Removal of As(V) Ions from Solution by Akaganeite bgr-FeO(OH) Nanocrystals

The original method is developed for producing the new inorganic sorption material of akaganeite bgr-FeO(OH). The material in question is characterized relative to arsenic contained in aqua. The possibility is established for removing arsenate ions from water by contemporary physicochemical methods.     

土壤中石油污染物微生物降解及其降解去向

通过多因素对比预实验，将筛选出的7个石油烃降解的主要影响因素以正交表方法组合起来，对其进行了实验研究。探讨了石油迁移转化对于各种土壤物理化学条件及其他环境因素改变的敏感程度，并找出了各主要影响因素的重要性和最佳水平；测定了土壤中所存在的石油污染物在生物降解作用下的后期产物，研究了不同条件下的样品残留污染物组分之间的差异。影响土壤中石油烃类降解的主要因素有土壤石油污染强度、营养物(NH4NO3、K2HPO4)、氧化剂(3%H2O2溶液)、表面活性剂(TW80)、温度、土壤含水率和土壤透气性；在降解的不同阶段，各个因素的重要性以及最佳水平会发生相应的变化；在生物降解后期，土壤中残留的石油污染物主要是正构和异构烷烃；正构烷烃的色谱图由原来的对称钟形变为左陡右缓的偏钟形；异构烷烃所占比重增大，正十五烷和正二十一烷之间的谱图基线被明显抬高。     

Fabrication of Arsenic Sulfide Optical Fiber with Low Hydrogen Impurities

Arsenic sulfide glass optical fibers typically possess extrinsic absorption bands in the infrared wavelength region associated with residual hydrogen and oxygen related impurities, despite using purified precursors. We report a purification process based on the addition of tellurium tetrachloride (TeCl₄) to the glass. During melting, the chlorine from TeCl₄ reacts with the hydrogen impurities to produce volatile products (e.g., HCl) that can be removed by subsequent dynamic distillation. The processing conditions have been modified accordingly to produce optical fibers with significantly reduced loss due to hydrogen sulfide impurity content (1.5 dB/m).     

镇沅金精矿选择性固砷焙烧—氰化浸出新工艺研究

对云南镇沅金矿的难当金精矿进行了选择性固砷焙烧－氰化浸出的试验研究，取得了满意结果。砷固定率大于９２％，硫挥发率为７８％－８４％，金浸出率可达９１％－９３％。选择性固砷焙烧－氰化浸出新工艺可有效消除砷害，综合利用有价成分硫，特别适宜于含砷高硫，同时含碳等杂质的细粒浸染型难浸金矿石的处理，在我国有较大的发展前景。     

不同浊度下的泥沙对水体镉、铅、砷去除的影响分析

针对流域突发性重金属污染,不同浊度下的泥沙对重金属有一定的去除效果。以浊度为指示指标,通过试验研究了常温(25 ℃)和低温(5 ℃)条件下浊度50～650 NTU(Nephelometric Turbidity Unit)范围内泥沙对重金属镉、铅、砷吸附去除的影响。试验结果表明:泥沙对重金属镉、铅、砷的去除效果为铅＞镉＞砷,其中铅的去除率达到99%。浊度与能处理达标的最高重金属浓度呈线性关系,常温下浊度与能处理达标的最高镉、铅、砷浓度关系曲线的相关系数分别为0.996、0.998、0.999,低温下其相关系数分别为0.999、0.996、0.998。常温较低温更利于泥沙对重金属镉、铅、砷的去除,能去除更高浓度的重金属,达到生活饮用水卫生标准。     

河套盆地晚更新世以来黄河改道对高砷地下水分布的控制机制

针对河套盆地开展了历时多年的水文地质环境地质调查,利用采集的298组浅层地下水样品以及收集并甄选的382个水文地质钻孔记录分析发现:河套盆地内95%的高砷地下水(As质量浓度10μg/L)集中在黄河决口、改道形成的古河道影响带及黄河决口扇裙带。其中,盆地南部首次发现了较为集中的高砷地下水,其分布范围与黄河北岸的晚更新世以来黄河决口、改道形成的4个大型决口扇,在空间上有着良好的对应关系。黄河古河道带及决口扇裙带表现为较强的还原环境及蒸发浓缩作用以及较弱的地表水补给强度。受pH值、含铁氧化物的还原性溶解等因素影响,决口扇裙带浅层地下水中砷的含量略低于平原中部黄河古河道带。结果表明:黄河古河道带及决口扇裙带特定的沉积环境控制着地下水的水文地球化学过程,进而对高砷地下水的分布具有决定性的作用。     

Novel technology of purification of copper electrolyte

The effects of arsenic with different valence states on the purification of copper electrolyte were studied and a novel technology of purification of copper electrolyte by copper arsenite was proposed. The results show that the purification performance of As（Ⅲ） compounds is better than that of As（Ⅴ） compounds. The purification technology by copper arsenite has the advantages of simple operation, high purification performance and low cost in comparison with other technologies and its appropriate purification conditions are that copper arsenite concentration is 18 g/L, reaction temperature is 65 ℃ and reaction time is 8 h. The removal rates of Sb and Bi are 53.22% and 58.67% respectively under these conditions. The purification principle show that a kind of yellow precipitate mainly composed of arsenic, antimony （ Ⅴ ）, bismuth and oxygen forms in electrolyte after copper arsenite is added, and consequently antimony and bismuth are removed from electrolyte.     

氢化物发生-原子荧光光谱法测定铬矿中砷

铬矿中砷的测定方法对完善铬矿检测方法和质量评价手段有重要意义。在0.5 g样品中加入2 g过氧化钠,于650 ℃熔融20 min,熔融物经盐酸酸化溶解,以10%盐酸为载流,15 g/L硼氢化钾溶液为还原剂,采用氢化物发生-原子荧光光谱法(HG-AFS)进行测定,建立了铬矿中砷测定的新方法。实验表明,砷质量浓度在0.025～100 μg/L范围内与荧光强度呈线性关系,相关系数为1.000 0,方法检出限为0.05 μg/g,定量限为0.17 μg/g。对产地为南非、土耳其、巴基斯坦等19个国家共2 649个铬矿样品的成分进行统计,发现铬矿主要成分为铬、铁、镁、铝和硅;干扰试验表明,这些样品中的共存元素均不干扰测定。按照实验方法对3个不同砷含量的铬矿样品进行精密度和加标回收试验,结果的相对标准偏差(RSD,n=11)为1.4%～6.0%,回收率为96%~109%。将实验方法应用于与铬矿基体近似的铁矿标准物质中砷的测定,测定值与认定值基本一致。