The multi-structure of oxidized-reduced tungsten carbide surface(s)

The XPS of bulk tungsten carbide, partially oxidized WC surfaces at 373 and 573 K as well as tungsten trioxide have been reported. Bulk WC has been prepared from WO₃ as a starting material in a mixture of CH₄ (20%) and H₂ (80%) at 1150 K for 4 h, while partially oxidized WC surfaces were prepared by oxygen chemisorption on a clean WC surface at 200 K, then the temperatures were raised to 373 and 573 K respectively. The XPS of a freshly prepared WC reveals the presence of a small amount of WO₃ on the surface and a slightly higher concentration in the bulk. The oxygen-exposed fresh WC surfaces and surfaces treated at temperatures higher than 373 K show the presence of WO₃ in a considerable quantity depending on the length and the treatment temperature. Ar⁺ bombardment of this partially oxidized surface reduces WO₃ to WO₂ and W(0), while WC is partially reduced to W(0). Isomerization reactions of alkanes on oxygen-exposed WC surface occurs in reality on a composite surface structure containing WC, WO₃, WO₂ and elemental W(0).     

Argon I Lines Produced in a Hollow Cathode Source, 332 nm to 5865 nm

We report precision measurements by Fourier transform spectroscopy of the vacuum wavenumber, line width, and relative signal strength of 928 lines in the Ar I spectrum. Wavelength in air and classification of the transition are supplied for each line. A comparison of our results with other precision measurements illustrates the sensitivity of Ar I wavelengths to conditions in the light source.     

Parametric study of the electrical to thermal power conversion in an inductively coupledrf plasma torch

An inductively coupled (ic) radio-frequency (rf) stabilized argon plasma was generated in a quartz tube using a 7 MHzrf generator. The electrical and thermal powers were measured and the efficiency of energy conversion was computed. The results indicate that for a constant power input, there is an optimum argon flow rate for which maximum energy conversion efficiency occurs.     

Thermal transport behavior of van der Waals solids and liquids in the neighborhood of the solid-liquid phase transition

The thermal conductivity, , is one of the few transport coefficients which shows a relatively small change at the solid-liquid phase transition, and hence it is a property that can be used in comparing dynamic properties of both ordered and disordered systems. Although the discontinuity in can be accounted for largely by the difference in density, , of solid and liquid at the phase transition, its volume dependence is examined more closely. The thermal diffusivity, which is known to dominate the dynamic structure factor of liquid argon, has been determined around the phase transition also; the sound velocity has been considered in addition. The results are discussed and a comparison is made with these properties in solid and liquid benzene and cyclohexane.Paper presented at the Ninth Symposium on Thermophysical Properties, June 24–27, 1985, Boulder, Colorado, U.S.A.     

Thermal accommodation coefficient of gases on controlled solid surfaces: Argon-tungsten system

The knowledge of the thermal accommodation coefficient for gases on well-controlled surfaces as a function of temperature is imperative to understanding the mechanism of interphase heat transfer on the microscopic level. With this goal in view, a heat transfer column instrument is designed, fabricated, assembled, and tested for the specific case a argon—tungsten system. With 99.9999%, pure argon, six sets of data are taken in the rarefied gas region in the maximum temperature range of 500–1500 K. Four sets of these measurements are in the temperature-jump region and are analyzed by the constant-power method to compute the thermal accommodation coefficient of argon on a controlled tungsten surface. The other two sets are taken under free-molecular flow conditions and are interpreted in accordance with the man-free-path kinetic theory for the low-pressure regime. These data are compared and discussed in the context of reported data in the literature and interpreted in the light of the surface condition and finish of the tungsten wire.Nomenclature A area of the solid surface - C _j constants in Eq. (3); j=0, 1, 2, 3, and 4 - E _i incident energy flux - E _r reflected energy flux - E _s reflected energy flux when the interaction between the gas and the solid atoms is complete - g temperature-jump distance - L half-length of the metal wire - M molecular weight of the gas - P gas pressure - Q _H total thermal energy conducted by the gas per unit time from the hot surface - Q_KT total thermal energy conducted by the gas per unit time if the striking gas molecules were to attain thermal equilibrium with the hot surface - R molar gas constant - r radial coordinate - r _f radius of the hot wire - S sticking coefficient - S_o initial sticking coefficient - T temperature - T _e linearly extrapolated gas temperature on the hot-wire surface - T _g temperature of the impinging gas molecules - T _H temperature of the hot surface - T _i temperature of the incident gas stream - T _r temperature of the gas molecules receding after collision with the solid surface - T _s temperature of the solid surface Greek Symbols thermal accommodation coefficient for the gas—solid surface - resistivity of the metal wire - gas coverage on the solid surface For an explanation of symbols, see Nomenclature.     

扫描速度对硼铸铁气缸套表面钨极氩弧硬化效果的影响

研究了钨极氩弧扫描速度对硼铸铁表面硬化效果的影响规律。结果表明：扫描速度增加,硬化层宽度、深度减小,而硬度提高,裂纹率增大；硬化层硬度沿层深的分布是从表及里由高而低,在过渡区下降缓慢；沿层宽的分布是层中心最高,向两侧逐渐降低,直至硼铸铁基体达到最低值；在保证不出现裂纹的条件下,硬化层表面的最高硬度值可达61．4HRC,硬化层最高显微硬度值可达1156．4HV0．1；硼铸铁材料采用氩弧热源淬火时,淬硬层与基体之间过渡区明显,硬化区组织为莱氏体,过渡区为马氏体、残余奥氏体和少量石墨。     

脉冲进气旋转喷吹技术的水力模拟

在铝合金熔体净化旋转喷吹技术的基础上 ,采用水力模拟实验研究了脉冲进气方式对气泡大小的影响。实验结果表明 :脉冲进气方式有利于产生射流 ,使气泡变小 ,并增加了气泡与熔体接触的比表面积 ,从而改善了除氢的动力学条件 ,有利于提高除氢效果。     

冷却条件对超级钢钨极氩弧焊焊接接头组织性能的影响

采用钨极氩弧焊焊接方法对400MPa级超级钢进行焊接，并对焊后空冷和水冷两种冷却条件下的焊接接头进行了组织性能分析。研究结果表明，水冷条件下，其接头的综合力学性能要优于空冷条件，可以应用与实际生产。     

Decarburization rate of RH refining for ultra low carbon steel

The decarburization behaviors of ultra low carbon steel in a 210-t RH vacuum degasser were investigated under practical operating conditions.According to the apparent decarburization rate constant (KC) calculated by the carbon content in the samples taken from the hot melt in a ladle at an interval of 1-2 min,it is observed that the total decarburization reaction period in RH can be divided into the quick decarburization period and the stagnant decarburization period,which is quite different from the tradit...