全文获取类型
收费全文 | 1886篇 |
免费 | 173篇 |
国内免费 | 134篇 |
专业分类
电工技术 | 32篇 |
综合类 | 101篇 |
化学工业 | 776篇 |
金属工艺 | 189篇 |
机械仪表 | 28篇 |
建筑科学 | 53篇 |
矿业工程 | 56篇 |
能源动力 | 68篇 |
轻工业 | 185篇 |
水利工程 | 5篇 |
石油天然气 | 39篇 |
武器工业 | 6篇 |
无线电 | 105篇 |
一般工业技术 | 432篇 |
冶金工业 | 78篇 |
原子能技术 | 23篇 |
自动化技术 | 17篇 |
出版年
2024年 | 6篇 |
2023年 | 51篇 |
2022年 | 78篇 |
2021年 | 84篇 |
2020年 | 77篇 |
2019年 | 68篇 |
2018年 | 75篇 |
2017年 | 86篇 |
2016年 | 67篇 |
2015年 | 49篇 |
2014年 | 77篇 |
2013年 | 114篇 |
2012年 | 105篇 |
2011年 | 128篇 |
2010年 | 78篇 |
2009年 | 121篇 |
2008年 | 94篇 |
2007年 | 122篇 |
2006年 | 121篇 |
2005年 | 90篇 |
2004年 | 91篇 |
2003年 | 77篇 |
2002年 | 68篇 |
2001年 | 48篇 |
2000年 | 38篇 |
1999年 | 38篇 |
1998年 | 27篇 |
1997年 | 21篇 |
1996年 | 24篇 |
1995年 | 11篇 |
1994年 | 9篇 |
1993年 | 9篇 |
1992年 | 11篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有2193条查询结果,搜索用时 15 毫秒
1.
2.
Nitrile rubber (NBR) blends with excellent performance have always been a hot research topic in petroleum field. Due to the excellent performance and compatibility of polyamide 6 (PA6), it provides an opportunity for the preparation of high-performance NBR/PA6 blends. In this article, NBR/PA6 blends were prepared by the three-step molding process. Experimentally, it was found that PA6 has a prominent reinforcement effect in NBR matrix. The variation of this mechanical property was investigated from different aspects of the crystal structure, crystallinities, phase morphology, and so on. It can be cleared that the formation of fibrous structure of PA6 phase is the main factor for reinforcement of the polymer blends. Meanwhile, the formation mechanism of the special phase structure induced by the three-step process is deeply expounded and its structural evolution schematic is established. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47472. 相似文献
3.
Yong Liu Kangzhuang Chen Fengbo Dong Shuai Peng Yongjie Cui Chenyu Zhang Keqing Han Muhuo Yu Hui Zhang 《Ceramics International》2018,44(9):10199-10203
In this paper, polyborosilazane precursor was synthesied from HMDZ, HSiCl3, BCl3 and CH3NH2 using a multistep method. By controlling the storage conditions, parts of the polyborosilazane fibers were hydrolyzed. FT-IR, NMR, XRD, TEM and monofilament tensile strength test were employed to study the effects of hydrolysis of precursor on the structures and properties of polymer-derived SiBN ceramic fibers. FT-IR and NMR results indicate that Si-N group in PBSZ reacts with H2O to form Si-O-Si group. After pyrolysis reaction at 1400℃, Si-O-Si group will finally transformed into highly ordered cristobalite and β-quartz, resulting in formation of the wrinkled surface of the obtained SiBN ceramic fiber. The strip-like defects on fiber surface, according to monofilament tensile strength test, had a significant effect on mechanical property of the obtained SiBN ceramic fiber and caused no increase in fiber tensile strength of hydrolytic polyborosilazane fiber before and after pyrolytic process. 相似文献
4.
Yingchao Hu Wenqiang Liu Yuandong Yang Xianliang Tong Qianjun Chen Zijian Zhou 《Ceramics International》2018,44(14):16668-16677
Li4SiO4 sorbents for high-temperature CO2 removal have drawn extensive attention owing to their potential application in carbon capture and storage (CCS). The major challenge in the application lies in the poor CO2 capture performance under realistic conditions of low CO2 concentrations, owing to the dense structure and poor porosity. In this work, Li4SiO4 sorbents were prepared with porous micromorphologies and large contact areas using a variety of organometallic Li-precursors, achieving fast CO2 sorption kinetics, high capacity and excellent cyclic stability at a low CO2 concentration (15?vol%). It was found that a high conversion of ~?74% was maintained for pure Li4SiO4 even after 100 sorption/desorption cycles. Moreover, by doping with Na2CO3 to reduce the CO2 diffusion resistance, the conversion of the sorbent was further enhanced to 93.2%. The enhancement mechanism of alkali carbonate have been proven here to be ascribed to the formation of the eutectic melt of Li/Na carbonates, the existence and function of which has been confirmed in this study. 相似文献
5.
