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排序方式: 共有1323条查询结果,搜索用时 15 毫秒
1.
Xianjin Li Tianyu Li Pengcheng Xu Congxin Xie Yunhe Zhang Xianfeng Li 《Advanced functional materials》2021,31(22):2100133
Bromine-based flow batteries (Br-FBs) are considered one of the most promising energy storage systems due to their features of high energy density and low cost. However, they generally suffer from uncontrolled diffusion of corrosive bromine particularly at high temperatures. That is because the interaction between polybromide anions and the commonly used complexing agent (N–methyl–N–ethyl–pyrrolidinium bromide [MEP]) decreases with increasing temperatures, which causes serious self-discharge and capacity fade. Herein, a novel bromine complexing agent, 1–ethyl–2–methyl–pyridinium bromide (BCA), is introduced in Br-FBs to solve the above problems. It is proven that BCA can combine with polybromide anions very well even at a high temperature of 60 °C. Moreover, the BCA contributes to decreasing the electrochemical polarization of Br−/Br2 couple, which in turn improves their power density. As a result, a zinc–bromine flow battery with BCA as the complexing agent can achieve a high energy efficiency of 84% at 40 mA cm−2, even at high temperature of 60 °C and it can stably run for more than 400 cycles without obvious performance decay. This paper provides an effective complexing agent to enable a wide temperature range Br-FB. 相似文献
2.
Electrochemical investigations on low-Si alloyed steels with Si content ranging from 0.25 to 3.2 wt.% were carried out in a 0.1 M NaCl borate-buffered solution (pH 8.4) in reducing conditions at 90 °C. Silicon as an alloying element was proved to degrade at first the steel ability to passivate. For longer immersion times, protective effects developed more efficiently on the steel containing 3.2 wt.% silicon. Passive layers electrochemically formed in the transpassive domain on the steel containing 3.2% Si were shown to be significantly different from those grown at rest potential. 相似文献
3.
高温润滑涂层设计的系统考虑 总被引:3,自引:0,他引:3
航天、航空、核能等尖端技术迫切要求使用耐高温润滑涂层,以保护金属构件的表面,增加发动机、推进器的工作效率和输出功率,80年代国际摩擦学界根据工业和国防的需要将高温润滑涂层和耐磨材料定为摩擦学学科发展的重要研究方向之一。本文对高温润滑涂层设计中遇到的典型环境、涉及到的关键问题、未来发展的途径等问题作了阐述。 相似文献
4.
A generalized equation was derived to calculate the melting temperatures of homopolymers and copolymers. The Gibbs‐Thomson equation for homopolymers and a modified application to copolymers were derived using the proposed equation. The melting temperature Tm0 in the Flory equation corresponds to the melting temperature TmC,∞ of copolymer crystals with stems of infinite length. Also, TmC,n*, the melting temperature for copolymer crystals with stems containing the maximum possible number of structural units, n*, should be used instead of Tm0 as the basis of supercooling in crystallization. The proposed equation shows good agreement with experimental data for α‐alkene‐ethylene homogeneous copolymers. 相似文献
5.
6.
Y. Kraftmakher 《International Journal of Thermophysics》1994,15(5):983-991
Relaxation phenomena due to equilibration of point defects in metals are reviewed. The relaxation effect in specific heat observed in tungsten and platinum confirms that in both cases the nonlinear increase in the high-temperature specific heat has to be attributed to point-defect formation. Relaxation phenomena observed by measurements of electrical resistivity and positron annihilation are also considered. The comparison of the data seems to be favorable for the conclusion that all the phenomena are of one origin. 相似文献
7.
The modified direct observation method is employed for the determination of the liquidus lines in the (Hg1_xZnx)1_yTey, ternary system. The liquidus temperatures of the ternary samples of various compositions withx from 0.05 to 0.30 andy from 0.5 to 0.9 are measured. The temperature-composition phase diagrams and some liquidus isotherms are established for
this system. 相似文献
8.
赵青南 《武汉理工大学学报(材料科学英文版)》2005,(4)
1Introduction Theultravioletrays(UV)insunlight(-4%)cantransmitintoroomthroughcommonfloatglass,theUVcanmakethematerialsintheroom,eg,paper,furni ture,textilefabricandplastics,becoloredanddeterio rated.ShieldingfromUVirradiationisofinterestinmanyfields.Formu… 相似文献
9.
Abstract— The ACPD-method was used to measure crack growth in low cycle fatigue tests at elevated temperature. The material which was investigated at T = 550°C was the ferritic steel 2.25Cr–1Mo. Characteristic values of representative hysteresis loops were determined. The crack growth data were correlated with the effective part of the fracture mechanics parameter Δ J. A new method for the calculation of Δ J is proposed. 相似文献
10.
Fibre-reinforced plastics (FRPs) are candidate materials for the insulation of superconducting magnet coils in future fusion reactors. This paper reports on a test programme performed to assess the mechanical properties of these materials and to obtain information on the damage and fracture mechanisms. Different types of FRPs (epoxies and poly- and bismaleimides as resins; two- and three-dimensional E-, S- or T-glass fabrics as reinforcements) were irradiated at room temperature by 2 MeV electrons and 60Co-gamma rays up to 1.8 × 108 Gy and by different reactor spectra up to a neutron fluence of 1 × 1023 m−2 (E > 0.1 MeV) at room temperature, 80 K or 5 K. Mechanical tests in tension as well as in the intralaminar crack opening and shear mode were carried out on the irradiated samples at 77 K. After low temperature irradiation, half of the samples were subjected to a warm-up cycle to room temperature before testing at 77 K. Results on the influence of different radiation sources and annealing cycles on the mechanical properties of these materials will be discussed. 相似文献