全文获取类型
收费全文 | 225篇 |
免费 | 16篇 |
国内免费 | 2篇 |
专业分类
综合类 | 15篇 |
化学工业 | 159篇 |
金属工艺 | 3篇 |
机械仪表 | 3篇 |
建筑科学 | 3篇 |
矿业工程 | 7篇 |
能源动力 | 7篇 |
轻工业 | 14篇 |
石油天然气 | 17篇 |
无线电 | 5篇 |
一般工业技术 | 6篇 |
冶金工业 | 1篇 |
原子能技术 | 1篇 |
自动化技术 | 2篇 |
出版年
2023年 | 1篇 |
2021年 | 5篇 |
2019年 | 4篇 |
2018年 | 3篇 |
2017年 | 11篇 |
2016年 | 12篇 |
2015年 | 5篇 |
2014年 | 10篇 |
2013年 | 22篇 |
2012年 | 4篇 |
2011年 | 9篇 |
2010年 | 7篇 |
2009年 | 12篇 |
2008年 | 8篇 |
2007年 | 9篇 |
2006年 | 8篇 |
2005年 | 8篇 |
2004年 | 7篇 |
2003年 | 10篇 |
2002年 | 12篇 |
2001年 | 10篇 |
2000年 | 14篇 |
1999年 | 7篇 |
1998年 | 4篇 |
1997年 | 5篇 |
1996年 | 3篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有243条查询结果,搜索用时 203 毫秒
1.
2.
均匀设计法在烷基糖苷合成中的应用 总被引:2,自引:0,他引:2
在烷基糖苷的合成反应中,影响糖苷得率的因素很多,且各因素之间又存在着相互牵制作用。为了探索合成的最佳条件,我们采用了均匀实验设计法。实验证明:它特别适用于多因素多水平的实验设计,同时减少了实验的次数,降低了实验的费用,提高了工作效率。 相似文献
3.
Alkyl radicals produced in the indirect reduction of alkyl halides or alkyldimethylsulfonium salts by electrochemically generated aromatic radical anions couple fast with the latter and alkylated or dialkylated dihydro compounds are formed. Rate constants measured for the coupling reaction between on one hand methyl, primary, secondary and tertiary alkyl radicals as well as benzyl and cumyl radicals and on the other hand a wide spectrum of electrochemically generated aromatic radical anions are found to be about 1×109 M−1 s−1. Previous measurements of coupling rate constants for primary alkyl radicals have been re-evaluated since they were affected by the presence of an SN2 reaction occurring between the alkyl halides used as radical precursors and the aromatic radical anions. New experiments are also included using alkyldimethylsulfonium salts as precursors in order to prevent such SN2 artefacts. It is concluded that sterical hindrance does not play a significant role for the radical-radical anion coupling reactions. In general the rate constants for the coupling reactions are all close to 109 M−1 s−1. 相似文献
4.
介绍了一种测定废水中LAS浓度的新方法。克服了常规方法亚甲基蓝比色法要绘制标准曲线,操作过程复杂等局限性。该方法测定过程简单,结果准确,标准偏差为1.4l,变异系数为3.92%。 相似文献
5.
Mustafa E. Tat Paul S. Wang Jon H. Van Gerpen Thomas E. Clemente 《Journal of the American Oil Chemists' Society》2007,84(9):865-869
Biodiesel is a fuel comprising mono-alkyl esters of medium to long-chain fatty acids derived from vegetable oils or animal
fats. Typically, engines operated on soybean-based biodiesel exhibit higher emissions of oxides of nitrogen (NOx) compared
with petroleum diesel. The increase in NOx emissions might be an inherent characteristic of soybean oil’s polyunsaturation,
because the level of saturation is known to affect the biodiesel’s cetane number, which can affect NOx. A feedstock that is
mostly monounsaturated (i.e. oleate) helps to balance the tradeoff between cold flow and oxidative stability. Genetic modification
has produced a soybean event, designated 335-13, with a fatty acid profile high in oleic acid (>85%) and with reduced palmitic
acid (<4%). This high-oleic soybean oil was converted to biodiesel and run in a John Deere 4045T 4.5-L four-stroke, four-cylinder,
turbocharged direct-injection diesel engine. The exhaust emissions were compared with those from conventional soybean oil
biodiesel and commercial No. 2 diesel fuel. There was a significant reduction in NOx emissions (α = 0.05) using the high-oleic soybean biodiesel compared with regular soybean oil biodiesel. No significant differences were
found between the regular and high-oleic biodiesel for unburned hydrocarbon and smoke emissions. 相似文献
6.
