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排序方式: 共有407条查询结果,搜索用时 31 毫秒
1.
在固定床反应器中研究了新型脱氯剂与脱氯剂T411 Q对HCl气体的吸附行为,考察了不同实验条件对脱氯剂穿透氯容的影响。结果表明,新型脱氯剂在300~550℃时都可将气体所含HCl体积分数脱除至1.0×10-6以下;气体所含HCl体积分数在(1.0~2.0)×10-3间变化时,对其脱氯能力影响不大;脱氯剂粒径越小其穿透氯容越大;空速增大,穿透氯容呈下降趋势,但在空速为1 000~3 000 h-1的条件下,其穿透氯容的变化不显著;在450℃,空速为2 500 h-1,HCl体积分数为2.0×10-3时,新型脱氯剂的穿透氯容比T411 Q的高24%~40%。通过对固定床脱氯行为的简化处理,得出新型脱氯剂与气体HC1反应的床层氯容分布方程,根据该方程可以预测不同时刻、不同床层深度处钙基高温脱氯剂的穿透氯容。 相似文献
2.
F. La Via G. Galvagno F. Giannazzo A. Ruggiero L. Calcagno M. Mauceri G. Pistone G. Abbondanza A. Veneroni L. Zamolo G.L. Valente 《Microelectronic Engineering》2006,83(1):48-50
The results of a new epitaxial process using an industrial 6 × 2″ wafer reactor with the introduction of HCl during the growth have been reported. A complete reduction of silicon nucleation in the gas phase has been observed even for high silicon dilution parameters (Si/H2 > 0.05%) and an increase of the growth rate until about 20 μm/h has been measured. Photoluminescence at room temperature and at 50 K was used for defects quantification and distribution. On these wafers grown using HCl high voltage Schottky diodes have been realized. The diodes were analyzed by current-voltage (I-V) characteristics. 相似文献
3.
Two commercial SCR catalysts, with a nominal W content of about 9 wt.% and a V nominal content of 0.55 and 1.8 wt.%, respectively, were contacted with different amounts of Na and K and with HCl vapours in order to simulate poisoning by species more specifically contained in exhaust gases from MSW combustion. Catalysts were characterised using XRD analysis, SEM/EDX analysis, BET and pore size distribution measurements, NH3 TPD, TG analysis. Poisoning agents do not cause loss of surface area nor pore occlusion. A significant loss of surface acidity was observed upon alkali metals poisoning whereas a decreasing of vanadium content was observed for the more concentrated catalysts upon HCl poisoning. Catalysts deactivation is proportional to the number of acid sites neutralised by alkali metals adsorbing ammonia in the temperature range typical of SCR process. HCl promotes the formation of new acid sites showing a lower activity compared to the original one. 相似文献
4.
Rassoul Dinarvand Mohammed Massoud Alimorad Massoud Amanlou Hamid Akbari 《应用聚合物科学杂志》2006,101(4):2377-2383
Polyadipic anhydride (PAA), an aliphatic polyanhydride, and polytrimethylene carbonate (PTMC), an aliphatic polycarbonate, were synthesized via ring opening polymerization of oxepan‐2,7‐dione and melt‐condensation of trimethylene carbonate (1,3 dioxan‐2‐one), respectively. PTMC–PAA blend microspheres containing different ratios of buprenorphine HCl (2, 5, and 10%) were prepared by an oil‐in‐oil emulsion solvent removal method. Microspheres with different ratios of PTMC–PAA (85/15, 70/30, and 55/45) containing 5% buprenorphine HCl were prepared. Microspheres were spherical with visible cracks and pores on the surface. The average particle size of microspheres was around 200 μm for all microspheres. Drug loading efficiency of PTMC–PAA microspheres (85/15, 70/30, and 55/45) was 97.2, 95.2, and 70.2%, respectively. With the increase in the PTMC ratio, the melting point and the enthalpy of melting were both decreased. The mechanism for drug release from PTMC–PAA blend microspheres were generally a combination of drug diffusion through polymers and biodegradation of the polymers. In first three days, the release from microspheres followed zero order kinetics and was dependent on the PAA content. After three days the drug release from microspheres followed first order kinetics. In conclusion it was demonstrated that buprenorphine HCl release from microspheres could be successfully controlled by using different ratios of PTMC–PAA blends. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2377–2383, 2006 相似文献
5.
