Enhanced gaseous hydrogen solubility in ferritic and martensitic steels at low temperatures

Metals that are exposed to high pressure hydrogen gas may undergo detrimental failure by embrittlement. Understanding the mechanisms and driving forces of hydrogen absorption on the surface of metals is crucial for avoiding hydrogen embrittlement. In this study, the effect of stress-enhanced gaseous hydrogen uptake in bulk metals is investigated in detail. For that purpose, a generalized form of Sievert's law is derived from thermodynamic potentials considering the effect of microstructural trapping sites and multiaxial stresses. This new equation is parametrized and verified using experimental data for carbon steels, which were charged under gaseous hydrogen atmosphere at pressures up to 1000 bar. The role of microstructural trapping sites on the parameter identification is critically discussed. Finally, the parametrized equation is applied to calculate the stress-enhanced hydrogen solubility of thin-walled pipelines and thick-walled pressure vessels during service.     

Feedforward control of the transverse strip profile in hot-dip galvanizing lines

Hot-dip galvanizing is a standard technology to produce coated steel strips. The primary objective of the galvanizing process is to establish a homogeneous zinc layer with a defined thickness. One condition to achieve this objective is a uniform transverse distance between the strip and the gas wiping dies, which blow off excessive liquid zinc. Therefore, a flat strip profile at the gas wiping dies is required. However, strips processed in such plants often exhibit residual curvatures which entail unknown flatness defects of the strip. Such flatness defects cause non-uniform air gaps and hence an inhomogeneous zinc coating thickness. Modern hot-dip galvanizing lines often use electromagnets to control the transverse strip profile near the gas wiping dies. Typically, the control algorithms ensure a flat strip profile at the electromagnets because the sensors for the transverse strip displacement are also located at this position and it is unfeasible to mount displacement sensors directly at the gas wiping dies. This brings along that in general a flatness defect remains at the gas wiping dies, which in turn entails a suboptimal coating.In this paper, a model-based method for a feedforward control of the strip profile at the position of the gas wiping dies is developed. This method is based on a plate model of the axially moving strip that takes into account the flatness defects in the strip. First, an estimator of the flatness defects is developed and validated for various test strips and settings of the plant. Using the validated mathematical model, a simulation study is performed to compare the state-of-the-art control approach (flat strip profile at the electromagnets) with the optimization-based feedforward controller (flat strip profile at the gas wiping dies) proposed in this paper. Moreover, the influence of the distance between the gas wiping dies and the electromagnets is investigated in detail.     

Fretting-induced friction and wear in large flat-on-flat contact with quenched and tempered steel

Fretting may cause severe surface damage and lead to unexpected fatigue failure. Our test apparatus was designed based on reciprocating, large, annular flat-on-flat contact without any edge effects in the direction of the fretting movement. Fretting wear tests were run with quenched and tempered steel with different normal pressures and sliding amplitudes under gross sliding conditions. The development of the friction coefficient and total wear mass depended mostly on the accumulated sliding distance. Initially, friction and wear were highly adhesive but gradually changed to abrasive due to third body accumulation in the interface.     

高精度薄壁钢套类零件制造工艺

薄壁钢套类零件是机械制造中常碰到的一类难加工零件,由于其不同的功能用途和典型结构特点,其制造有一定难度,在实际生产过程中,经常出现加工制造后的零件尺寸精度、形状精度、形位精度达不到使用及设计要求。本文较系统地阐述了薄壁钢套类零件的典型制造工艺方法以及在制造过程中的变形分析和应对措施。     

Modelling dislocation assisted tempering during rolling contact fatigue in bearing steels

Rolling contact fatigue in bearing steels is manifested by dark-etching regions, which are attributed to deformation induced tempering. In order to quantitatively explain this phenomenon, a model is suggested for martensite tempering assisted by dislocation glide during rolling contact fatigue. In the model, dislocations transport carbon from the matrix to carbide particles, provided that the carbon is located at a certain distance range from the dislocation contributing to the tempering process. By calculating the amount of carbon in the matrix, the kinetics of carbide thickening and hardness reduction are computed. It is found that the dark-etching region kinetics can be controlled by both bearing operation conditions (temperature and deformation rate) and microstructure (type, size, and volume fraction of carbides). The model is validated against tested bearings, and its limitations are discussed.     

Effect of steel slag on 3D concrete printing of geopolymer with quaternary binders

A new type of 3D-printable ‘one-part’ geopolymer was synthesized with fly ash (FA), granulated blast furnace slag (GBFS), steel slag (SS) and flue gas desulfurization gypsum (FGD). The effects of SS content (0–40%) on the rheological properties, 3D-printability, mechanical anisotropy and reaction kinetics of geopolymer were investigated. The yield stress and plastic viscosity monotonically decreased with the increasing SS content. Contrarily, the geopolymer with 10% of SS presented better extrudability, buildability and mechanical strength than those with 0, 20%, 30% and 40% of SS. This was mainly attributed to the conflicting influence of SS on geopolymerization, of which the OH^? produced by hydration of SS raised the alkalinity of the reaction system and accelerated the dissolution of SiO₄^4? and AlO₄^5?, while the low reactivity prohibited the following polymerization process. Furthermore, the 3D-printed geopolymer presented more compact microstructure and less mechanical anisotropy thanks to the crosslinking of morphologically complementary products, including N(C)-A-S-H, C–S–H, AFt and CH, formed via synergistic reaction of FA-GBFS-SS-FGD system.     

燃气热水器在无回水管水路中实现零冷水的方案研究

本文分析了燃气热水器行业针对无回水管水路系统实现零冷水功能的现有技术方案,指出现有技术方案存在的一些缺陷,并结合试验研究,对无回水管水路系统提出了一套全新的实现零冷水功能的技术解决方案。     

浅析火力发电厂汽水系统中内径管与外径管的设计选择

按照管道加工工艺的不同,管道可分为内径控制管和外径控制管。通过热轧工艺生产的外径控制无缝钢管,可满足火力发电厂汽水系统中绝大部分管道的使用要求。对于超(超)临界机组的主蒸汽和高温再热蒸汽管道采用的P91/P92材质的大口径厚壁无缝钢管,由于对材料性能和加工工艺有特殊要求,因此宜采用内径控制管。     

不同管距时玉米渗灌效果的试验研究

在运城市夹马口灌区和红旗灌区进行了1996,1997两个年度的玉米渗灌试验,研究了不同毛管间距条件下渗灌对其产量及水分生产率等的影响。结果表明,玉米渗灌毛管间距采用0.8~1.0 m较为适宜。毛管间距愈大,产量愈低;渗灌较地面灌平均减产7.23%,较旱地平均增产30.8%;玉米生长期内总耗水量地面灌最大,渗灌次之,旱地最小。渗灌可明显提高玉米水分生产率,渗灌处理水分生产率平均为1.65 kg/m3,是地面灌的1.2倍,是旱地的1.33倍;两年度渗灌较地面灌平均节水44.4%。     

聚丙烯装置聚合区设备布置及管廊的配管设计

结合工程特点及工艺流程,阐述了300 kt/a聚丙烯装置的布置原则,管道、管架设计要点和方法,以及需要注意的问题。