全文获取类型
收费全文 | 12571篇 |
免费 | 859篇 |
国内免费 | 289篇 |
专业分类
电工技术 | 96篇 |
技术理论 | 1篇 |
综合类 | 688篇 |
化学工业 | 6799篇 |
金属工艺 | 552篇 |
机械仪表 | 108篇 |
建筑科学 | 874篇 |
矿业工程 | 324篇 |
能源动力 | 598篇 |
轻工业 | 1266篇 |
水利工程 | 112篇 |
石油天然气 | 581篇 |
武器工业 | 13篇 |
无线电 | 56篇 |
一般工业技术 | 891篇 |
冶金工业 | 544篇 |
原子能技术 | 160篇 |
自动化技术 | 56篇 |
出版年
2024年 | 42篇 |
2023年 | 111篇 |
2022年 | 223篇 |
2021年 | 341篇 |
2020年 | 330篇 |
2019年 | 278篇 |
2018年 | 253篇 |
2017年 | 323篇 |
2016年 | 405篇 |
2015年 | 381篇 |
2014年 | 620篇 |
2013年 | 698篇 |
2012年 | 804篇 |
2011年 | 951篇 |
2010年 | 693篇 |
2009年 | 715篇 |
2008年 | 658篇 |
2007年 | 757篇 |
2006年 | 758篇 |
2005年 | 632篇 |
2004年 | 544篇 |
2003年 | 447篇 |
2002年 | 413篇 |
2001年 | 362篇 |
2000年 | 374篇 |
1999年 | 282篇 |
1998年 | 260篇 |
1997年 | 150篇 |
1996年 | 162篇 |
1995年 | 143篇 |
1994年 | 130篇 |
1993年 | 123篇 |
1992年 | 68篇 |
1991年 | 48篇 |
1990年 | 39篇 |
1989年 | 42篇 |
1988年 | 16篇 |
1987年 | 30篇 |
1986年 | 20篇 |
1985年 | 17篇 |
1984年 | 25篇 |
1983年 | 16篇 |
1982年 | 16篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1959年 | 2篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(11):7242-7251
In the present study, metal-free catalysts for efficient H2 generation from NaBH4 methanolysis was produced for the first time from apricot kernel shells with two-step activation. The first stage of the two-stage activation includes the production of activated carbon with the KOH agent (AKOH), and the second stage includes hydrothermally HNO3 activation with oxygen doping (O doped AKOH + N). The hydrogen production rate (HGR) and the activation energy (Ea) of the reaction with the obtained metal-free catalyst (10 mg) were determined as 14,444 ml min?1 g?1 and 7.86 kJ mol?1, respectively. The structural and physical-chemical properties of these catalysts were characterized by XRD (X-ray diffraction), SEM (scanning electron microscopy), elemental CHNS analysis, FT-IR (Fourier transform infrared spectroscopy), and nitrogen adsorption analysis. Also, the reusability results of this metal-free catalyst for H2 production are promising. 相似文献
2.
《Ceramics International》2022,48(12):17185-17195
This study introduces micro-nano bubbles (MNBs) in the process of polishing zirconia ceramics through sodium borohydride hydrolysis to assist in polishing yttria-stabilized zirconia (YSZ). Compared with conventional silica sol, the material removal rate using this MNB-assisted technology is increased by 261.4%, and a lower surface roughness of 1.28 nm can be obtained. Raman, X-ray diffraction, and X-ray photoelectron spectroscopy are used to study the structural changes and phase stability of the YSZ during different polishing periods. The results show that MNBs are the key factor promoting the transformation from the tetragonal phase to the monoclinic phase on the surface of the YSZ during polishing. The H2O molecules (or OH? ions) on the surface of the YSZ are driven by the thermal kinetic energy of the micro-jets formed by the collapse of micro-bubbles, and they permeate to occupy more oxygen vacancies in the crystal lattice. Atomic force microscopy and nano-indentation tests show that the micro-protrusions on the surface of the YSZ preferentially undergo phase transformation, and their hardness decreases. This promotes abrasives to preferentially remove rough spots on the surface and achieve more efficient polishing. We believe this work adds valuable insights regarding low-temperature degradation and ultra-precise machining of YSZ ceramic materials. 相似文献
3.
