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1.
Gas/liquid mass transfer has been investigated using a stirred vessel gas/liquid contactor using non‐Newtonian media and carbon dioxide as absorbent and gas phase, respectively. The volumetric mass transfer coefficients at different operational variables have been determined. Non‐Newtonian media (liquid phase) were prepared as aqueous solutions of sodium carboxymethyl cellulose salt. The influence of the rheological properties, polymer concentration, stirring rate, and gas flow rate on mass transfer was studied for these liquid phases. Kinematic viscosity and density experimental data were used to calculate the average molecular weight corresponding to the polymer employed. The Ostwald model has been used to fit the rheological behavior of aqueous solutions of the polymer employed as absorbent phase. Reasonably good agreement was found between the predictions of the proposed models and the experimental data of mass transfer coefficients. 相似文献
2.
Results for various types of polar compounds in SRC-11 coal-derived liquids and other fuels were obtained by one or more of the three analytical methods: non-aqueous titration, i.r. spectroscopy and h.p.l.c. Practical aspects as well as precision, accuracy and assumptions necessary for effective application of each of the methods are discussed. H.p.l.c. is applicable to the widest variety of compound types, is the most rapid, most sensitive and shows the best promise for increased development and improvement. Application and development of these techniques is a logical step toward improving process monitoring, catalyst development, toxicological screening and general fuel analysis. 相似文献
3.
Modelling of Diffuse Interfaces with Temperature Gradients 总被引:1,自引:0,他引:1
The work is devoted to capillary phenomena in miscible liquids under the assumption that they have a constant and the same density. The model consists of the heat equation, diffusion equation, and the Navier-Stokes equations with the Korteweg stress. We study several configurations corresponding to the microgravity experiments planned for the International Space Station. The basic conclusion of the numerical simulations is that transient capillary phenomena in miscible liquids exist and can produce convective flows sufficiently strong to be observed experimentally. In particular, there exists a miscible analogue to the Marangoni convection where the temperature gradient is applied along the transition zone between two fluids. Convection also appears if, instead of the temperature gradient, the case where the width of the transition zone varies in space is considered. Finally, similar to the immiscible case, miscible drops move in a temperature gradient. 相似文献
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The effect of nonuniform magnetic field on the linear and nonlinear wave propagation phenomena in two-phase pipe flow of magnetic fluid is investigated theoretically to realize the effective energy conversion system using boiling two-phase flow of magnetic fluid. Firstly, the governing equations of two-phase flow based on the unsteady thermal nonequilibrium two-fluid model are presented and the linear void wave propagation phenomena in boiling two-phase flow are numerically analyzed by using the finite volume method. Next, the nonlinear pressure wave propagation in gas-liquid two-phase flow is numerically analyzed by using the finite different method. According to these theoretical studies on the wave propagation phenomena in two-phase flow of magnetic fluid, it seems to be a reasonable proposal that the precise control of the wave propagation in two-phase flow is possible by effective use of the magnetic force. 相似文献
6.
Five new salts based on 1-alkyl-2-methyl pyrrolinium ion are reported, two involving the iodide ion and three involving the bis(trifluoromethanesulfonyl) amide ion. The iodide salts have melting points around 100 °C, while the amide salts have melting points around room temperature. Two of the amide salts can be easily quenched into the glassy state and exhibit glass transition temperatures around −70 °C. The 2-methyl pyrrolinium cation bears structural similarities to the aromatic imidazolium cations on one hand and the cyclic ammonium cation family based on the pyrrolidinium cation on the other. The properties of the salts reported here are compared within these two related families of salts. 相似文献
7.
Roberta Bomparola Alessandro Lavacchi Ugo Bardi 《Surface & coatings technology》2007,201(24):9485-9490
The influence of temperature on the kinetics and the morphology of silver deposits obtained from an air and water-stable ionic liquid (the 1-butyl-3-methyl imidazolium tetrafluoroborate) was studied by means of cyclic voltammetry and chronoamperometry. The nucleation and growth mechanisms have been investigated and the effect of temperature evaluated up to 200 °C. Dense, pure and very thin (about 0.3 μm) silver coatings, with decorative properties, have been obtained on commercial copper electrodes at different temperatures. The characterization of the deposits morphology has been performed by visual investigation and SEM microscopy. Data about thickness were acquired by Calotest® measurements. The deposits result constituted by pure silver as determined by combination of EDX microanalysis and Auger Electron Spectroscopy (AES). The deposition method promises to be a new, environmentally friendly, method for silver electrodeposition which is the reason for the absence of cyanide and volatile toxic solvents in the electroplating bath. 相似文献
8.
Michael Maiwald Hongping Li Thorsten Schnabel Kay Braun Hans Hasse 《The Journal of Supercritical Fluids》2007,43(2):267
On-line NMR spectroscopy can beneficially be applied to studies of supercritical and near-critical fluids as an alternative to optical spectroscopy. Up to now high pressure NMR experiments are predominantly accomplished using custom made NMR batch reactors. The authors present a novel high pressure cell with displacement plunger for on-line NMR experiments on compressible fluids which can be used in conjunction with commercially available SCF NMR flow probes. The on-line technique offers advantages compared to stopped flow techniques such as enhanced control of mixture composition and reaction parameters as well as the facility of engagement into the reaction. The new apparatus is used for NMR studies on hydrogen bonding of methanol in near critical and supercritical carbon dioxide up to 403 K and 35 MPa for which data on the chemical shift of the hydroxyl group and methyl group are reported and interpreted. 相似文献
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求文针对我国天然气凝液如何利用问题,结合新技术进展,进行了初步探讨,认为原料较多的场合,应以催化脱氢或芳构化作为当前的主要加工方向。对原料较少的场合,也提出一些看法。 相似文献