全文获取类型
收费全文 | 1930篇 |
免费 | 41篇 |
国内免费 | 50篇 |
专业分类
电工技术 | 54篇 |
综合类 | 82篇 |
化学工业 | 434篇 |
金属工艺 | 147篇 |
机械仪表 | 90篇 |
建筑科学 | 72篇 |
矿业工程 | 62篇 |
能源动力 | 98篇 |
轻工业 | 60篇 |
水利工程 | 15篇 |
石油天然气 | 101篇 |
武器工业 | 6篇 |
无线电 | 211篇 |
一般工业技术 | 241篇 |
冶金工业 | 77篇 |
原子能技术 | 21篇 |
自动化技术 | 250篇 |
出版年
2024年 | 2篇 |
2023年 | 31篇 |
2022年 | 26篇 |
2021年 | 45篇 |
2020年 | 42篇 |
2019年 | 33篇 |
2018年 | 37篇 |
2017年 | 45篇 |
2016年 | 47篇 |
2015年 | 58篇 |
2014年 | 82篇 |
2013年 | 115篇 |
2012年 | 118篇 |
2011年 | 155篇 |
2010年 | 86篇 |
2009年 | 123篇 |
2008年 | 82篇 |
2007年 | 100篇 |
2006年 | 106篇 |
2005年 | 81篇 |
2004年 | 76篇 |
2003年 | 66篇 |
2002年 | 64篇 |
2001年 | 64篇 |
2000年 | 52篇 |
1999年 | 40篇 |
1998年 | 33篇 |
1997年 | 33篇 |
1996年 | 30篇 |
1995年 | 28篇 |
1994年 | 25篇 |
1993年 | 24篇 |
1992年 | 20篇 |
1991年 | 19篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有2021条查询结果,搜索用时 15 毫秒
1.
《Advanced Powder Technology》2020,31(12):4585-4597
Focussing on visible light active ferrites for high performance removal of noxious pollutants, we report the synthesis of Mg0.5NixZn0.5-xFe2O4 (x = 0.1, 0.2, 0.3, 0.4, & 0.5) ferrite nanoparticle for degradation of reactive blue-19 (RB-19). Lattice parameters calculated using intense X-ray diffraction (XRD) peaks and Nelson-Riley plots (N-R plot) are in well agreement with each other. The sample Mg0.5Ni0.4Zn0.1Fe2O4 (M5N4) exhibits best performance with 99.5% RB-19 degradation in 90 min under visible light. Photoluminescence (PL) results confirm that recombination of charge carriers is highly reduced in the photocatalyst. Scavenging experiments suggest that O2− radicals were the dominant species responsible for photocatalytic performance. The photocatalytic mechanism was explained in terms of dopant driven shifting of conduction bands and valence bands (calculated by Mott-Schottky plots). The thermodynamic probability of radical generation along with role of redox cycles of metal ions has been discussed in the mechanism. The dye degradation was ascertained by detection of intermediates via mass spectrometry analysis and a possible degradation route was also predicted. The findings in this work provide intriguing opportunities to modify the electronic band structure of spinel ferrites for visible and solar light photocatalytic activity for environmental detoxification. 相似文献
2.
Microstructures of hundreds of micron thick poly(styrene-block-isoprene) copolymer films solution-cast in a cylindrical tube with the solvent evaporation controlled were investigated by transmission electron microscope (TEM), small angle X-ray scattering (SAXS) and optical microscope (OM). In a block copolymer with cylindrical polyisoprene microdomains, the orientation of the cylinders was varied along radial direction of the cylindrical tube. Highly aligned hexagonal arrays of in-plane polyisoprene cylinders were formed with their cylindrical axis parallel to the circumference of the tube in the regimes close to the wall edge. In contrast randomly ordered microdomains were observed at the center of the tube. We have also found that the orientation depends on the solvent evaporation rate and an intermediate rate (∼2.3 nL/s) provides the best orientation. In the case of a block copolymer with a bicontinuous double gyroid structure, we obtained a globally ordered microstructure where [111] crystallographic direction was parallel to the circumference of the tube. For both block copolymers, the area of highly ordered arrays of nanoscopic domains is over 1 mm2. Development of the orientation was explained by coupling two orthogonal fields: (1) The flow of a solution induced by strong capillary force at a meniscus between the cylindrical tube wall and the block copolymer solution and (2) the solvent evaporation. 相似文献
3.
