Relative importance of transformation temperatures and sulphur content on hot ductility of steels

Abstract

Low (0·3%) and high manganese (1·4%) plain C – Mn steels with varying sulphur levels have had their hot ductility determined over the temperature range 700 – 1000°C, both after 'solution treatment' at 1330°C and directly after casting. It has been established that the width, depth and position of the hot ductility curves after solution treatment is more related to the transformation behaviour than either the sulphur in solution or the sulphide volume fraction or distribution. The growth of deformation induced ferrite at the austenite boundaries seems to be mainly diffusion controlled, and the higher is the transformation temperature for the γ – α phase change, the faster is the growth. Large amounts of ferrite can then form, giving good ductility. Thus, high transformation temperatures Ae ₃ or Ar ₃ are required to produce narrow ductility troughs. It is believed that any detrimental influence of the sulphides on these 'solution treated' steels is swamped by the rapid increase in ferrite volume fraction. For the as cast state, as more sulphides are able to precipitate at the interdendritic boundaries and austenite grain boundaries than in the solution treated condition, increasing the sulphur level causes a small deterioration in ductility at the high temperature end of the trough. In the present work, only narrow troughs have been found. This is in contrast to previous work on as cast C – Mn – Nb – Al steels, which exhibited wide troughs in the ductility curves, where it was shown that higher total sulphur levels lead to considerably worse ductility and that sulphur can be as detrimental to the ductility as niobium. It is recommended that, to avoid transverse cracking during continuous casting, in addition to keeping the sulphur level low, the carbon and manganese should also be as low as possible.     

Influence of cooling and reheating on the evolution of copper rich liquid in high residual low carbon steels

Abstract

This study investigates some effects of austenite microstructure on processes leading to copper hot shortness. Low carbon steels containing 0˙55 wt-% copper were subjected to two thermal profiles in an infrared image furnace with attached confocal scanning laser microscope: hold at 1150°C for 60 s; hold at 1150°C for 60 s, quench to 400°C, reheat to 1150°C. Heat treatments were conducted in dried/deoxidised argon to image microstructures. Subsequent samples were oxidised in air. The oxide/metal interface was studied in a scanning electron microscope. Additional confocal scanning laser microscope experiments involved melting copper directly on the steel. After quench/reheat, austenite grain size decreased by a factor of ～1˙7 and grain boundaries were redistributed. Copper evolved during the first heating was no longer found at boundaries. Results from direct copper exposure reveal an apparent effect of boundary character on copper penetration rate. Possible mechanisms by which hot shortness is affected are discussed.     

Plasticity induced transformation in a metastable β Ti-1023 alloy by controlled heat treatments

Abstract

Investigations into the possibility of improving the strength–ductility relation in a metastable β-titanium alloy (Ti–10V–2Fe–3Al) through plasticity induced transformation (PiTTi) have been carried out. Various heat treatments in the β and/or α+β condition were performed to study their influence on both the microstructure and solute partitioning, which eventually control the PiTTi effect. Stress induced martensite formation promoting such effect has been observed upon compression testing for β and β+(α+β) microstructures. The stress–strain curves exhibiting stress induced martensite show a ～20% increase in strength, while still retaining a reasonable ductility level. Microstructural parameters such as grain size and solute concentration (especially V) in β have been related to the alloy's ability to exhibit PiTTi.     

Prediction of residual stress distributions for single weld beads deposited on to SA508 steel including phase transformation effects

Abstract

The sensitivity of residual stress distributions in bainitic–martensitic steel welds to the transformation strains that arise when austenite decomposes on cooling has been assessed by examining the predictions of three models for a simple bead-on-plate configuration. These cover the following scenarios: case I, no phase transformations; case II, transformations with volume change effects only; case III, transformations with volume change effects and associated Greenwood–Johnson transformation plasticity. Austenite decomposition was predicted by implementing Kirkaldy's reaction rate equations as a subroutine in the finite element code Sysweld, eliminating the need for a continuous cooling transformation diagram. Predicted residual stresses were then compared and rationalised alongside measurements obtained by neutron diffraction and the contour method. It was found that serious errors in predicting the location and magnitude of the peak stresses occurred if transformations were not included, while cases II and III gave similar results generally in agreement with the stress maps. Indeed, the trends in the experimental results were intermediate between cases II and III. Differences between the models and the potential for further improvements are discussed.     

