界时刻定量评价的方法以及方法在油气潜力评估中的应用意义     

Inorganic–organic hybrid materials with zirconium oxoclusters as protective coatings on aluminium alloys

Inorganic–organic hybrid materials are attracting a strong scientific interest mainly for their outstanding inherent mechanical and thermal properties, which can be traced back to the intimate coupling of both inorganic and organic components. By carefully choosing the experimental parameters used for their synthesis, chemically and thermally stable acrylate-based hybrid material embedding the zirconium oxocluster Zr₄O₄(OMc)₁₂, where OMcCH₂C(CH₃)C(O)O, can be deposited as UV-cured films on aluminium alloys.

In particular, the molar ratios between the oxocluster and the monomer, the polymerisation time, the amount of photo-initiator and the deposition conditions, by using an home-made spray-coating equipment, were optimised in order to obtain the best performing layers in terms of transparency and hardness to coat aluminium alloy (AA1050, AA6060 and AA2024) sheets. Furthermore, it was also evaluated whether the hybrid coatings behave as barrier to corrosion.

Several coated samples were prepared and characterised. Environmental scanning electronic microscopy (ESEM) and scratch test were used to investigate the morphology of the films and to evaluate their scratch resistance, respectively. Electrochemical impedance spectroscopy (EIS) was performed in order to evaluate if the coatings actually protect the metallic substrate from corrosion.

In order to measure shear storage modulus (G′) and loss modulus (G″) of the materials used for coatings, bulk samples were also obtained by UV-curing of the precursors solution. Dynamical mechanical thermal analysis (DMTA) was performed in shear mode on cured disks of both the hybrid materials and pristine polymer for comparison. The values of T_g were read off as the temperatures of peak of loss modulus. The length and mass of all the samples were measured before and after the DMTA analysis, so that the shrinkage of the materials in that temperature range was exactly evaluated.     

Dynamic Multicast Session Provisioning in WDM Optical Networks with Sparse Splitting Capability

In this work, we study dynamic provisioning of multicast sessions in a wavelength-routed sparse splitting capable WDM network with an arbitrary mesh topology where the network consists of nodes with full, partial, or no wavelength conversion capabilities and a node can be a tap-and-continue (TaC) node or a splitting and delivery (SaD) node. The objectives are to minimize the network resources in terms of wavelength-links used by each session and to reduce the multicast session blocking probability. The problem is to route the multicast session from each source to the members of every multicast session, and to assign an appropriate wavelength to each link used by the session. We propose an efficient online algorithm for dynamic multicast session provisioning. To evaluate the proposed algorithm, we apply the integer linear programming (ILP) optimization tool on a per multicast session basis to solve off-line the optimal routing and wavelength assignment given a multicast session and the current network topology as well as its residual network resource information. We formulate the per session multicast routing and wavelength assignment problem as an ILP. With this ILP formulation, the multicast session blocking probability or success probability can then be estimated based on solving a series of ILPs off-line. We have evaluated the effectiveness of the proposed online algorithm via simulation in terms of session blocking probability and network resources used by a session. Simulation results indicate that our proposed computationally efficient online algorithm performs well even when a fraction of the nodes are SaD nodes.