全文获取类型
收费全文 | 5395篇 |
免费 | 721篇 |
国内免费 | 474篇 |
专业分类
电工技术 | 99篇 |
综合类 | 415篇 |
化学工业 | 1388篇 |
金属工艺 | 574篇 |
机械仪表 | 293篇 |
建筑科学 | 198篇 |
矿业工程 | 190篇 |
能源动力 | 99篇 |
轻工业 | 612篇 |
水利工程 | 52篇 |
石油天然气 | 341篇 |
武器工业 | 62篇 |
无线电 | 386篇 |
一般工业技术 | 692篇 |
冶金工业 | 625篇 |
原子能技术 | 196篇 |
自动化技术 | 368篇 |
出版年
2024年 | 31篇 |
2023年 | 107篇 |
2022年 | 164篇 |
2021年 | 203篇 |
2020年 | 186篇 |
2019年 | 200篇 |
2018年 | 166篇 |
2017年 | 203篇 |
2016年 | 190篇 |
2015年 | 224篇 |
2014年 | 299篇 |
2013年 | 391篇 |
2012年 | 389篇 |
2011年 | 352篇 |
2010年 | 223篇 |
2009年 | 249篇 |
2008年 | 224篇 |
2007年 | 324篇 |
2006年 | 314篇 |
2005年 | 288篇 |
2004年 | 254篇 |
2003年 | 227篇 |
2002年 | 207篇 |
2001年 | 177篇 |
2000年 | 135篇 |
1999年 | 128篇 |
1998年 | 106篇 |
1997年 | 83篇 |
1996年 | 88篇 |
1995年 | 81篇 |
1994年 | 54篇 |
1993年 | 34篇 |
1992年 | 48篇 |
1991年 | 49篇 |
1990年 | 40篇 |
1989年 | 31篇 |
1988年 | 17篇 |
1987年 | 19篇 |
1986年 | 16篇 |
1985年 | 25篇 |
1984年 | 12篇 |
1983年 | 12篇 |
1982年 | 3篇 |
1981年 | 8篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1971年 | 1篇 |
1959年 | 3篇 |
排序方式: 共有6590条查询结果,搜索用时 31 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(99):41783-41794
To satisfy arising energy needs and to handle the forthcoming worldwide climate transformation, the major research attention has been drawn to environmentally friendly, renewable and abundant energy resources. Hydrogen plays an ideal and significant role is such resources, due to its non-carbon based energy and production through clean energy. In this work, we have explored catalytic activity of a newly predicted haeckelite boron nitride quantum dot (haeck-BNQD), constructed from the infinite BN sheet, for its utilization in hydrogen production. Density functional theory calculations are employed to investigate geometry optimization, electronic and adsorption mechanism of haeck-BNQD using Gaussian16 package, employing the hybrid B3LYP and wB97XD functionals, along with 6–31G(d,p) basis set. A number of physical quantities such as HOMO/LUMO energies, density of states, hydrogen atom adsorption energies, Mulliken populations, Gibbs free energy, work functions, overpotentials, etc., have been computed and analysed in the context of the catalytic performance of haeck-BNQD for the hydrogen-evolution reaction (HER). Based on our calculations, we predict that the best catalytic performance will be obtained for H adsorption on top of the squares or the octagons of haeck-BNQD. We hope that our prediction of most active catalytic sites on haeck-BNQD for HER will be put to test in future experiments. 相似文献
2.
Recently, the successful synthesis of wafer-scale single-crystal graphene, hexagonal boron nitride (hBN), and MoS2 on transition metal surfaces with step edges boosted the research interests in synthesizing wafer-scale 2D single crystals on high-index substrate surfaces. Here, using hBN growth on high-index Cu surfaces as an example, a systematic theoretical study to understand the epitaxial growth of 2D materials on various high-index surfaces is performed. It is revealed that hBN orientation on a high-index surface is highly dependent on the alignment of the step edges of the surface as well as the surface roughness. On an ideal high-index surface, well-aligned hBN islands can be easily achieved, whereas curved step edges on a rough surface can lead to the alignment of hBN along with different directions. This study shows that high-index surfaces with a large step density are robust for templating the epitaxial growth of 2D single crystals due to their large tolerance for surface roughness and provides a general guideline for the epitaxial growth of various 2D single crystals. 相似文献
3.
