Boosting the photoconversion efficiency of TiO2 nanotubes using UV radiation-assisted anodization as a prospective method: An efficient photocatalyst for eliminating resistant organic pollutants

1D TiO₂ nanotube arrays (TNTs), as versatile nanostructures, have attracted a considerable amount of scientific attention, particularly in photocatalytic applications. In the present study, UV radiation-assisted anodization method with various irradiation times (30–120 min) was employed as a preferable approach to fabricating TNTs with remarkable optical property and photocatalytic activity. The results revealed that in situ irradiation not only improved the surface area (from 30.10 to 48.5 m²), but also increased the roughness factor (from 77.27 to 124.73). Furthermore, UV radiation had a significant impact on optical property and by altering elemental composition, led to a red shift in absorption edge (from 3.2 to 1.4eV). Meanwhile, voltammetric experiments showed that 120 min UV radiation during anodization was able to substantially cause a surge of the photocurrent density and the photoconversion efficiency of TNTs from 0.15 to 0.55 mA cm⁻² and from 13% to 40%, respectively. As a consequence of the improvement in optical property and photochemical features, anodic TNTs fabricated under 120 min UV radiation could increase the photocatalytic degradation of 2,4-DCP from 75% to 100%. Moreover, the kinetics study showed that all photocatalytic reactions followed zero-order kinetics which rate constant over the synthesized TNTs under 120 min UV radiation was about 5.1 times greater than that of conventionally fabricated TNTs. Likewise, the pathway of photocatalytic degradation and the proportion of reactive species in this process were assessed by scavenging tests. The results confirmed that holes (h⁺) play the main role that 53% of photocatalytic degradation occurred via both direct and indirect reactions with h⁺ species. The rest of the degradation pathways were also allocated to e⁻ and ^•O₂⁻ species by accounting for 37% and 10%, respectively.     

一种新的加权最小二乘测距定位方法

三站二维定位问题是最小定位问题，一般只利用几何关系就能获得定位估计，但由于未利用距离测量的统计信息，定位精度较差。该文先将点到点的距离测量转化为点到线的距离估计，再在此基础上推导出一种新的加权几休定位方法，其中加权的确定利用了距离测量的统计信息。仿真实验表明，在测距误差较小时新方法具有更高的定位精度。     

Numerical study on PEMFC’s geometrical parameters under different humidifying conditions

Steady-state and three-dimensional simulations were carried out to study the influences of geometrical parameters on the performance of PEMFC under different hydrating conditions. Flow fields, species transport, transport of water in polymer membrane and movement of liquid water in cathode and anode porous layers were determined, in order to accomplish a complete estimation of ohmic and concentration losses of PEMFC power. The geometrical parameters were thickness of the polymer membrane, cathode catalyst layer as well as gas channel to rib width ratio. Every simulation was made under different relative humidities of inlet flows (50 and 100%) for every change of characteristic length. Results show that the influence of the geometrical parameters on ohmic and concentration losses is of considerable importance. The performance of PEMFC is seriously affected under dehydrating conditions. However, such performance may be considerably improved by using suitable geometrical parameters. Cathode and anode liquid saturation may not only affect the transport of species, but also the polymer electrolyte water content. These results show the importance of simultaneously calculating both the water absorption and desorption through the polymer electrolyte and the liquid saturation in the cathode and anode porous mediums to obtain an actual view of ohmic and concentration losses of the PEMFC performance.     

几何设计约束的表示与满足问题研究

对于智能ＣＡＤ系统来说，具有解决几何设计约束的功能是重要的。本文提出了一种面向对象的几何设计约束表示方法，它可以通过两种方式来表达。文中给出了一个约束传播算法，用于解决约束满足问题。     

Non-contact methods of measuring moisture concentration in external layers of building partitions: III—Water vapour condensation on the cementitious surfaces

This paper presents the results of the larger study into a potential application of laser radiation for the detection of phase transition processes in low temperatures occurring on the surface layers of cementitious materials. An attempt was made to identify relationships between the environmental conditions—temperature and air humidity, and the selected parameters of the reflected light. Onset of the condensation process and formation of water microdrops on the surface of the material leads to the phase displacement of individual laser rays, which are represented by different speckle images.

Although the analysis of parameters of the reflected light are very difficult in the case of porous materials because of highly developed roughness of the surface structure it has been proved that a dynamic study of the phase transition phenomena can be successfully carried out without mechanical intervention.     

Non-contact methods of measuring moisture concentration in external layers of building partitions II—Monitoring of the water vapour condensation on porous surfaces

This paper present the results of the investigation into a potential application of laser radiation for the detection of phase transition processes occurring on the surface layers of porous materials. An attempt was made to discuss in the approximation equations, the relationships between coefficients of the reflected light, the temperature and humidity of the surrounding environment. Laser light reflected from the porous surface carries information about the roughness of the structure. The presence of water microdrop on the surface of the porous material, as a result of condensation and thus a phase transition, leads to the phase displacement of individual rays, which is represented by different images. Therefore, a comprehensive analysis of the reflected light parameters allows a dynamic study of the phase transition phenomena without mechanical intervention.     

Formulation of unified Jacobian for serial-parallel manipulators

This paper presents a general approach for Jacobian analysis of serial-parallel manipulators (S-PMs) formed by two lower mobility parallel manipulators (PMs) connected in serials. Based on the kinematic relation, coupling and constraint properties of each PM, the unified forward and inverse Jacobian matrices for S-PMs are derived in explicit form. It is shown that the Jacobian matrices of S-PMs have unified forms, which include the complete information of each PM. A (3-RPS)+(3-SPS/UP) S-PM is used as an example to demonstrate the proposed approach. The established model is applicable for S-PMs with various architectures.     

电火花铣削中电极损耗及补偿的几何描述方法

提出了电火花铣削加工的基于数学模型的电极分解加工补偿法，即通过将电火花铣削加工过程划分为两个阶段——型腔侧面轮廓加工和底面的加工，这样就简化了放电状态的检测和电极补偿运动。在分别对侧面和底面加工过程分析的基础上，建立了侧面轮廓和底面加工的电极损耗和补偿的数学模型，为电极自动在线补偿提供了理论基础。     

基于可视化编程的轴类零件形位误差的数据处理

在万能工具显微镜上用光学分度头对典型轴类零件的形位误差如圆度误差、同轴度误差等进行测量时,采用最小二乘法对测量数据进行处理,所得结果具有较好的数值稳定性和较高的求解精度。     

太赫兹自由电子激光放大器研究

太赫兹自由电子激光(FEL)是获得高功率太赫兹辐射的重要途径,目前运行的太赫兹FEL装置基本上都采用振荡器结构,若采用FEL放大器模式,则可产生具有更高峰值功率的太赫兹辐射。本文以北京大学超导电子直线加速器的束流参数为基础,通过模拟分析确定了太赫兹FEL放大器对太赫兹种子源、电子束流及波荡器等的要求。模拟结果显示,太赫兹种子的峰值功率在10 W以上即可实现太赫兹FEL放大;在较易实现的参数条件下,可获得峰值功率数兆瓦的太赫兹辐射。