Thermal transport and chemical conversion in single reacting sorbent particles

The effects of particle size and carbon dioxide concentration on chemical conversion in engineered spherical particles undergoing calcium oxide looping are investigated. Particles are thermochemically cycled in a furnace under different carbon dioxide concentrations. Changes in composition due to chemical reactions are measured using thermogravimetric analysis. Gas composition at the furnace exit is evaluated with mass spectroscopy. A numerical model of thermal transport phenomena developed previously is adapted to match the physical system investigated in the present study. The model is used to elucidate effects of reacting medium characteristics on particle temperature and reaction extent. Experimental and numerical results show that (1) an increase in particle size results in a decrease in carbonation extent, and (2) the carbonation step consists of fast and slow reaction regimes. The reaction rates in the fast and slow carbonation regimes increase with increasing carbon dioxide concentration. The effect of carbon dioxide concentration and the distinction between the fast and slow regimes become more pronounced with increasing particle size.     

集中药包与条形药包爆破漏斗及抛掷堆积研究

把集中药包拉成条形药包之后，其爆破漏斗变化有多大?条形药包能否改善抛掷堆积?可否用集中药包的爆破漏斗参数(n、R、R’、P)及经验方法来设计条形药包的爆破漏斗?本试验研究将回答这些问题。     

Preparation of flexible polyhedral particles via concentrated emulsion templating polymerization

This paper presents recent efforts on the preparation of flexible polyhedral particles via concentrated emulsion templating polymerization in which the hydrophilic monomer (acrylamide) and hydrophobic monomer (butyl acrylate) are polymerized simultaneously in the continuous and dispersed phase, respectively. Such templating polymerization has been enhanced in our systems owing to the introduction of acrylamide monomer and their higher polymerization rate in continuous phase as compared with butyl acrylate in dispersed phase. Diffusion between the different phases was also inhibited. Furthermore, the stability of the concentrated emulsion and the molecular weight of the produced poly(butyl acrylate) were found to be significantly affected by the amount of redox initiator. The morphology of the particles could be controlled by varying the volume fraction of the dispersed phase and the polyhedral particles were achieved at higher volume fraction. Copyright © 2005 Society of Chemical Industry     

Ennoblement of stainless steel in natural seawater – A new explanation

The ennoblement of corrosion potential (E_corr) of passive metal immersed in seawater was investigated with electrochemical technology and epifluorescence microscopy. The in situ observation showed that the bacteria number increased on the metal surface according to an exponential law which was in the same way with the ennoblement of E_corr. At the same time, the anodic polarization current of high‐Mo stainless steel decreased in the initial days. According to the mix‐potential theory and the characteristics of polarization curves of high‐Mo steel in natural seawater, the ennoblement of corrosion potential may be induced by the decrease of the passive current density.     

利用网络技术实施财务集中控制

针对企业集团分权化管理的缺点，设计出一套利用互联网络技术实现企业集团财务集中控制的模式，给出了模式的图示及说明。     

Structural Disruption of Toothpastes Under Deformation — An Easy Release of Active Ingredients

The author suggests a technological approach relevant to the optimization of toothpaste compositions with regard to the easy release of the therapeutic ingredients under shear deformation. It is based on the comparative assessment of the steady‐state viscous behaviour of placebo samples (mixtures containing all the components except the therapeutic ingredients) and the final products. It is presumed that the maximum beneficial effect of the toothpastes, as therapeutic agents, is achieved if the final products and the placebo blends display similar shear‐thinning characteristics.     

Rheological behaviour of concentrated yeast suspension

The effect of yeast cell volumetric concentration on the rheological properties of the suspensions was measured in a pipe-flow viscometer at 30°C: at low microbial concentrations the suspensions were Newtonian; however, non-Newtonian behaviour, which could be described by the power-law equation, was observed with suspensions at high microbial volumetric concentrations. At conditions of constant microbial morphology and growth rate, the results also indicated that a relationship could be developed between the power-law constants and the microbial volumetric concentration.     

集中载荷作用下的套管抗挤能力分析

根据油田套管损坏情况,建立了集中载荷作用下的套管抗挤能力计算模型,利用能量法和曲杆理论,分析研究了承受180°对称分布集中载荷、90°均匀分布集中载荷和120°均匀分布集中载荷下中厚壁套管抗挤能力,得出了理想圆管抗挤强度和套管屈曲临界挤毁压力的计算公式,通过分析比较理论解与有限元解,其最大相对误差不超过1%,得出了套管抵抗局部载荷的能力低于抵抗均布载荷的结论。     

A fatigue-life prediction methodology for notched aluminum-magnesium alloy in gulf seawater environment

Local-strain and linear-elastic fracture-mechanics (LEFM) methodologies have been investigated for prediction of the corrosion-fatigue life of notched components of specially developed Al-2.5Mg alloys exposed to Arabian Gulf seawater environment. Corrosion-fatigue crack initiation life estimates were obtained using strain-life relationships; corrosion-fatigue crack propagation life estimates were obtained using LEFM relationships. The total corrosion-fatigue life was considered to be the sum of the crack initiation and crack propagation lives. Estimated corrosion-fatigue lives were compared with experimentally obtained corrosion-fatigue life data using center-notched specimens of three types of Al-2.5Mg alloys (containing different amounts of chromium) exposed to Arabian Gulf seawater environment. Two notch geometries, a circular notch (K _t= 2.42) and an elliptical notch (K _t= 4.2), were investigated. Good corrosion-fatigue life predictions can be obtained using local-strain and LEFM methodologies by determining the relevant material constants via a few simple fatigue tests on smooth specimens and a few crack-growth-rate tests in the environment at the frequency of interest.     

浓硝酸装置高压釜技术改造的探讨

简要介绍淮化集团浓硝酸生产工艺，通过对热发烟硝酸生产的关键设备高压釜的进料管，筛板的改造，增加氧气压力，提高N2O4纯度等工艺调整，使高压釜的生产能力由原设计的12.8t热酸／h增加到38.6t热酸／h。