岩盐钻井水溶双井连通开采工艺的研究与推广 总被引:1,自引:0,他引:1
文章就全国井矿盐采区多年的开采工艺技术,进行了系统的研究与总结,并提出了岩盐钻井水溶开采双井连通的各种开采工艺及其关键技术,具有很强的适用性和推广价值。 相似文献
4.
Mushroom-like ZnO microcrystals have been prepared via a solution calcination route, using Zn(NO3)2 as Zn source in the absence of any surfactants, templates or catalysts. This is the first example to prepare mushroom-like crystals as semiconductors, which are expected to show particular physical properties. The ZnO products were investigated by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy and photoluminescence (PL) spectrum measurements. A suitable concentration of Zn(NO3)2 solution was important for the growth of the mushroom-like products. The reported synthetic procedure is straightforward and inexpensive, and thus can be readily adopted to produce large quantities of mushroom-like ZnO microcrystals. 相似文献
5.
智能小区中的网络和布线设计解决方案——智能建筑学术讨论系列文章之七 总被引:1,自引:0,他引:1
当前小区信息网络建设中存在多种实施方案。笔者分析比较了常用的几种典型方案的优劣。讨论了目前建设中的一些解决方法,提出了兼顾现状,适度超前的设计实施原则。 相似文献
6.
本文介绍了VAc/BA/MMA三元共聚的两种方法,并通过实验证实:聚合方法对三元共聚物的粘接强度有明显的影响。 相似文献
7.
8.
Using chloroform/dimethylformamide (CF/DMF) co-solvent, electrospinning of poly[(R)-3-hydroxybutyrate] (PHB) solutions was carried out at ambient temperature. The effects of the applied voltage (V), flow-rate (Q), and solution viscoelastic properties on the Taylor cone, electrified jet, and fiber morphology were investigated. In addition, the electric field developed by the needle-plate electrode configuration was calculated using a finite element analysis to reveal the tip-to-collector (H) effect. Among the processing parameters (V, Q and H), it was found that Q played a key role in determining the jet diameter (dj) and electrospun fiber diameter (df), and scaling laws existed between them, i.e., dj-Q0.61 and df-Q0.33. The diameter reduction ratios of Do/dj (Do is the needle diameter) and dj/df were measured as 50-120 and 5-10, respectively; it suggested that major jet stretching took place in the straight electrified jet region, and further chain orientation could be gained by the subsequent process of jet whipping. By changing PHB concentrations from 5 to 15 wt%, the solution viscosity (ηo) was increased from 100 to 4900 cP, whereas the surface tension and solution conductivity remained unchanged; it provided a good model solution to exclusively reveal the ηo effect on the electrospinning process. Our results showed that the ηo-dependence of dj and df also followed simple scaling laws: dj-ηo0.06, and df-ηo0.39, with a prefactor depending on the processing variables, mainly the flow-rate. Regardless of the PHB concentrations used, the obtained PHB fibers showed a similar crystallinity fraction of ca. 0.63 and possession of major α-crystals together with a small amount of β-crystals with zigzag chain conformation. 相似文献
9.
Do Hoon Kim Umme Farva Woo Sik Jung Eui Jung Kim Chinho Park 《Korean Journal of Chemical Engineering》2008,25(5):1184-1189
This paper reports an alternative method for the growth of GaN epitaxial layer on (0001) Al2O3 substrate by hot-wall vapor phase epitaxy technique. Tris (N,N-dimethyldithiocarbamato)-gallium (III), Ga(mDTC)3 was introduced as a precursor material for the seed layer formation in the growth of GaN. Optimal growth conditions with
seed layers formed by the Ga(mDTC)3 concentration of 0.047 mol/L were identified: Growth temperature was found to be 850 °C, and optimal distance between the
reactant outlet and substrate was determined to be 12.5 cm. Characterization results showed that this growth method produce
high-crystallinity GaN epitaxial layers at a relatively lower growth temperature compared to the existing growth techniques
and simplify the growth process. 相似文献
10.
本研究了几种不酸PH值对硅酸胶结的影响。结果表明,草酸浓度增大时,硅酸胶结速度变缓,至PH3-4时,硅酸不再胶结;而HCL浓度增大,虽然胶结速度变缓,但最终仍胶结。 相似文献