《石油化工》2015,44(4):506
采用便携式微量水分析仪和库仑法微量水分析仪测定了乙烯、丙烯试样中的微量水含量,对试样的传输系统、进样量的控制、液体试样的气化和水标准气体的制备方法进行了改进,优化了测试条件。以低吸附惰性管线和小死体积单进单出的不锈钢减压器为试样传输系统,缩短了测试时间。采用液态烃闪蒸气化取样进样器气化液体试样并准确控制试样的进样量,可避免液体试样渐次气化对水含量测定结果的影响及对采样钢瓶大小的限制。采用渗透管发生器制备水标准气体,可验证分析结果的准确度。采用库仑法微量水分析仪测定水含量时,试样流量选择600 m L/min较适宜,开封保存15 d之内的卡尔·费休试剂对测定结果无影响。采用便携式微量水分析仪测定水含量时,选择试样流量在400~800 m L/min之间较适宜。两种仪器的测量结果相近,稳定性好,准确度高,回收率在102%~107%之间,相对偏差小于10%。 相似文献
4.
Thermally conductive polymers offer new possibilities for the heat dissipation in electric and electronic components, for example, by a three‐dimensional shaping of the heat sinks. To face safety regulations, improved fire performance of those components is required. In contrast to unfilled polymers, those materials exhibit an entirely different thermal behavior. To investigate the flammability, a phosphorus flame retardant was incorporated into thermally conductive composites of polyamide 6 and hexagonal boron nitride. The flame retardant decreased the thermal conductivity only slightly. However, the burning behavior changed significantly, due to a different heat propagation, which was investigated using a thermographic camera. An optimum content of hexagonal boron nitride for a sufficient thermal conductivity and fire performance was found between 20 and 30 vol%. The improvement of the fire performance was due to a faster heat release out of the pyrolysis zone and an earlier decomposition of the flame retardant. For higher contents of hexagonal boron nitride, the heat was spread faster within the part, promoting an earlier ignition and increasing the decomposition rate of the flame retardant. 相似文献
5.
Isaac Isarn Leïla Bonnaud Lluís Massagus ngels Serra Francesc Ferrando 《Polymer International》2020,69(3):280-290
The enhancement of the thermal conductivity, keeping the electrical insulation, of epoxy thermosets through the addition of pristine and oxidized carbon nanotubes (CNTs) and microplatelets of boron nitride (BN) was studied. Two different epoxy resins were selected: a cycloaliphatic (ECC) epoxy resin and a glycidylic (DGEBA) epoxy resin. The characteristics of the composites prepared were evaluated and compared in terms of thermal, thermomechanical, rheological and electrical properties. Two different dispersion methods were used in the addition of pristine and oxidized CNTs depending on the type of epoxy resin used. Slight changes in the kinetics of the curing reaction were observed in the presence of the fillers. The addition of pristine CNTs led to a greater enhancement of the mechanical properties of the ECC composite whereas the oxidized CNTs presented a greater effect in the DGEBA matrix. The addition of CNTs alone led to a marked decrease of the electrical resistivity of the composites. Nevertheless, in the presence of BN, which is an electrically insulating material, it was possible to increase the proportion of pristine CNTs to 0.25 wt% in the formulation without deterioration of the electrical resistivity. A small but significant synergic effect was determined when both fillers were added together. Improvements of about 750% and 400% in thermal conductivity were obtained in comparison to the neat epoxy matrix for the ECC and DGEBA composites, respectively. © 2019 Society of Chemical Industry 相似文献
6.
Qiuping Wang Bojan Šarkanj Jasna Jurasovic Yusuf Chisti Michael Sulyok Jiashun Gong Sarote Sirisansaneeyakul Draženka Komes 《International Journal of Food Science & Technology》2019,54(5):1541-1549
Theabrownins (TB) are polymeric phenolic compounds associated with the multiple bioactivities of Pu-erh tea, a post-fermented Chinese dark tea. High-TB instant Pu-erh tea was produced via a novel submerged fermentation (SF) using Aspergillus tubingensis and compared with samples produced commercially via the conventional solid-state fermentation (SSF). Viable microorganisms and microbial toxins, especially aflatoxins B1, G1, B2, G2, cyclopiazonic acid, fumonisins B1, B2, B3 and ochratoxin A, were below the detection limit in all samples. Fewer microbial metabolites were found in SF instant tea compared with the SSF teas. Based on an adult consuming 1 g of instant Pu-erh tea daily, the dietary intake of investigated elements was below the safe limits recommended by various authorities. Tasters viewed the instant tea infusions as very mild, smooth, mellow and full. This suggested that submerged fermentation using A. tubingensis offers a speedy and safe alternative to commercial production of instant Pu-erh tea. 相似文献
7.
非线性扩频序列的三项式特性 总被引:5,自引:1,他引:4
讨论了三类非线性扩频序列(GMW序列、No序列和Kasami序列)的三项式特性,利用这三类序列的迹表示,证明了GMW序列、No序列和Kasami序列均具有正则三项式对。 相似文献
8.
9.
10.
本文提供了SN388在三维施工中炮点表的几种设置方法,并进行了相应的对比说明,最后给出了改进炮点表设置的有关设想。 相似文献