The Effect of Phosphorus on the Microstructure and Properties of Compacted Graphite (CG) Irons

Abstract

The effect of up to 0.15% phosphorus on the microstructure and mechanical properties of step-block castings made from compacted- graphite iron has been examined. There was no major effect on the microstructure, but two minor effects were observed. First, the higher-phosphorus irons showed a small increase in the amount of carbides and pearlite within the microstructure, but there was no effect on the depth of surface chill. Second, at low magnesium contents the higher-phosphorus irons demonstrated a marked increase in the amount of flake graphite. Phosphorus had no adverse effect on tensile strength, and a reported lowering of tensile elongation at elevated phosphorus content was not found in this work. There was, however, a decrease in Charpy impact toughness at higher phosphorus levels.     

Non-isothermal thermomechanical metallurgical model and its application to welding simulations

Abstract

This paper presents a thermomechanical metallurgical macroscopic model for steels. The model is based on an existing model that is extended for non-isothermal behaviour in combination with phase transformations. The model and its numerical implementation in ABAQUS are described using vector notation for stress and strain tensors. Model parameters are presented for the dual phase steel DP600 and the structural steel S355. For DP600, thermomechanical model parameters, i.e. hardening and strain rate dependency, have been obtained by fitting temperature and strain rate dependent tensile tests. A metallurgical model was implemented using data obtained from phase field models for the austenite growth and continuous cooling transition diagrams for phase transformations from austenite to low temperature phases. The model is applied to welding simulations of DP600 overlap joints and S355 T joints. The final distortion is compared to experiments and it is shown that the model presented is able to reproduce the experimental results very well.     

Ferrite to austenite reverse transformation process in B containing 9%Cr heat resistant steel HAZ

Abstract

Creep properties of the high Cr heat resistant steel welded joint can be improved by adding B due to prevention of the grain refinement in heat affected zone (HAZ). In the present study, phase transformation behaviour of the B steel HAZ has been investigated to understand suppression mechanism of the grain refinement. During reverse transformation, fine austenite was formed through diffusional transformation at the prior austenite grain boundary in the first stage, and then coarse austenite was formed at the same location of the original austenite. The volume fraction of the fine austenite increased with increasing perk temperature of the weld thermal cycle. This phenomenon can be explained if the coarse austenite contains high density of dislocations. Clear surface relief was observed during the reverse transformation by a confocal laser microscope. These results indicate that martensitic or displacive reverse transformation takes place during welding and it prevents the grain refinement in HAZ.     

Analysis of martensite transformation behaviour in welded joint using low transformation temperature welding wire

Abstract

Low transformation temperature welding (LTTW) wire has been found to improve the fatigue strength in welded joints. In the present study, the temperature dependence of the mechanical properties in a dual phase microstructure of austenite and martensite was estimated using the properties of full austenite and full martensite in numerical analyses. A welding method effective for residual stress reduction and fatigue strength improvement was shown by applying a calculation method under transformation superplasticity and transformation induced plasticity in high strength steel welded joints. With this method, the influence of the welding pass sequence on the residual stress distribution and fatigue strength was examined in a boxing fillet welded joint using LTTW. The transformation tensile residual stress in the weld toe was decreased by sectioned welding, and the fatigue limit by sectioned welding with LTTW improved in comparison with the fatigue limit of a joint welded with conventional wire in the same process.     

Microstructure in adiabatic shear bands in a pearlitic ultrahigh carbon steel

Abstract

Adiabatic shear bands, obtained in compression deformation at a strain rate of 4000 s^?1, in a pearlitic 1·3%C steel, were investigated. Shear bands initiated at 55% compression deformation with the width of the band equal to 14 μm. Nano-indentor hardness of the shear band was 11·5 GPa in contrast to the initial matrix hardness of 3·5 GPa. The high strength of the shear band is attributed to its creation from two sequential events. First, large strain deformation, at a high strain rate, accompanied by adiabatic heating, led to phase transformation to austenite. Second, retransformation upon rapid cooling occurred by a divorced eutectoid transformation (DET). The result is a predicted microstructure consisting of nano size carbide particles within a matrix of fine ferrite grains. It is proposed that the DET occurs in iron–carbon steels during high rate deformation in ball milling, ball drop tests and in commercial wire drawing.