表面包覆改善球形Ni（OH）2高温性能的研究

采用Yb／Co氢氧化物共沉淀包覆方法和Ca3（PO4）2与Co（OH）2分别沉淀分层包覆方法在球形Ni（OH）2的表面进行了均匀的包覆。前者利用COSO4，YbCl3和NaOH溶液进行共沉淀包覆，后者是先在球形Ni（OH）2的表面沉淀包覆Ca3（PO4）2，然后再沉淀包覆Co（OH）2。结果显示，两种包覆方法均能有效地提高球形Ni（OH）2的高温（60℃）性能。按照Yb／Co=0．75％：2％共沉淀包覆的试样制成AA型电池后，在60℃下1C放电的容量保持率达到常温下的90％。而2％Ca3（P04）2与2％Co（OH）2分层包覆后的球形Ni（OH）2制成AA型电池后，在60℃下1C放电的容量保持率达到常温下的81％。未包覆和仅用Co（OH）2包覆的球形Ni（OH）2制成的AA型电池，在60℃下1C放电的容量保持率分别只有46％和48％。通过循环伏安测试表明，利用表面包覆的方法可以增大正极材料Ni（OH）2在高温下的氧化电位、析氧电位和两者之间的电位差，从而提高了材料在高温下的电化学性能。     

镱应力传感器的制作与应用

在数十MPa~2 GPa范围内的动态应力测量中,镱传感器的压阻系数高,可灵活埋置于待测材料中使用。该种传感器对研究冲击波在岩石、土壤、液体介质和结构材料中的传播与衰减规律显示出了优异性能。对国内外镱应力传感器研制工作进行了总结,介绍了该类传感器在爆炸、射弹侵彻、高速碰撞以及高能激光辐照等方面的应用,并指出了该种传感器存在的一些问题。     

单一偏振的多波长环形腔掺镱光纤激光器

在环形腔掺镱光纤激光器中加入一段G .6 5 2光纤作为多模光纤 ,依靠其中导模的空间模式跳变构成动态梳状滤波器 ,于室温下实现了掺镱光纤激光器 1 0 3μm波长附近稳定的 6波长激光同时输出。激光线宽为 0 15nm ,边模抑制比达到 4 0dB以上。通过调整腔内的偏振控制器 ,可以得到不同波长个数和波长间隔的多波长激光输出     

Synthesis, structure and catalytic behavior of ytterbium complexes bearing a phenoxy（quinolinyl）amide ligand

Two ytterbium complexes stabilized by phenoxy(quinolinyl)amide ligand 3,5-Bu t 2 -2-OC 6 H 2 CH 2 N-8-C 9 H 6 N (L) were synthesized and characterized. Reaction of anhydrous YbCl 3 with 1 equiv. of LLi 2 in THF gave the ytterbium chloride [LYbCl(THF)] 2 (1) in 73% yield. A further reaction of complex 1 with equimolar of NaN(SiMe 3 ) 2 in THF afforded the unexpected heterobimetallic "ate"-complex L 2 YbNa(THF) 2 (2) via a ligand redistribution reaction. Complex 2 could also be prepared in high isolated yield by the reaction of anhydrous YbCl 3 with 2 equiv. of LNa 2 generated in situ. Both complexes 1 and 2 were characterized by IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction analysis. It was found that complex 2 was an effective catalyst for the addition reaction of aromatic amines to carbodiimides.     

高纯稀土金属Sm、Yb和Tm的制备

采用镧热还原蒸馏法对蒸气压较高的稀土元素Sm、Yb和Tm的制备进行了研究,制得了纯度达4N级的稀土金属Sm和Yb,其纯度分别为99.99%和99.993%（质量分数,相对75种杂质元素）;对于稀土金属Tm,由于还原温度较高,还原蒸馏产物中La的含量偏高,需要对其进行低温、高真空升华提纯,提纯后纯度达到99.995%（同上）;实验结果表明,高纯度还原剂La的制备,尤其是La中金属杂质总量的控制,是获得4N级Sm、Yb和Tm的关键步骤。     

高功率多模铒镱共掺双包层光纤激光器的研究

为了获得尽可能高的输出功率以满足应用需求,分别以实验和数值分析的方法对铒镱共掺双包层光纤激光器的性能进行了进一步研究.实验上,采用加拿大国家光学研究所生产的EY805型铒镱共掺双包层多模光纤作为增益介质,描述了输出功率随入纤抽运功率以及光纤长度的变化,在光纤长度为1.8m的情况下,获得了3.5W的最大输出功率,光-光转换效率达31.8%.基于速率和传输方程,对该铒镱共掺双包层光纤激光器进行了数值模拟,在相同光纤长度下,计算的最大输出功率约.W,光-光转换效率0%,比实验结果要高.讨论了进一步对该光纤激光器性能进行优化的措施.该结果对于促进铒镱共掺双包层光纤激光器的实用化及其性能改进具有重要意义.     

