Resistance reduction effect of potassium bismuth titanate doping in yttrium–manganese co-doped medium Curie temperature barium titanate lead free ceramics through improved synthesis process

Through improved synthesis process, resistance reduction effect of (K_0.5Bi_0.5)TiO₃ (KBT) doping in Y–Mn co-doped BaTiO₃ (BT) lead free ceramics was investigated. By different doping methods (doping K₂O, Bi₂O₃ and TiO₂ or synthesized KBT), medium Curie temperature (around 130 °C) lead free BT ceramics were obtained with ultra-low resistivity (13.84 Ωcm) with a temperature maintaining process at 700 °C. In this contribution, effect of sintering process and doping methods is discussed in detail.     

International legislation on trace elements as contaminants in food: a review

Environmental contaminants such as trace elements may be present in all foods. Foods, raw materials and ingredients for food production are to an increasing extent traded across borders. Hence, there is a need for international legislation on trace elements as contaminants in food. In 1961, the FAO and WHO established the Codex Alimentarius to elaborate international food legislation. Contaminants in food are handled by the Codex Committee for Food Additives and Contaminants (CCFAC). The Codex Alimentarius system for developing legislation concerning trace elements as contaminants in food is based upon the Codex General Standard for Contaminants and Toxins in Food (GSCTF). By October 2001, the principles for setting maximum limits (MLs) for contaminants in food are agreed, and work is in progress on MLs for trace elements such as lead and cadmium in the various food categories. The status for the proposals is presented and discussed. The EU Regulation 466/2001 of 8 March 2001 sets MLs for lead and cadmium in various foods. This regulation will apply from 5 April 2002. The EU regulation is more detailed but similar to the Codex draft standards for lead and cadmium in food. In future, legislators and administrators in the Codex and EU and analytical chemists will discuss how to use more and better analytical data as risk-management tools to protect public health. Trace elements' speciation is an important aspect of this discussion.     

火焰原子吸收法测定高铋物料中的铅

本文介绍了在以高铋物料为基体 ,5 %的HNO3 介质中 ,波长 2 17nm处进行火焰原子吸收法测定铅的试验 ,采用标准加入法进行回收率的试验 ,回收率大于 98% ,特征浓度为 0 .0 7μg/ml,结果令人满意 ,能满足炉前样分析的要求     

Anodic oxidation of mecoprop herbicide at lead dioxide

The electrochemical oxidation of an aqueous solution containing mecoprop (2-(2-methyl-4-chlorophenoxy)propionic acid) has been studied at PbO₂ anodes by cyclic voltammetry and bulk electrolysis. The influence of current density, hydrodynamic conditions, temperature and pH on the degradation rate and current efficiency is reported. The results obtained show that the use of PbO₂ leads to total mineralization of mecoprop due to the production of oxidant hydroxyl radical electrogenerated from water discharge. The current efficiency for the electro-oxidation of mecoprop is enhanced by low current density, high recycle flow-rates and high temperature. In contrast, the pH effect was not significant. It has also been observed that mecoprop decay kinetics follows a pseudo-first-order reaction and the rate constant increases with rising current density.     

滚子丝杠副的原理研究

本文对滚子丝杠副的运动原理及啮合原理进行分析 ,并推导了参数计算公式及由啮合原理求出了滚子的空间螺旋面方程     

Microstructure and properties of cutting magnesium-brass containing no lead

1 INTRODUCTIONLead-brass has excellent cutting ability , me-chanical and physical properties and is one of themost widely used copper alloys . The occupationratio of brass tube to all kinds of tubes reaches90 % in developed countries . The cutting lead-brass is a dual-phase brass and fine lead particlesdistribute dispersivelyin grains and on grain boun-ries . Theleadin wasted brass can easily beleachedand dissolvedinto soil .If the wasted lead-brass isburned in air ,the lead will become p…     

黄铜中纳米级微裂纹的形核与钝化

黄铜薄膜试样在透射电镜中原位拉伸观察表明，在平衡条件下加载裂发出的位错纯化成无位错区，它是一个应变很高的异常弹性区。当缺口足够锐，外加载荷足够大时，这个非线弹性区中的应力有可能达到原子键合力，从而使纳米级微裂纹在无位错区中不连续形核，或从钝化的原裂纹顶端形核。这个微裂纹一昊形核，即使保持恒位移，也将钝化成空洞或缺口。     

浅析胶料与镀铜钢丝帘线粘合的影响因素

采用正交设计法和对比试验法，考察了硫黄、氧化锌、促进剂、炭黑以及某些工艺条件对胶料与镀铜钢丝帘线粘合力的影响。结果表明，硫黄品种对粘合力的影响不大；氧化锌用量增大，粘合力增大；用１．０份促进剂ＣＺ时的粘合力大于用１．３份促进剂ＤＺ；使用高结构炭黑可增大粘合力；胶料的混炼方法和硫化时间对粘合力的影响较大。     

日用陶瓷铅溶出量与儿童多动症关系的探讨

根据目前日用陶瓷铅溶出量状况和铅中毒儿童多动症的研究结果，论证了日用陶瓷铅溶出量与儿童多动症存在相互关系，介绍了日用陶瓷铅溶出量与铅中毒检测方法，对铅中毒儿童多动症的预防和治疗提出了建议。