Fluorene-centered perylene monoimides as potential non-fullerene acceptor in organic solar cells

A fluorene-centered perylene monoimide dimer, PMI-F-PMI with a partly non-coplanar configuration has been developed as a potential non-fullerene acceptor for organic solar cells (OSCs). The optimum power conversion efficiency (PCE) of the OSC based on PMI-F-PMI as acceptor and poly (3-hexyl thiophene) (P3HT) as donor is up to 2.30% after annealing at 150 °C. The PCE of 2.30% is the highest value for the OSCs based on P3HT donor and non-fullerene acceptor lies in that PMI-F-PMI’s lowest unoccupied molecular orbital (LUMO) level around −3.50 eV matches well with the donor P3HT to produce higher open-circuit voltage (V_oc) of 0.98 V. Meanwhile, PMI-F-PMI makes remarkable contribution to devices’ light absorption as the maximum EQE (30%) of the devices is at 512 nm, same to the maximum absorption wavelength of PMI-F-PMI. The other favorable characteristics of PMI-F-PMI in bulk heterojunction (BHJ) active layers is proved through the photo current density measures, the relatively balanced electron–hole transport, and the smooth morphology with root mean square (RMS) value of 1.86 nm. For these advantages, PMI-F-PMI overwhelms its sister PMI-F and parent PMI as an acceptor in BHJ solar cells.     

Annealing and doping-dependent magnetoresistance in single layer poly(3-hexyl-thiophene) organic semiconductor device

We compare the current density–voltage (J–V) and magnetoconductance (MC) response of a poly(3-hexyl-thiophene) (P3HT) device (Au/P3HT(350 nm)/Al) before and after annealing above the glass transition temperature of 150 °C under vacuum. There is a decrease of more than 3 orders of magnitude in current density due to an increase of the charge injection barriers after de-doping through annealing. An increase, approaching 1 order of magnitude, in the negative MC response after annealing can be explained by a shift in the Fermi level due to de-doping, according to the bipolaron mechanism. We successfully tune the charge injection barrier through re-doping by photo-oxidation. This leads to the charge injection and transport transitioning from unipolar to ambipolar, as the bias increases, and we model the MC response using a combination of bipolaron and triplet-polaron interaction mechanisms.     

GPRS手机入网测试自动化

全球移动通信系统(GSM)广泛的应用于现代通信系统就在于其良好的兼容性,不同的移动设备之间在遵守一定协议规范的条件下可以相互通信;本设计测试的是GSM第11系列GSM11.10,他包括诸多测试项,只对接收机参考灵敏度电平在GSM900与DCS1800两个频段进行测量。给出了传统形式下的手动测试和自动测试平台的比较,并建立了收信机参考灵敏度指标的自动测试平台。     

AUTOCAM简介及其初步使用的心得

一般来说,新闻直播中镜头是固定的,不需要太多的操作。如今,使用可远程遥控的摄像设备已成为一个热点。本文主要以东方卫视为例,从选型、使用及日常维护等方面,对对AUTOCAM的进行简单介绍。     

10MW高温气冷实验堆(HTR-10)燃耗测量系统控制方案的改进

基于10MW高温气冷实验堆(HTR-10)的FCA系统及CFC系统的设计原理及运行规程,在不改变FCA系统原有设备部件的前提下,对FCA系统运行逻辑关系进行了优化,改进了原燃耗测量程序,实现了燃耗测量过程的自动运行及测量结果的自动建库.在此基础上,设计了CFC系统与FCA系统PLC的通信协议,实现了燃耗测量流程与控制系统的实时数据通信.上述改进的结果使得燃料装卸流程不再需要另设运行班组,提高了效率,将人为操作的步骤最少化,降低了误操作的可能性.     

200kA预焙槽节能降耗的几点尝试

通过对200kA预焙槽节能方面做的几点尝试，探索出了200kA预焙电解槽在节约能源方面的措施，并取得了较好的节能效果。     

轴端沟槽底部激光强化工艺参数优化研究

分析了选用不同激光能量密度对HT300进行表面强化处理时，材料表面呈现的四种状况；未相变硬化、相变硬化、表面微熔与表面熔凝的金相组织。根据工艺要求，选取相变硬化方法对轴端沟槽底表面进行处理。分析了工件激光处理方法并通过试验研究，寻找轴端沟槽底部激光强化工艺参数；激光功率（P）、光斑直径（D）及扫描速度（V）的优化组合。硬度测试及耐磨性能试验表明：激光相变处理和激光熔凝处理后轴端沟槽底部表面较表面感应淬火硬度分别提高7%和34%，绝对磨损体积分别下降了13%和25%。实践证实，对轴端沟槽底部激光相变硬化处理方法较其他表面处理方法工艺简单，加工工件符合技术要求，试验结果对零件表面处理提供了可靠依据。     

荆门热电厂4号炉高温再热器超温控制

分析了荆门热电厂4号炉高温再热器超温的原因，提出了减缓超温程度的措施，并取得了较好的成效。     

西门子PLC与计算机间的通讯程序设计

介绍了西门子（Siemens）公司生产的S7－200型PLC与计算机之间的通讯网络构成及主要通讯指令，说明了利用PLC进行通信的实质和设计步骤，给出了PLC与计算机通讯时上位机和下位机的相应程序。     

单相负载三相供电功率分配之PLC改造实践

介绍了单相负载一工频感应炉供电的S7-200CPU224改造实践方案.依托原有设备条件,三相功率分配同样设计采用电容、电抗进行调节,起、停及三相电流平衡控制由晶闸管 接触器形式替代原单纯采用接触器控制,有效值测量使用有别于FFT的检测算法.运行实践表明:节能降耗明显,设备故障率大幅降低,具有良好的推广应用价值.