Y2O2S:Yb,Ho上转换发光材料的制备及性能

利用硫熔法制备了不同浓度的Yb和Ho掺杂的Y2O2S:Yb,Ho上转换发光材料。采用X线衍射仪、扫描电镜和荧光光谱仪对粉体的相组成、形貌和上转换发光性能进行表征。结果表明:不同浓度的Yb和Ho掺杂后没有改变Y2O2S的晶体结构;颗粒形貌较为规则,多呈现多面体状,分散性较好,颗粒表面很光滑;在980nm激光激发下,Y2O2S:Yb,Ho呈现出以绿光发射为主的上转换荧光,Yb的最佳掺杂量为8%(摩尔分数),Ho的最佳掺杂量为2%(摩尔分数),Ho3+和Yb3+掺杂浓度可显著影响不同颜色发射峰的强度;对激活离子Ho3+来说,同类离子之间发生能量传递和交叉弛豫行为,导致上转换荧光强度发生猝灭;对敏化离子Yb3+来说,Yb3+吸收能量,以热的形式释放出来,产生杂质猝灭。     

异硫氰酸镱苄胺配合物的合成及其热分解非等温动力学研究

本文叙述了异硫氰酸镱苄胺配合物Yb(NCS)_3·4C_6H_5CH_2NH_2的合成方法。通过对该配合物进行热分解非等温动力学研究,推断了该配合物的热分解反应机理及动力学补偿效应表达式。     

Measurements of Enthalpy Change of Reaction of Formation, Molar Heat Capacity and Constant-Volume Combustion Energy of Solid Complex Yb（Et2dtc）3（phen）

A ternary solid complex Yb(Et2dtc)3(phen) was obtained from the reaction of hydrous ytterbium chloride with sodium diethyldithiocarbamate (NaEt2dtc), and 1, 10-phenanthroline (o-phen·H2O) in absolute ethanol.The bonding characteristics of the complex were characterized by IR.The result shows Yb3 bands with two sulfur atoms in the Na(Et2dtc)3 and two nitrogen atoms in the o-phen.The enthalpy change of liquid-phase reaction of formation of the complex ΔrHθm (l), was determined as being (-24.838±0.114) kJ·mol-1 at 298.15 K, by an RD-496 Ⅲ type heat conduction microcalormeter.The enthalpy change of the solid-phase reaction of formation of the complex ΔrHθm (s), was calculated as being (108.015±0.479) kJ·mol-1 on the basis of an appropriate thermochemistry cycle.The thermodynamics of liquid-phase reaction of formation of the complex was investigated by changing the temperature during the liquid-phase reaction.Fundamental parameters, the activation enthalpy, ΔHθ≠, the activation entropy, ΔSθ≠, the activation free energy, ΔGθ≠, the apparent reaction rate constant k, the apparent activation energy E, the pre-exponential constant A, and the reaction order n, were obtained by a combination of the reaction thermodynamic and kinetic equations with the data from the thermokinetic experiments.At the same time, the molar heat capacity of the complex cm, p, was determined to be (86.34±1.74) J·mol-1·K-1 by the same microcalormeter.The constant-volume combustion energy of the complex, ΔcU, was determined to be (-17954.08±8.11) kJ·mol-1 by an RBC-Ⅱ type rotating-bomb calorimeter at 298.15 K.Its standard enthalpy of combustion, ΔcHθm, and standard enthalpy of formation, ΔfHθm, were calculated to be (-17973.29±8.11) kJ·mol-1 and (-770.36±9.02) kJ·mol-1, respectively.     

箔式镱应カ传感器及试验研究

为测量弹药爆炸及武器侵彻等强冲击荷载下岩体及混凝土结构中应力，研制了箔式镱应力传感器。对传感器工作原理进行了分析，研究出了镱敏感元件的加工工艺，合理设计了传感器结构。对传感器进行了试验研究，试验表明传感器具有横向效应小、量程范围宽、过载能力强、频响高、结构简单、使用方便等优点，可广泛应用于强冲击荷载下混凝土或岩石等介质中的应力测试。