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排序方式: 共有5578条查询结果,搜索用时 15 毫秒
1.
Amirhossein Moghanian Saba Nasiripour Atiyyeh Koohfar Mohammad Sajjadnejad SeyedMohammad Hosseini Mohsen Taherkhani Zahra Miri Seyed Hesamedin Hosseini Mehrnaz Aminitabar Ali Rashvand 《International Journal of Applied Ceramic Technology》2021,18(5):1430-1441
Bioactive glasses (BGs) have been used for bone formation and bone repair processes in recent years. This study investigated the titanium substitution effect on 58S BGs (Ti-BGs) 60SiO2-(36 − X)CaO-4P2O5-XTiO2 (X = 0, 3, and 5 mol.%) prepared by the sol-gel technique, and the main goal was to find the optimum amount of titanium in Ti-BGs. Synthesized BGs, which were investigated after immersion in simulated body fluid (SBF), were tested by X-ray diffraction (XRD) analysis, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy. Moreover alkaline phosphate (ALP) activity, 3-(4,5dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay, and antibacterial studies were employed to investigate the biological properties of Ti-BGs. According to the FTIR and XRD test results, hydroxyapatite (HA) formation on Ti-BGs surfaces was confirmed. Meanwhile, the presence of 5 mol.% compared to 3 mol.% increased the HA grain distribution and their size on the Ti-BGs surface. Additionally, MTT and ALP results confirmed that the optimal amount of titanium substitution in BG was 5 mol.%. Since 5 mol.% Ti incorporated BG (BG-5) had the highest biocompatibility level, antibacterial properties, maximum cell proliferation, and ALP activity among the synthesized Ti-BGs, it is presented as the best candidate for further in vivo investigations. 相似文献
2.
The synthesis of BaMgAl10O17∶ Eu2 (BAM) phosphors using the sol-gel method and their luminescence properties were reported. The blue-light emitting BAM was synthesized using citric acid and ethylene glycol as chelating materials. Emission of blue-light was obtained from these phosphors. The luminescent intensity increases as the temperature of heat treatment is increased. This study investigated the effects of the molar ratio of ethylene glycol to citric acid (Φ value), with respect to the phase formation and luminescence properties of BAM. The variation of the Φ value resulted in the change of the sol-gel reaction mechanism and the microstructures of the resultant powders. An increase in Φ value leads to an increase in the rate of BAM phase formation. The photoluminescent intensity of the prepared phosphors increases with heating temperatures because of enhanced crystallization. 相似文献
3.
BaFe12O19/SiO2-B2O3微晶玻璃陶瓷的制备和微波性能 总被引:1,自引:0,他引:1
采用柠檬酸sol-gel工艺合成了BaFe12O19/SiO2-B2O3微晶玻璃陶瓷,研究了SiO2-B2O3玻璃的含量,Ba/Fe原子比和热处理温度对体系析出晶相的影响,以及介电常数和磁异率在1MHz-6GHz频率范围的变化规律,结果表明,休系中SiO2-B2O3玻璃的含量和Ba/Fe比越高,BaF312O19相的析出越困难,前驱体合适的热处理温度为1000℃,介电常数和磁导率基本上随测试频率的增而加下降;介电损耗的最大值为0.43,磁损耗较小。 相似文献
4.
LaNiO3 was synthesized by sol-gel method in which lanthanum nitrate and nickel nitrate were used as start materials and citric acid was used as complex for gel formation.The precursor was dried and subsequently heated at elevated temperature to form the desired product.XRD analysis shows that pure LaNiO3 was synthesized.Electrical conductivity and electrochemical performance of the material were tested.The electrical conductivity decreases from 34.5that there are current peaks in the curve, which is the evidence of the electrochemical activity of LaNiO3. 相似文献
5.
K. Y. Cheah T. S. Tang Fujio Mizukami Shu-ichi Niwa Makoto Toba Y. M. Choo 《Journal of the American Oil Chemists' Society》1992,69(5):410-416
A new catalyst, ruthenium-tin-alumina is found to selectively hydrogenate oleic acid to 9-octadecen-1-ol (oleyl + elaidyl
alcohol) at low pressure with high yield. Catalyst preparation methods, catalyst raw materials and activation conditions have
a significant effect on the activity of the catalyst. The optimum atomic ratio of ruthenium to tin is about 1:2. Catalyst
prepared by an improved sol-gel method shows higher activity and selectivity than catalysts prepared by impregnation and coprecipitation
methods. Chloride is found to have a negative effect on catalytic activity. The best catalyst is prepared from chloride-free
ruthenium and tin raw materials. Under the optimum reaction conditions of 250°C and 5.6 MPa, the selectivities for 9-octadecen-1-ol
and total alcohol (9-octadecen-1-ol + stearyl alcohol) formation are 80.9% and 97%, respectively, at a conversion of 81.3%. 相似文献
6.
Control over crystallographic orientation in ceramic thin films is important for highly anisotropic structures. Layered perovskites, like Bi4 Ti3 O12 , have interesting properties associated with their ferroelectric nature, which may be fully exploited only when films are highly textured. Textured films of this titanate were fabricated via a sol–gel technique without using epitaxial growth. Orientation in the film is confirmed by XRD and SEM, and supported by refractive index and dielectric measurements. In an attempt to explain the orienting effect, light scattering experiments were conducted to yield information about the molecular size, shape, and conformation of macromolecules as the sol–gel solution ages and condensation reactions proceed. These experiments clearly show an increase in the size of molecular clusters with time. We believe that it is the organization of these large clusters during spin coating, and the relationship of the backbone chemistry to the crystal structure of Bi4 Ti3 O12 , that are responsible for the observed orientation. 相似文献
7.
YAG:Ce Phosphors for WLED via Nano-Pesudoboehmite Sol-Gel Route 总被引:5,自引:0,他引:5
The sub-micron sized YAG : Ce phosphors were synthesized via a modified sol-gel method by peptizing nano-pesudoboehmite particulate. It is found that YAG phase from the dried gel powders appears at 1000 ℃ then the pure YAG phase exists at a relatively lower sintering temperature of 1400 ℃. The smaller sizes of phosphors in the ranges of 1 - 3 μm are obtained due to the contribution of seeding effects of nano-sized alumina particles to strengthen each step of the processes. Both the excitation and emission spectra of photoluminescence of the phosphor obtained at 1400 ℃ meet well with the spectroscopic requirements of the WLED phosphors. 相似文献
8.
采用两步溶胶–凝胶法制备出 ATO(掺锑氧化锡)-SiO_2复合抗静电薄膜。通过 DTA-TG、XRD、SEM 对 薄膜的结构和形貌进行了表征,结果表明:抗静电复合薄膜表面均匀致密。薄膜中 SiO_2为无定形结构,ATO 的衍射峰 与 SnO_2一致。研究了 SnO_2的含量对薄膜导电性能、结合强度和透过率的影响,发现随 SnO_2含量增加 ?(SnO_2/ SiO_2)从 5 至 12.5,薄膜的表面电阻降低(从 1010ù/□降低到 108ù/□),薄膜的结合强度下降,薄膜的透过率降低(从 89.0%降至 84.2%),结合三方面性能,得出最佳 SnO_2的配比为:?(SnO_2/ SiO_2)=10。 相似文献
9.
10.