MnBi合金的结构与永磁性能

本文综述了有关MnBi低温相永磁材料方面的最新研究进展，对MnBi永磁合金的制备方法、结构及其永磁性能作了较为详尽的介绍。快淬和高能球磨方法可望成为单相性好的MnBi永磁合金的实用制备工艺。合金化方面的研究也显示出MnBi系合金的潜力。MnBi合金有望成为永磁性能较好且有好的温度特性(尤其是在高温时有很高的矫顽力并有正的矫顽力温度系数)的材料。MnBi合金可作为特殊用途的永磁材料，在许多领域获得应用。     

Bi-Mn合金片状初生MnBi相在强磁场中的凝固组织

进行了强磁场下Bi-Mn合金的全熔和半固态实验,研究了MnBi相在强磁场中的凝固行为．在10T强磁场下从全熔态和Curie点以上半固态开始凝固的实验中,MnBi相在360℃左右逐渐形成片状相,其短轴为易磁化轴;加磁场后易磁化轴转向磁场方向,并沿磁场方向定向排列和聚合,最终形成条状组织;片状相在强磁场的作用下有分裂趋势．结合晶体的磁各向异性和生长各向异性的特点,从磁化理论和晶体学出发,分析了Bi—Mn合金初生MnBi相在磁场中的凝固行为．     

Aligned Solidification Structure of the MnBi Phase in Semisolidified Bi-Mn Alloy with a Static Magnetic Field

The solidification structure of Bi-3 wt pct Mn alloy grown up in the semisolid zone under the influence of a staticmagnetic field (up to 1.0 T) and the relation of the magnetic property with the solidification structure have beeninvestigated experimentally. It was shown that the primary phase MnBi crystals in the alloy aligned and oriented alongthe direction of the applied magnetic field. The orientating tendency and the average length of the elongated MnBicrystals increased with the increase of the applied field and the solidification time. Moreover, the remanence of thealloy along the aligned direction of the MnBi phase in the case of solidification with a magnetic field was apparentlyanisotropic and nearly double of that without the magnetic field. This indicated that the MnBi crystals orientedand aligned along their easy magnetization axis. A model was proposed to explain the alignment and orientationgrowth of the MnBi crystals in a magnetic field in terms of the magnetic anisotropy of the crystals     

定向共晶Bi／MnBi磁性材料的组织与性能

本文报道了对共晶Bi/MnBi磁性材料凝固特性的研究结果。讨论了生长速度R、温度梯度G_L对纤维间距λ和剩余磁感应强度B_r的影响。结果表明,当R>2cm/h时,λ~2R=常数;温度梯度G_L对λ无明显影响;Bi/MnBi的B_r值随R的增大而下降,随G_L的增大而提高,显示出凝固特性与磁学性能间的密切关系。     

Bi／MnBi共晶中的小叶片状MnBi的形成SCIEI

当凝固速度较低时，单向凝固生长的Ｂｉ／ＭｎＢｉ共晶在生长的初始阶段甚至整个试样长度内出现小叶片状共晶组织．本文分析了小叶片状共晶组织的形貌特征及其生成机制．     

Bi-Mn合金在强磁场中凝固时MnBi相织构组织的演化

在3种不同凝固条件下,制备了Bi-Mn合金,研究了合金中MnBi相织构组织随磁感应强度和凝固时间的演化.结果表明,合金从265～355℃的固液两相区凝固时,随1.0T磁场中凝固时间的延长,取向棒状MnBi晶粒沿磁场方向聚合长大,长径比增大约50%;合金从355～446℃的固液两相区凝固时,随外磁场强度的增大(最大达10.0 T)和凝固时间的增加,取向片状MnBi晶粒沿磁场方向聚合长大,形成疏松不规则的粗大棒状晶粒;合金从完全熔化状态凝固时,以0.15℃/s的速度冷却可以获得MnBi相织构组织,以0.015℃/s或更小的速度冷却则不能;延长磁场中Bi-Mn合金的凝固时间不能有效提高材料的剩磁性能.     

STRUCTUREAND PROPERTY OF DIRECTIONALLY SOLIDIFIED EUTECTIC Bi/MnBi ALLOY

Eutectic Bi/MnBi magnetic alloy was prepared by directional solidification.When thegrowth rate,R>2 cm/h,the MnBi fibre spacing,λ,distributed homogeneously inBi matrix,follows λ~2R=constant.The thermal gradient.G_L,does not influenceλ.The magnetic property,B_r of Bi/MnBi alloy decreases with the increase of R andincreases with the increase of G_L.     

Magnetic and structural phase transitions of MnBi under high magnetic fields

Abstract

High-field x-ray diffraction and magnetization measurements and differential thermal analysis (DTA) were carried out for polycrystalline MnBi with an NiAs-type hexagonal structure to investigate its magnetic and structural phase transitions. The lattice parameter a rapidly decreases below the spin reorientation temperature T_SR(=90 K) in a zero magnetic field. The parameter c decreases gradually with decreasing temperature and exhibits an anomaly in the vicinity of T_SR. By applying a magnetic field of 5 T, the parameter a increases by ～0.05% when T<T_SR and varies smoothly when 8≤T≤300 K. DTA data show that the magnetic phase transition temperature from the ferromagnetic state to the paramagnetic state increases linearly at a rate of 2 KT^?1 with increasing magnetic field up to 14 T.     

定向过共晶Bi／MnBi材料的凝固特性与磁学性能

本文研究了过共晶Ｂｉ／ＭｎＢｉ材料的凝固特性，讨论了生长速度Ｒ对过共晶Ｂｉ／ＭｎＢｉ材料的共晶生长和剩余磁感应强度Ｂｒ的影响。结果表明，当Ｒ＞１．２μｍ／ｓ时，过共晶Ｂｉ／ＭｎＢｉ合金能获得纤维状共晶组织，其凝固特性与共晶合金相似；用低纯度Ｂｉ，并增加含Ｍｎ量，能有效地提高Ｂｉ／ＭｎＢｉ材料的磁性，这在实用上具有重大意义。     

新型磁性材料Bi／MnBi的研究与发展

Ｂｉ／ＭｎＢｉ材料是一种具有一系列独特性能的新型磁性功能材料。本文阐述了该材料的制备、性能、用途及其研究现状、存在的问题和发展趋势。