Xiaoyuan Sun Zixuan Liu Hao Qian Yunfei Liu Yinong Lyu 《Ceramics International》2021,47(17):24207-24217
A strategy that constructs the morphotropic phase boundary and manipulates the domain structure has been used to design the component of 0.96[Bi0.5(Na0.84K0.16)0.5Ti(1-x)NbxO3]-0.04SrTiO3 (BNKT-4ST-100xNb) to enhance the strain properties for actuator application. Non-equivalent Nb5+ donor doping modulates the phase transition from the mixture of rhombohedral and tetragonal phases to the pseudocubic phase and results in the coexistence of multiple phases. Moreover, the high-resolution TEM confirms the existence of polar nano regions that contribute to the macroscopic relaxor behaviour. The size of the domains is reduced with increasing Nb5+, resulting in an enhanced relaxor behaviour. The ferroelectric-relaxor transition temperature decreases from 85 to below 30 °C, implying a non-ergodic to ergodic relaxor transition. An improved strain of 0.56% and a giant normalized strain of 1120 pm/V were achieved for BNKT-4ST-1.5Nb, which were attributed to the unique domain structure in which nanodomains are embedded in an undistorted cubic matrix. Ferroelectric, antiferroelectric, and relaxor phases coexist. As the electric field is large enough, a reversible phase transition occurs. Furthermore, good temperature stability was obtained due to the stability of the nanodomains, and no degradation in strains was observed even after 104 cycles, which may originate from the reversible phase transition and dynamic domain wall. The results show that this design strategy offers a reference way to improve the strain behaviour and that BNKT-4ST-100xNb ceramics could be a potential material for high-displacement actuator applications. 相似文献
4.
There are many potential causes of corrosion in animal buildings. Animals exhale large quantities of moisture into the air creating high relative humidity in the building if the moisture is not properly vented. High humidity increases the potential for condensation. In addition, ammonia may be found in large quantities in animal buildings. Ammonia is released from manure and urine. In addition, ammonium chloride is used as a nitrogen source in fertilisers. In this study, the atmospheric corrosion of hot-dip-galvanised steel and zinc alloy-coated steel such as zinc–aluminium and zinc–aluminium–magnesium has been studied in atmospheres containing different levels of ammonia. Investigations have also been conducted at different levels of ammonium chloride. The results are discussed in view of the mechanisms of corrosion of zinc and zinc alloy-coated steel in ammonia and ammonium chloride-containing environments. 相似文献
5.
6.
Manjin Kim Qinfen Gu Tanveer Hussain Yahia Ali Trevor B. Abbott Kazuhiro Nogita 《International Journal of Hydrogen Energy》2021,46(53):27096-27106
With superior properties of Mg such as high hydrogen storage capacity (7.6 wt% H/MgH2), low price, and low density, Mg has been widely studied as a promising candidate for solid-state hydrogen storage systems. However, a harsh activation procedure, slow hydrogenation/dehydrogenation process, and a high temperature for dehydrogenation prevent the use of Mg-based metal hydrides for practical applications. For these reasons, Mg-based alloys for hydrogen storage systems are generally alloyed with other elements to improve hydrogen sorption properties. In this article, we have added Na to cast Mg–La alloys and achieved a significant improvement in hydrogen absorption kinetics during the first activation cycle. The role of Na in Mg–La has been discussed based on the findings from microstructural observations, crystallography, and first principles calculations based on density functional theory. From our results in this study, we have found that the Na doped surface of Mg–La alloy systems have a lower adsorption energy for H2 compared to Na-free surfaces which facilitates adsorption and dissociation of hydrogen molecules leading to improvement of absorption kinetic. The effect of Na on the microstructure of these alloys, such as eutectic refinement and a density of twins is not highly correlated with absorption kinetics. 相似文献
7.
8.
9.
Shensong Wang Zheng Wu Jie Chen Jiangping Ma Jingshi Ying Shouchen Cui Shigang Yu Yongming Hu Jinhe Zhao Yanmin Jia 《Ceramics International》2019,45(9):11703-11708
In this work, the hydrothermally-synthesized sodium niobate nanowires were used to decompose Rhodamine B dye solution through the piezo-catalytic effect. With the sodium niobate catalyst, a high piezo-catalytic degradation ratio of ~80% was achieved under the excitation of vibration for the Rhodamine B dye solution (~5?mg/l). These active species in the catalytic process, hydroxyl radicals and superoxide radicals with the strong oxidation ability, were also observed, which confirmed the key role of piezoelectric effect for piezo-catalysis. The piezo-catalysis of sodium niobate nanowires provides a high-efficiency and reusable tool in application in depredating the dye wastewater. 相似文献
10.
This DFG-funded research project aimed to gain a better understanding of the mechanisms of the W-Cl repair principle within the framework of fundamental investigations, to contribute to the creation of the necessary basis for a broader application of the repair principle in practice. The focus was on the development of a model to describe the chloride redistribution after the application of a system sealing surface protective coating. On the basis of Fick's second law of diffusion, a mathematical model with a self-contained analytical solution was developed, with the help of which the chloride redistribution after application of a system sealing surface protective coating can be calculated under the idealized assumption of complete water saturation of the concrete. Furthermore, the influence of the dehydration of the concrete, expected as a result of the application of the repair principle W-Cl, on the chloride redistribution was investigated. On the basis of laboratory tests and numerical simulations, material-specific reduction functions were developed to quantify the relationship between the chloride diffusion coefficient and the ambient humidity. 相似文献