Investigation on the effectiveness of the repair method 8.3 “Corrosion protection by increasing the electrical resistivity” in chloride-containing concrete Part 2: Chloride redistribution in concrete after application of a system sealing surface protective coating

This DFG-funded research project aimed to gain a better understanding of the mechanisms of the W-Cl repair principle within the framework of fundamental investigations, to contribute to the creation of the necessary basis for a broader application of the repair principle in practice. The focus was on the development of a model to describe the chloride redistribution after the application of a system sealing surface protective coating. On the basis of Fick's second law of diffusion, a mathematical model with a self-contained analytical solution was developed, with the help of which the chloride redistribution after application of a system sealing surface protective coating can be calculated under the idealized assumption of complete water saturation of the concrete. Furthermore, the influence of the dehydration of the concrete, expected as a result of the application of the repair principle W-Cl, on the chloride redistribution was investigated. On the basis of laboratory tests and numerical simulations, material-specific reduction functions were developed to quantify the relationship between the chloride diffusion coefficient and the ambient humidity.     

DP980+Z烘烤硬化值与退火温度的关系

摘要：为了研究退火温度对镀锌DP980+Z烘烤硬化值的影响，退火温度控制在760～820℃之间，系统分析退火温度对烘烤硬化值的影响。通过准静态拉伸试验机测量烘烤硬化值及抗拉强度，采用lepara试剂对组织中的马氏体进行着色，利用金相显微镜及图像处理软件测量马氏体的体积分数；采用扫描电镜观察DP980+Z的双相组织特点，并且将组织图片通过CAD转化成有限元图进行网格划分，建立代表性体积单元（RVE），通过有限元分析铁素体、马氏体强度对烘烤硬化值的影响。在同样的变形量情况下，DP980+Z的原始屈服强度越高，烘烤硬化值越高。     

Studies on chitin 3—effect of coagulants and annealing on the preparation and the properties of chitin membrane

Chitin membrane was prepared by casting a N,N-dimethyl acetamide, N-methyl 2-pyrrolidone and lithium chloride (DMA-NMP-LiCl)solution of chitin and coagulating with several media. The effect of the coagulants on membrane formation was studied. 2-Propanol was found to be more favourable than methanol, ethanol, acetone and mixtures of 2-propanol and water. The membrane obtained in 2-propanol was subjected to annealing. Annealing made the membrane dense and strong. The tensile strength of the membrane annealed at 145°C for 2hr was about twice that of an unannealed membrane. The solute permeability of the annealed membranes was lower than that of the original one. These phenomena could be clearly interpreted in terms of crystallinity.     

醋酸铅在离子液体中溶解机理的研究

通过[bmim]Cl和Pb(OAc)2混合反应后析出PbCl2沉淀,制备得到溶解有醋酸铅的离子液体[bmim]OAc。实验发现,即使使用过量的醋酸铅,PbCl2仍然不能沉淀完全,这表明离子液体中的Pb2+离子并不是以游离形式存在的,而是以配位的形式存在,并且由离子液体包裹着。因此,醋酸铅在离子液体[bmim]OAc中的溶解度得到增加,平均溶解度达到1 1mmol/ml,最大溶解度达到3 0mmol/ml。     

Extension of the QUASAR River-Water Quality Model to Unsteady Flow Conditions

A modification of the well-known water-quality model 'quality simulation along river systems'(QUASAR) is presented in order to extend its ability, so that it may be considered applicable under unsteady-flow conditions. An aggregated dead-zone travel-time parameter, based on (a) the kinematic wave velocity (celerity) of the flow wave and (b) the behaviour of the solute within so-called 'dead zones', has been incorporated into the existing model formulation. This extends the current continuously-stirred tank reactor-based model process to account for the behaviour of solute under unsteady-flow conditions. The enhanced water-quality model has been validated by application to the Colorado River.     

VARIATIONS IN ALFALFA JUICE SOLUTE CONCENTRATIONS AS WATER IS EVAPORATED

Alfalfa juice was extracted from plants during the graving phases of the first and second crops. The alfalfa juice was dried and solute concentrations were measured periodically during the process using freezing point depression (FPD) as an indicator. Solute/solvent weight ratios were calculated from the freezing point depression of fresh unconcentrated 'uice extracted from both firsc and second crops. At the time of harvest, tie FPD was a function of this ratio. The first and second crops behaved distinctively different during the drying process, with the second having a larger soluce concentration and a greater FPD at a given moisture content. The appearance of preci itate during the drying process and the general1 large FPD makes this materiay a questionable product for drying vitg low temperature processes.     

A physically based method for triangulated surface flattening

This paper introduces a new method of generating 2D flat patterns from a 3D triangulated surface by opening the bending configuration of each winged triangle pair. The flattening can be divided into four steps. First, a 3D triangulated surface is modeled with a mass-spring system that simulates the surface deformation during the flattening. Second, an unwrapping force field is built to drive the mass-spring system to a developable configuration through the numerical integration. Third, a velocity redistribution procedure is initiated to average velocity variances among the particles. Finally, the mass-spring system is forced to collide with a plane, and the final 2D pattern is generated after all the winged triangle pairs are spread onto the colliding plane. To retain the size and area of the original 3D surface, a strain control mechanism is introduced to keep the springs from over-elongation or over-shrinkage at each time step.     

Distribution and segregation of solute in Al2O3 short fiber reinforced Al-5%Cu alloy containing La by squeeze casting

Al2O3 short fiber reinforced La-bearing Al-5%Cu alloy was fabricated by squeeze casting, and the solidified structure and the solute segregation during alloy solidification were studied. The results indicated that La has been enriched near the interface which is favorable to improve the wettability between the fiber and Al alloy, but the RE-rich phase was not formed at the interface. At the end of the solidification of the composites, the change of the solute in the surplus liquid phase results in the type of matrix alloy being changed because of the selective crystallization, and the segregation at the interface is finally formed. There is no special influence by La on the Cu segregation in the matrix alloy.     

高压水冷器(E5104)的换热管腐蚀原因分析

应用光学显微镜、扫描电镜能谱和X射线衍射分析对 炼油厂加氢精制装置高压水冷器(E5104)的换热管腐蚀原因进行了分析.结果表明，循环水 中的溶解氧腐蚀导致换热管外壁产生鼓包，最终使鼓包处穿孔，是换热管腐蚀损坏的主要原 因.     

稀土La对Al-Si合金复合材料凝固组织与溶质偏析的影响

利用挤压铸造法制备了Al2O3/Al-Si-La复合材料;研究了稀土La对复合材料凝固组织以及基体合金凝固时溶质偏析的影响。结果表明,稀土La可细化基体合金的凝固组织,La富集在界面附近,有利于改善铝合金液对氧化铝短纤维的润湿性,但是未发现任何富稀土相在界面上形成。稀土La对基体合金中镁的偏聚没有明显的影响,镁和稀土La均在界面处富集,且它们的分布位置大致近似。