岩石样品中铷的中子活化分析

研究了苦味酸溶液的ｐＨ变化对用１８－Ｃ－６（１８Ｃ６）的硝基苯溶液定量萃取Ｒｂ的影响及１８Ｃ６浓度变化对定量萃取Ｒｂ的影响，确定了定量反萃Ｒｂ的实验条件。作出了磷酸锆无机离子交换柱上的Ｒｂ－Ｃｓ分离曲线。测定了岩石样品的微量Ｒｂ和痕量＾８４Ｒｂ。     

汽轮机自带冠导叶片精铸工艺实践

介绍了自带冠导叶片精铸工艺方案 ,分析了存在的问题。     

Wavelet transform applied to EO-1 hyperspectral data for forest LAI and crown closure mapping

A comparison of the performance of three feature extraction methods was made for mapping forest crown closure (CC) and leaf area index (LAI) with EO-1 Hyperion data. The methods are band selection (SB), principal component analysis (PCA) and wavelet transform (WT). Hyperion data were acquired on October 9, 2001. A total of 38 field measurements of CC and LAI were collected on August 10-11, 2001, at Blodgett Forest Research Station, University of California at Berkeley, USA. The analysis method consists of (1) conducting atmospheric correction with High Accuracy Atmospheric Correction for Hyperspectral Data (HATCH) to retrieve surface reflectance, (2) extracting features with the three methods: SB, PCA and WT, (3) establishing multivariate regression prediction models, (4) predicting and mapping pixel-based CC and LAI values, and (5) validating the CC and LAI mapped results with photo-interpreted CC and LAI values. The experimental results indicate that the energy features extracted by the WT method are the most effective for mapping forest CC and LAI (mapped accuracy (MA) for CC=84.90%, LAI MA=75.39%), followed by the PCA method (CC MA=77.42%, LAI MA=52.36%). The SB method performed the worst (CC MA=57.77%, LAI MA=50.87%).     

Conformational Study of the Structure of dibenzo-18-crown-6. Comparison with 18-crown-6

We report for the first time the conformational analysis of dibenzo-18-crown-6, db18c6. The conformational search was carried out using the CONFLEX conformational search method of cyclic molecules. Energies were calculated for the low-lying predicted conformations at different levels of theory up to the G3MP2 level. At the G3MP2 level, the predicted ground state (GS) conformation was more stable than the experimental conformation by only 1.60 kcal/mol. Strong similarity was found between the GS structure and experimental conformations of db18c6 and 18-crown-6, 18c6. The GS and experimental conformations of db18c6 are non-planar. This allows db18c6 to exist in optically active enantiomers. Similar to 18c6, it was concluded that the db18c6 structure is stabilized by intramolecular hydrogen bond. We also performed the computations for the water and chloroform solution phase, where the same conformation was predicted as the GS conformation.     

Crown ethers appended copper tetraazamacrocyclic complexes as receptors for cationic guests

Tetraazamacrocyclic copper(II) complexes linked by the system of conjugated double bonds with one or two benzo-15-crown-5 ether moieties (4Cu and 5Cu) as well as model compounds were synthesized and characterized. The CV of these complexes in acetonitrile (ACN) solution exhibited reversible Cu^II/I redox process. Complexation of Na⁺ and Mg²⁺ cations with 5Cu in the gas phase was confirmed by electrospray mass spectrometry. In solution complexation of Li⁺ and Na⁺ with 5Cu was weak. Complexation of Cl⁻ anion to coordinated copper in 5Cu resulted in an appreciable shift in the Cu^II/I redox potential after addition of studied cations. The addition of increasing amounts of Mg²⁺ cation to the solution of 5Cu resulted in a significant shift of the Cu^II/I reduction process accompanied by further reduction to Cu⁰ followed by replacement of copper by Mg²⁺ cation. Barium(II) cation interacted only with reduced (Cu⁺) form of 5Cu.     

