堇青石基玻璃陶瓷的制备与展望

介绍了制备堇青石基玻璃陶瓷的三种方法：熔融法、烧结法和溶胶-凝胶法，综述了玻璃组成、添加剂和成核剂对堇青石基玻璃陶瓷的烧结及性能的影响，并对其未来的发展进行了展望。     

A broad line n.m.r. study of oriented poly(vinylidene fluoride)

Broadline nuclear magnetic resonance measurements have been carried out for the proton resonance in oriented poly(vinylidene fluoride). The spectra in general show two component lines with distinctly different line widths. The broad component shows a high degree of molecular orientation and can be satisfactorily assigned to the crystalline regions of the polymer. The narrow component corresponds to an oriented non crystalline phase which is sufficiently constrained to allow motion about the chain axis only. An appreciable decrease in the value of the rigid mass fraction was observed in both of the samples over the temperature range examined. Our calculations indicate that this could play an important role in the temperature dependence of the pyroelectric response of this material.     

N.m.r. line shape-relaxation correlation analysis of bitumen and oil sands

The first results of the analysis of bitumen and oil sands using the recently developed n.m.r. spingrouping technique are presented. The n.m.r. relaxation experiments were carried out on bitumen, and on natural and dried oil sands samples. The results indicate that the spin-grouping can resolve and quantify several components of the samples studied. The bitumen and bitumen fraction of the oil sands are resolved according to their spin-spin relaxation times into three major groups: solid-like (rigid), solid-like (mobile) and semi-liquid. The water in the oil sands exists in two different environments. Tentatively one environment is assigned to be the bridges between the sand grains, while the other is assigned to be the clay surface. One can conclude that with spin grouping of complex mixtures the decomposition (in which components are resolved according to their dynamic state) is possible. The accuracy of such resolution is of the order of a few per cent.     

The radiation crosslinking and scission of ethylene-propylene copolymers studied by solid-state nuclear magnetic resonance

Methyl groups from chain scission and H-crosslinks have been identified by solid-state nuclear magnetic resonance in amorphous ethylene-propylene copolymers containing 23 and 36 mole % propylene after γ-irradiation to 10 MGy at 30°C. G (scission) and G (crosslink) values determined from the n.m.r. spectra and by extraction are in agreement, which suggests that the crosslinks are not clustered. This may differ from the situation in polyethylene where there is a substantial crystalline content. G(S). G(X) and the ratio G(S)/G(X) increase with increasing propylene content of the copolymers.     

高层民用建筑中水泵结合器的设置

就高层民用建筑消防设计中水泵结合器的设置问题，从水泵结合器与消防车的配套设置、水泵结合器在自喷消防系统中的设置、安全阀的设置等方面介绍了具体方法，以合理设置并消除故障。     

Pulsed field gradient n.m.r. measurements and theoretical interpretation of the self-diffusion of polystyrene in solution

The self-diffusion coefficients of polystyrene dissolved in C₆D₆ were measured by means of pulsed field gradient n.m.r.. The dependence on the molecular weight was of the power of -2 in accordance with the reptation model. The concentration dependence was theoretically calculated within the blob concept which shows that in the crossover region the self-diffusion coefficient is determined only by the blob dimensions and the monomeric friction coefficient is constant. The calculated concentration dependence agrees well with that observed by the authors.     

缓冲层对氮化镓二维生长的影响

报道了在射频等离子体（RF-Plasma)辅助的分子束外延（MBE）技术中，使用白宝石（0001）衬底，采用低温缓冲层工艺外延氮化镓（GaN)。通过原子力显微镜（AFM）的表面形貌比较及X射线双晶衍射（XRD）ω扫描摇摆曲线的分析，讨论了低温缓冲层成核机理及缓冲层生长温度与形成准二维生长的关系，确立了缓冲层的三维成核，准二维生长的生长机理，并在此基础上实现了氮化镓外延层更好地二维生长，进一步提高了氮化镓外延层的晶体质量。     

Construction and stratification of the stability domains of the linear dynamic systems with PID controllers

The regularities of motion of a point on the plane (in the space) of adjustable controller parameters at variations of the phase margin under a fixed crossover frequency were analyzed. The problem of decomposition of the stability domain into the zones with simple and complex Nyquist plots and subsequent construction of the point subset where all points satisfying the requirements on the system frequency characteristics was solved. Examples were presented.     

The distribution of anthocyanins in grape skin extracts of port wine cultivars as determined by high performance liquid chromatography

The distribution of anthocyanins in methanolic skin extracts of 16 grape cultivars used for port wine production and grown at five sites in the Douro Valley in Northern Portugal has been assessed by high performance liquid chromatography. Results are confined to the seven most readily separated and identified anthocyanins and are expressed as percentages of their total (88–99% of the total integrated area). Anthocyanins based on malvidin (Mv) predominated. Of these, Mv 3-glucoside was the major pigment (33–60%), being exceeded by Mv 3-p-coumarylglucoside (2–51%) in only two cultivars; Mv 3-acetylglucoside (1–15%) was consistently the lowest. Peonidin 3-glucoside (1–27%) was prominent in four cultivars, but delphinidin 3-glucoside (1–11%), petunidin 3-glucoside (2–11%) and cyanidin 3-glucoside (trace-6%) were of low proportions throughout. The ratio Mv 3-acetylglucoside/total Mv glucosides appeared characteristic of cultivar, independent of site, and a useful aid to identification of grape cultivars. The coloured pulp of some cultivars contained peonidin 3-glucoside as a major component, present in greater proportions than in the skin; the percentage of Mv 3-p-coumarylglucoside was lower in pulp than in skin. The identities of six of the seven anthocyanins were confirmed by fast atom bombardment mass spectrometry and the structures of the Mv derivatives were determined by nuclear magnetic resonance. The formation of formyl and acetyl anthocyanin artefacts is described.     

Effect of 0.1 at.% zirconium on the cyclic oxidation resistance ofβ-NiAl

The effect of 0.1 at.% Zr (0.2 wt.% Zr) on the cyclic oxidation of hipped rc="/content/h47558r235716445/xxlarge946.gif" alt="beta" align="MIDDLE" BORDER="0">-NiAl was studied. Oxidation testing was performed in static air at 1100–1200 °C, using 1-hr exposure cycles for test times up to 3000 hr. The weight change versus time data were modeled with the COSP computer program to analyze and predict cyclic-oxidation behavior. Zr additions significantly change the nature of the scale-spalling process during cooling so that the oxide spalls near the oxide-air interface at a relatively low depth within the scale. Without Zr, the predominantly rc="/content/h47558r235716445/xxlarge945.gif" alt="agr" align="BASELINE" BORDER="0">-Al₂O₃ scale tends to spall randomly to bare metal at relatively high effective-scale-loss rates, particularly at 1150°C and 1200°C. This leads to higher rates of Al consumption for the Zr-free aluminide and much earlier depletion of Al, leading to eventual breakaway (i.e., failure).