Ionic liquid-based deep eutectic solvents as novel solvent-cum-catalyst media for thermal dehydrogenation of chemical hydrides

The current work explores the usage of novel synthesized Deep Eutectic Solvent (DES) as a catalyst cum solvent media for the thermal dehydrogenation of chemical hydrides, namely Ammonia Borane (AB) and Ethylene diamine bisborane (EDAB). In the first instance, the quantum chemistry based COSMO-SAC (COnductor like Screening MOdel Segment Activity Coefficient) model was used for the selection of the pertinent solvent. 1-Butyl-3-methylimidazolium methanesulfonate: Imidazole ([BMIM][MeSO₃]:[Im]) turned out to be an ideal eutectic mixture with the highest predicted solubility with amine boranes. The DES was synthesized by combining the Hydrogen Bond Acceptor (HBA), namely 1-Butyl-3-methylimidazolium methanesulfonate and Imidazole as Hydrogen Bond Donor (HBD) at a molar ratio of 1:2 and T = 70 °C. The formation of DES was confirmed by recording the NMR spectra. Further, the thermal dehydrogenation study was performed at a vacuum of 4 × 10^?2 mbar (gauge pressure) of AB/DES and EDAB/DES systems at 105 °C, where a hydrogen equivalent of 1.40 and 2.55 was produced, respectively. The residual samples were further analyzed through ¹H NMR analysis for the reaction mechanism and to confirm the role of Ionic Liquid-based DES as catalyst cum solvent media.     

网络电话语音质量提高的初探

在分析了分组交换网络中影响语音质量的几种因素之后，探讨如何对网络延迟进行分析与统计。并以支持静音消除功能的编码解码器G729AB为例，在分析网络抖动的统计方法的基础上，设计1种传输G729AB语音分组的构造系统和接收端的复现系统，及相应的抖动缓冲自适应算法，以求提高IP电话的语音质量，     

AB活性污泥法污水处理技术的消化和创新

本文介绍漳州市东区污水处理厂AB法设计、运行的特点，总结了安装、运行的效果，提出了今后改进方法。     

叶子花红色素提取工艺的优化

本文研究了用树脂吸附和分离叶子花红色素，比较了4种树脂对叶子花红色素的吸附，在叶子花红色素提取过程中用AB－8树脂吸附，洗脱剂用40％的乙醇，洗脱效果好，且AB－8树脂使用20次后吸附性能仍稳定。     

铸态及快淬态无钴AB5型贮氢合金的循环稳定性

对AB5型LaxMm1-x(NiMnSiAlFe)49(x=0,0.45,0.75,1.00,摩尔分数)贮氢合金进行了快淬处理,研究了La含量及快淬工艺对合金微观结构及电化学循环稳定性的影响.结果表明:La含量的增加对铸态合金的循环稳定性没有明显影响,但使快淬态合金的循环稳定性下降,且快淬处理能显著提高合金的循环稳定性.当La替代量从0增加到1.00时,经300次充放循环后,铸态合金的容量保持率(Rh)从59.2%增加到59.8%;16 m/s淬速快淬态合金的容量保持率从83.9%下降到65.0%.对于x=0.45的合金,当淬速从0(铸态被定义为淬速等于0)增加到28 m/s时,容量保持率从59.8%增加到75.8%.     

Fe替代Co对AB5型贮氢合金循环稳定性的影响

用铸造及快淬的方法制备了稀土基AB5型Mm（NiMnSiAl）4．3Co0.6-xFex（x=0，0．1，0．2，0．3，0．4，0．5，0．6）贮氢合金，用XRD。TEM及SEM观测了铸态及快淬态的微观结构，测试了合金在铸态及快淬态下的电化学循环稳定性。研究了Fe替代Co对铸态及快淬态贮氢合金微观结构及循环稳定性的影响。研究结果表明，Fe替代Co对铸态及快淬态合金的相结构没有明显影响，但对合金的循环稳定性产生显著影响。Fe替代Co能不同程度地改善铸态及快淬态合金的循环稳定性，但对快淬态合金循环寿命的改善更加显著，导致这一结果的主要原因是Fe替代Co使快淬态合金的微观组织显著细化。     

Cure kinetics and mechanical properties of the blend system of epoxy/diaminodiphenyl sulfone and amine terminated polyetherimide-carboxyl terminated poly(butadiene-co-acrylonitrile) block copolymer

The cure kinetics of blends of epoxy resin (4,4’-tetraglycidyl diaminodiphenyl methane; TGDDM)/curing agent (diaminodiphenyl sulfone; DDS) with ATPEI (amine terminated poly-etherimide) -CTBN (carboxyl terminated poly (butadiene-co-acrylonitrile)) block copolymer (AB type) were studied using differential scanning calorimetry under isothermal conditions to determine the reaction kinetic parameters such as activation energy and reaction constants. Final cure conversion decreased with increasing amount of AB in the blends. A diffusion controlled reaction was observed as the cure conversion increased, and the curing reaction was successfully analyzed by incorporating the diffusion control term in the rate equation for the epoxy/DDS/AB blends. The fracture toughness was improved to about 350% compared to that of the unmodified resin at 30% of AB block copolymer. This is attributed to the formation of co-continuous morphology between the epoxy phase and AB block copolymer phase. By increasing the amount of AB, the modulus of the cured blends decreased, which was due to the presence of CTBN rubbery phases.     

一种高压摆率低电压CMOS AB类放大器的设计

为了增加单位增益频率与压摆率,并能够工作在低电源电压下,同时降低偏置电流,提出了一种改进的基于0.18μm CMOS工艺的AB类放大器,其采用多级放大器结构,第一级为具有电流镜负载的NMOS差分对,第二反相级由共源放大器实现,第三极为AB类放大器,其能够在±500 m V电源下工作.电路仿真结果显示该放大器相位裕度为87°;总补偿电容为5 p F,与传统放大器相比减少了50%;单位增益频率为21.17 MHz,比传统放大器增大约10倍;压摆率为7.5和8.57 V/μs,与传统电路相比,分别增加了2.8倍和2.6倍.此外,与其他文献相比,该放大器具有较大的单位增益带宽和压摆率以及较小的功耗.     

A组分变化对AB2型储氢合金组织结构及电化学性能的影响

设计了两种成分AB2型合金,（Zr1-XTiX）（NiVMnCo）2＋α,采用XRD、SEM、TEM以及电化学性能测试方法分别对它们的铸态、快淬态及快淬态经过773 K、973 K和1 173 K退火处理的合金进行研究,结果表明,在AB2型储氢合金中加入少量Ti,可以增加电极的放电容量,提高循环寿命。熔体旋转快淬制备的非晶态合金电极的电化学性能差。快淬样品经过退火后,可获得纳米晶结构,能够大幅度提高电极材料的放电容量（370 mAh/g）和循环寿命（300次循环后容量衰减3%）。     

基于非对称打包和FSVM的图像检索

在图像检索的相关反馈中,引入支持向量机分类方法虽可以提升图像的检索性能,但是传统的支持向量机存在正样本数少、样本非对称、过学习和弱实时性的局限。针对上述问题,提出了一种基于非对称打包的FSVM算法。该算法首先对负样本进行非对称打包处理,最后结合模糊理论与SVM实现图像检索。Corel图片集上的实验表明,当正样本数较小时,该新算法的平均查准率-查全率要优于已有算法。