以自制苯并噻唑离子液体([HBth]HSO4)为活性组分,HZSM-5分子筛为载体,通过过量溶剂浸渍法制备了固载型苯并噻唑离子液体催化剂([HBth]HSO4/HZSM-5)并用于催化合成烷基糖苷,通过傅立叶变换红外光谱、N2物理脱附、场发射电子显微镜和X射线衍射对催化剂结构进行表征,结果表明,[HBth]HSO4被成功地引入到HZSM-5载体的表面及孔道内。当催化剂用量为1.5 wt%,反应温度为105℃,醇糖摩尔比n(葡萄糖):n(辛醇)=6:1时,辛基糖苷得率达148.8%(产物质量/葡萄糖的质量?100%)。底物拓展及催化剂稳定性研究结果表明,[HBth]HSO4/HZSM-5对烷基糖苷及其衍生物都具有良好的催化效果,且催化剂能稳定循环使用四次,活性组分流失是催化剂失活的主要原因。通过对烷基糖苷催化合成机理和动力学的研究,确定了动力学方程。 相似文献
7.
Understanding the molecular-level processes underlying interfacial phenomena is important in the area of adhesion. We briefly introduce IR-visible sum-frequency generation spectroscopy (SFG) using a total-internal-reflection geometry for the study of polymer-air, polymer-solid, and polymer-polymer interfaces. The following examples, predominantly of work done in our lab, illustrating differences in molecular structure and dynamic properties at interfaces are presented: the air- and solid-interface structure of an amorphous polystyrene (PS) and a semicrystalline polymer with side-chain crystallinity, poly(octadecyl acrylate) (PA-18); structure of a polymer-polymer interface between thin films of a semicrystalline polymer with side-chain crystallinity, poly(vinyl-N-octadecylcarbamate- co-vinyl acetate), and an amorphous PS; thermal order-to-disorder transitions of the air and solid interface of PA-18, and the interface of this polymer with PS; and dynamic surface-relaxation studies of a rubbed PS film. 相似文献
8.
Surface active properties such as surface and interfacial tension reductions and stability of oil-in-water (o/w) and water-in-oil
(w/o) emulsions by alkyl glycoside fatty acid polyesters, a potential fat substitute, and emulsifier blends of alkyl glycoside
polyesters and Ryoto sugar esters were investigated.
Our results indicate that blending of lipophilic and hydrophilic emulsifying agents produces a synergistic effect on reduction
of surface and interfacial tensions and may, in some cases, result in more stable emulsions. Alkyl glycoside polyesters may
be suitable for w/o emulsions, such as margarine and butter, and their blends with hydrophilic emulsifiers will produce reduced
calorie emulsifiers suitable for use in o/w emulsions, such as salad dressing. There appears to be great potential for using
such emulsifier blends in food, cosmetics and pharmaceutical applications. 相似文献
9.
以α-十六烯、二苯醚在催化剂的作用下合成十六烷基二苯醚,再采用氨基磺酸作为磺化剂,尿素为助溶剂成功合成了十六烷基二苯醚双磺酸钠,对合成过程中烷基化与磺化反应的工艺条件进行了优化。烷基化的最佳反应条件为:n(α-十六烯):n(二苯醚)=1:1,反应温度为80℃,反应时间为6h,烷基化的产率可达85.42%。磺化的最佳反应条件为:n(烷基二苯醚):n(氨基磺酸)=1:4,反应温度为95℃,反应时间为2h,磺酸基数目为1.84。 相似文献
10.
Carbodithioate esters are important functional organosulfur compounds widely used in diverse fields such as pharmaceuticals, agrochemicals and material sciences. Common preparative methods include reaction of alkyl halides, carbon disulfide and bases under both metal-free and metal-catalyzed conditions. However, organyl thiocyanates have not been previously explored, possibly because of their conversion to organyl disulfides under basic conditions. Here, we report an efficient and practical method for the preparation of libraries of carbodithioate esters from organyl thiocyanates by reacting with cyclic amine-based dithiocarbamic acid salts in water. The protocol is found to be applicable in general to various thiocyanates such as benzyl/aroyl methyl/cinnamyl and so on. Other notable features include no by-products such as disulfides, metal- and alkali-free, aqueous conditions, and finally easy and near-quantitative formation of cyclic amine-based dithiocarbamic acid salt as a stable alternative reagent. 相似文献