Renjith Devasia CP Reghunadhan Nair P Sivadasan KN Ninan 《Polymer International》2005,54(8):1110-1118
Polyacrylonitrile terpolymers of various compositions consisting of acrylonitrile (AN), itaconic acid (IA) and methyl acrylate (MA) were synthesized by solution polymerization in dimethylsulfoxide. Increase in concentration of either IA or MA retarded the overall polymerization rate and the polymer molecular weight. The system consisting of AN + MA and varying IA concentration was more prone to retardation in comparison with the system composed of AN + IA with variable MA concentration. The retardation factors were quantified. Minor quantities of MA boost the reactivity of IA in the terpolymer system. The terpolymer was richer in MA vis‐à‐vis the feed. The thermal characteristics of the terpolymer were examined as a function of its composition. In contrast to the copolymer of AN and IA requiring 1–1.5 mol% IA, the terpolymer required an IA content of approximately 2.5 mol% for optimum thermal stability. The polymer with 90 mol% AN, 2.5 mol% IA and 7.5 mol% MA exhibited reasonably good char‐forming characteristics and thermal stability. The overall crystallinity and crystallite size of the polymers were found to decrease on incorporation of the comonomers. The ‘aromatization index’ of the copolymer increased with the temperature of pyrolysis through re‐organization of the tetrahydropyridine ladder structure. Copyright © 2005 Society of Chemical Industry 相似文献
6.
聚合物-金属界面相形貌的研究 总被引:1,自引:0,他引:1
环氧树脂在 Al 合金表面生成纤维状的界面相结构,其形成、发展和特征与树脂的体系、交联反应条件以及 Al 合金的表面状态有关。环氧树脂的基础相为颗粒状的超结构组织。聚合物界面相的力学破坏表现为纤维体的拉伸、变形和断裂,而基础相在纯剪切受力时出现在45°方向的裂纹,并发展导致连接层的破坏。 相似文献
7.
Esabi B Kurbanoglu 《Journal of the science of food and agriculture》2003,83(11):1134-1138
Production of the fungus Aspergillus niger NRRL 330 was studied in submerged fermentation with ram horn hydrolysate (RHH) as substrate. The characteristics of RHH have been reported previously. The RHH was enriched by addition of glucose and KH2PO4. The effects of kinetic parameters on the biomass yield of the fungus were investigated. The optimal conditions for growth of A niger on RHH were initial pH 6.5, temperature 30 °C, fermentation time 96 h and agitation speed 150 rpm. Under these optimal conditions the initial carbohydrate content of RHH was reduced from 1.52 to 0.2% and the biomass yield was 8.9 g l?1. The biomass contained about 48.1% protein, 5.2% fat and 9.4% ash (on a dry weight basis). The amino acid content of the biomass was compared with Food and Agricultural Organisation (FAO) and animal feed standards. The protein produced contained all the essential amino acids for animal feed, but the amounts of these amino acids were somewhat lower than those of FAO and soybean reference protein. However, the amino acid composition of the biomass was better than that of animal feed. The results with RHH were also compared with previously reported data on fungal mycelium grown on waste liquor substrate. In conclusion, it was found that RHH could be used as a substrate in the production of fungal protein for use as animal feed. Copyright © 2003 Society of Chemical Industry 相似文献
8.
This two-part paper presents a closed-form procedure for evaluation of estimates of local thermomechanical stress fields in two-phase fibrous composites and laminates. The first part is concerned with a unidirectional elastic laminate subjected to uniform mechanical loads and to uniform changes in temperature. Both phases are assumed to be elastic, with temperature-dependent moduli and expansion coefficients; the solution reflects the influence of thermomechanical interactions. Exact solutions are not possible for any real system, because the local geometry is not known in detail. Instead, estimates of the fields are found from a modified Mori-Tanaka approximation. Examples are presented for two SiC/Ti---Al---Nb composites. Local stresses of interest are found after cooling from fabrication to room temperature. The presence of local yielding, and the influence of coupling terms on the local stress magnitudes are examined. Extension of the results to laminated plates is presented in Part II (Dvorak, G.J., Chen, T. & Teply, J., Composites Science and Technology, 43 (1992) 359–368, this issue). 相似文献
9.
10.
Free‐radical solution copolymerization of itaconic acid and acrylonitrile was carried out in DMSO using azodiisobutyronitrile as an initiator, changing the feed rate of itaconic acid. The resulting polymerization solution was spun to form polyacrylonitrile (PAN) precursors of carbon fibers. The precursors were treated with a CoSO4 aqueous solution on‐line. The structure and properties of untreated and treated PAN precursors and the resultant carbon fibers were characterized by SEM and TEM, a stabilization process, etc. It is suggested that CoSO4 acts as a catalyst in the formation of a ladder structure and reduces the temperature of cyclization, and the carbon fibers developed from treated PAN fibers showed improvement in the tensile strength and the Young's modulus. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 153–158, 2002 相似文献