Azacrown Ethers with Naphthyl Branches. Fluorescence Properties,Protonation and Metal Coordination

Starting from 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, we have prepared two compounds by replacing the amine hydrogens with naphthyl or 3,5-bis(2′-oxymethylnaphthyl)benzyl units. The absorption and emission spectra of compounds 2 (N,N′-bis(2-naphthylmethyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane) and 3 (N,N′-bis[3,5-bis(2′-oxymethylnaphthyl)benzyl]-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane) have been studied in CH₃CN:CH₂Cl₂ 1:1 (v/v) solution. For comparison purposes, the spectroscopic properties of N-methyl(2-methylnaphthalene)ethylamine (1) have also been investigated. For each compound, the absorption spectra are qualitatively very similar to that of naphthalene, with molar absorption coefficients as expected for the presence of one (1), two (2), and four (3) naphthyl chromophoric groups. The fluorescence spectra, however, are quite different from that of naphthalene. The naphthalene-type fluorescence (λ_max = 337 nm) is strongly quenched, particularly for compounds 1 and 2 which also exhibit a broad emission band in the visible region (λ_max ≈ 480 nm) assigned to a low lying charge-transfer excited state. In the case of compound 3, a quenched naphthalene-type band is accompanied by weak exciplex and excimer emissions. Upon titration with CF₃SO₃H, the charge transfer bands of 1 and 2 and the exciplex emission of 3 disappear and the naphthalene-type bands regain intensity. Titration plots show that in compounds 2 and 3 the protonation of the two nitrogens occurs stoichiometrically in two distinct steps. Titration with Zn²⁺ gives rise to 2.Zn²⁺ and 3.Zn²⁺ complexes. This article is dedicated to Professor Dedier Astruc.     

Optimal tree design for daylighting in residential buildings

Urban reforestation is advocated as an efficient countermeasure to the intensification of urban heat islands. The greening and beautification of residential quarters is one of the main concerns of residents, while lighting and ventilation are two main energy-consuming building services. Hence, the tree layout in green space between buildings is important, and it is necessary to determine the relationships between trees and buildings. This study takes Shanghai as a case study to optimize tree design between residential buildings and meet good daylighting requirements. Models were made using software such as AutoCAD and SketchUp. The relationships between maximum tree height and building separation were determined. For the same building layout, there were different tree height limits according to crown shape; the order of decreasing height limits was cylindrical, conical, spherical, and inverted conical crowns. Three cases having different green space between building layouts were studied. Their maximum tree heights differed. Overall, our model helps us realize good daylighting of a building environment. The formula allows us to determine which trees to plant between buildings in that we can predict the effects of future tree growth on building daylighting.     

冠醚液晶/PVC二元复合膜的温控离子渗透作用(英文)

冠醚液晶具有液晶的有序性和冠醚络合金属离子的特性,采用单臂冠醚液晶成功地用粒模拟生物膜的离子传输,首次提出了冠醚液晶和PVC的二元复合膜,这种新的仿生膜模型种巧妙地模拟生物膜的温控传输,能更充分发挥膜传输中液晶的基本功能。因此,提出了冠醚液晶分子在液晶志时能自组装成离子通道传输离子。     

一种移除所有皇冠的扩展NT算法

皇冠分解和NT算法长久以来被认V1为是在参数化点覆盖的求核问题中有着广泛应用的两种相互独立的方法。NT算法将给定的图分成V2,V1和V1／2三部分,将砜和V1移除从而完成图的分解。而皇冠分解则是找到尽可能多的皇冠结构,删除这些皇冠以降低图规模。最近的研究结果表明NT算法和皇冠分解存在很强的内在联系：NT算法中的砜,V1部分正好构成一个皇冠结构。本文进一步研究了皇冠分解和NT算法的内在联系,提出了严格皇冠和非严格皇冠的概念,提出了一般图中存在皇冠的判定定理,证明了NT算法可以移除一般图中存在的所有严格皇冠。论文还提出了一种扩展NT算法,能够移除图中的所有严格和非严格皇冠,即证明了用扩展NT算法处理过的图中将不会存在任何皇冠结构。