In recent years, polymer amines have been recognized as an excellent corrosion inhibitors for iron in acid solutions. In this work, the inhibitive effect of p‐toluidine and poly(p‐toluidine) on corrosion of iron in 1M HCl has been studied by the electrochemical methods such as impedance, linear polarization, Tafel polarization techniques. The effectiveness of poly(p‐toluidine) was found to be high in comparison with that of monomer. The results showed that p‐toluidine and poly(p‐toluidine) suppressed both cathodic and anodic processes of iron dissolution in 1M HCl. The inhibition efficiency of both p‐toluidine and poly(p‐toluidine) were found to increase with the inhibitor concentrations. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
6.
叙述了凝汽器铜管化学清洗的优点和在清洗过程中必须注意的几个问题,并且用实例进一步说明化学清洗还能够有效防止凝汽器铜管的腐蚀 相似文献
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9.
The corrosion of three commercial steels in a reducing atmosphere containing HCl plus H2S in the presence of ZnCl2–KCl deposits has been investigated at 400–500°C and compared with the corrosion of the same materials in a similar gas mixture
free from H2S. The presence of H2S in the gas accelerated the corrosion of the three commercial steels beneath ZnCl2–KCl deposits. All materials suffered from severe corrosion with partial detachment and spalling of the external scales. Degradation
of the steels resulted from the penetration of chlorine-containing species through the scale formed initially down to the
metal matrix, because chorine-rich species were detected close to the alloy/scale interface. Although the corrosion resistance
generally increased with increasing Cr content, even the high-Cr stainless steel SS304 is still unable to provide good corrosion
resistance against the ZnCl2–KCl deposits in the presence of H2S due to the bad adherence of the scales to the alloy. The mechanisms of attack are discussed on the basis of thermodynamic
considerations and of the active-oxidation model. 相似文献
10.
Liquid phase hydrodechlorination of chlorophenols over Pd/C and Pd/Al2O3: a consideration of HCl/catalyst interactions and solution pH effects 总被引:1,自引:0,他引:1
The liquid phase hydrodechlorination (HDC) of 2-chlorophenol (2-CP) and 2,4-dichlorophenol (2,4-DCP) has been studied over 1% (w/w) Pd/C and Pd/Al2O3 under conditions of minimal mass transport constraints. The HDC of 2,4-DCP generated HCl and 2-CP as the only intermediate partially dechlorinated product which reacts further to yield phenol; cyclohexanone was formed over Pd/Al2O3, but not over Pd/C, prior to complete dechlorination. Pd/Al2O3 is characterized (on the basis of TEM analysis) by a narrow distribution of smaller Pd particles to give a surface area weighted mean particle DIAMETER = 2.4 nm that is appreciably lower than the value of 13.2 nm established for Pd/C, where the latter is characterized by a broader distribution of larger (spherical) particles. The addition of NaOH served to increase fractional dechlorination by suppressing HDC inhibition due to the HCl that is generated. Reuse of the catalysts revealed an appreciable deactivation of Pd/C and a limited loss of activity in the case of Pd/Al2O3. Deactivation of Pd/C can be linked to a decrease (up to ca. 60%) in the initial BET surface area allied to appreciable leaching (up to ca. 40%) of the starting Pd content through the corrosive action of HCl and, while the average Pd diameter is essentially unaffected, there is evidence of a preferred leaching of larger Pd particles. The stronger metal/support interactions prevalent in Pd/Al2O3 results in limited Pd leaching and comparable initial HDC activities during catalyst reuse with/without NaOH addition. Inclusion of HCl in the reaction mixture (pH 5–1.5) resulted in a marked decline in the initial HDC rate associated with Pd/Al2O3 and a lesser drop in HDC activity for Pd/C. The difference in response to bulk solution pH variations are discussed in terms of the nature of the reactive species in solution and the amphoteric behavior of the Pd supports. 相似文献