不饱和酸结构对不饱和聚酯树脂固化行为的影响

通过IR分析了用顺酐和反酸与聚酯合成不饱和聚酯树脂的反应机理,讨论了二种树脂体系固化放热曲线不同的原因。     

水处理容器缠绕不饱和聚酯体系研究

研究了水处理容器缠绕不饱和聚酯树脂体系 ,重点阐述了不饱和聚酯凝胶期控制、表干及树脂增韧方法和纤维缠绕复合层的力学性能 ,分析了水容器受压树脂环向开裂的原因 ,探讨了提高树脂开裂强度的措施     

纳米TiO2/UPR复合体系的固化动力学及固化工艺研究

采用动态差示扫描量热法（DSC）对纳米TiO2／UPR复合体系的固化过程进行研究,得出不同升温速率下纳米TiO2／UPR复合体系固化过程中的DSC曲线;并根据动态DSC曲线求出固化反应的表观活化能、固化反应级数及动力学方程中的指前因子等参数;建立了复合体系固化反应动力学的数学模型并且确定了分阶段变温固化新工艺。     

A proteomic analysis of green and white sturgeon larvae exposed to heat stress and selenium

Temperature and selenium are two environmental parameters that potentially affect reproduction and stock recruitment of sturgeon in the San Francisco Bay/Delta Estuary. To identify proteins whose expression is modified by these environmental stressors, we performed a proteomic analysis on larval green and white sturgeons exposed to 18 or 26 °C and micro-injected with Seleno-L-Methionine to reach 8 µg g⁻¹ selenium body burden, with L-Methionine as a control. Selenium and high temperature induced mortalities and abnormal morphologies in both species, with a higher mortality in green sturgeon. Larval proteins were separated by two-dimensional gel electrophoresis and differential abundances were detected following spot quantitation and hierarchical cluster analysis. In green sturgeon, 34 of 551 protein spots detected on gels showed a variation in abundance whereas in white sturgeon only 9 of 580 protein spots were differentially expressed (P < 0.01). Gel replicates were first grouped according to heat treatment. Fifteen of these spots were identified using MALDI TOF/TOF mass spectrometry. Proteins involved in protein folding, protein synthesis, protein degradation, ATP supply and structural proteins changed in abundance in response to heat and/or selenium. 40S ribosomal protein SA, FK506-binding protein 10, 65 kDa regulatory subunit A of protein phosphatase 2, protein disulfide isomerase, stress-induced-phosphoprotein 1, suppression of tumorigenicity 13 and collagen type II alpha 1, were differentially expressed in high temperature treatment only. Serine/arginine repetitive matrix protein 1, creatine kinase, serine peptidase inhibitor Kazal type 5 and HSP90 were sensitive to combined temperature and selenium exposure. Valosin-containing protein, a protein involved in aggresome formation and in protein quality control decreased more than 50% in response to selenium treatment. Potential use of such proteins as biomarkers of environmental stressors in larval sturgeons could indicate early warning signals preceding population decline.     

UPR100弧焊机器人轨迹规划

对UPR100弧焊机器人进行了基于运动学的轨迹规划与仿真。采用D-H法建立了UPR100弧焊机器人运动学方程,运用Matlab编程实现了正、逆运动学求解,并利用正、逆运动学进行了轨迹规划。通过Matlab工具箱Sim Mechinics建立了UPR100弧焊机器人三维模型,并将轨迹规划仿真数据与理论数据进行比较,验证了轨迹规划的合理性与仿真模型的正确性,为UPR100弧焊机器人下一步的动力学研究与轨迹跟踪控制器设计奠定了理论基础。     

纳米SiOx改性不饱和聚酯树脂

用纳米SiOx粒子对298#不饱和聚脂(UPR)进行增强、增韧改性，发现随粒子用量增加，树脂凝胶时间、粘度增大；粒子用量为0．5％时树脂有脆韧转变现象；用量为3％时，拉伸强度和断裂延伸率分别提高约33％和60％。用KH-570偶联剂进行表面处理有助于提高纳米SiOx粒子在UPR中的均匀分散。     

2010-2011年国际不饱和聚酯树脂工业进展

介绍了2010-2011年国际原油市场、不饱和聚酯部分项目投产及企业并购情况。综述了UPR领域的研究及应用进展,包括UPR的改性、力学性能的改进、老化机理、生物复合材料、新型不饱和聚酯复合材料及其应用。     

2011-2012年世界不饱和聚酯树脂工业进展

介绍了2011-2012年国外不饱和聚酯原料市场动态,国外企业运营情况。综述了不饱和聚酯树脂领域的研究及应用进展,涉及不饱和聚酯树脂及其复合材料的电性能、收缩性能、力学性能、生物复合材料、表面处理、阻燃性能及环保等。     

不饱和聚酯型人造石英石的紫外老化研究

对不饱和聚酯树脂粘合的人造石英石板材进行了人工紫外加速老化试验,通过显微观察其表面形态,比较色差值,并采用红外谱图分析,研究石英石板材的紫外老化情况。试验结果表明,四种类型的不饱和聚酯树脂石英石在经过500h紫外照射后,表层都会出现不同程度的粉化现象。而FTIR谱图显示,树脂并没有出现明显的链降解,石英石板面的粉化应是石英粉与树脂的接合面在老化试验中发生分离,导致石英粉脱落。