From modification to mechanism: Supercritical hydrothermal synthesis of nano-zirconia

Nano-zirconia has been widely applied due to its excellent physical and chemical properties (e.g., high strength, corrosion resistance, oxygen ion conductivity). Existing preparation methods of nano-zirconia tend to require long reaction time, and the sizes of final particles are large with uneven distributions. Sub-/supercritical hydrothermal synthesis of nanoparticles is favored by researchers owing to controllable reaction process, uniform particle size distribution, good reproducibility, short reaction time, high conversion rate and harmlessness to environment. In this paper, the characteristics and mechanisms of dissolution, crystallization and growth of nano-zirconia during sub-/supercritical hydrothermal synthesis are systematically reviewed. The influences of process and material parameters on the size and purity of particles are analyzed. Then, the reaction mechanism and product phase transition mechanism during hydrothermal synthesis of zirconia are summarized to provide a theoretical reference for the oriented preparation. Finally, the improvement and commercialization of sub-/supercritical hydrothermal synthesis technology are evaluated, and the future research topics are proposed.     

影响荔枝酒发酵过程中挥发酸的因素

挥发酸的控制是荔枝酒的生产过程中的重要技术瓶颈,发酵过程易造成荔枝果酒挥     

PIXE study on recovery of making-technology of Chinese Longquan celadon made in the Southern Song Dynasty (1127–1279 CE)

Proton induced X-ray emission (PIXE) technique and factor analysis were used to study the recovery of making-technology of Chinese Longquan celadon made in the late Southern Song Dynasty (1127–1279 CE). Based on factor analysis, for the raw material for body and the recipe for glaze, there is a close but slightly different relationship between these Longquan celadons unearthed from the core area of Dayao and the non-core area, despite all the Longquan celadons belong to the high-calcium-glaze system. The chemical compositions of most of the tentative body and glaze samples are very close to those of Longquan celadons unearthed from the core area of Dayao and the non-core area. This study can provide a guidance for recovery of making-technology of Longquan celandon.     

环境中污染源废气检测方法及影响因素分析

对污染源废气监测原理进行了简单分析,阐述了当前我国常用的环境中污染源废气检测方法,并对废气检测影响因素及质量控制进行了深入探究。     

LDPE薄膜雾度和透光率测试的影响因素

本文研究了制样方法、试样划伤、表面污染以及试样厚度等因素对LDPE薄膜透光率和浊度的影响。     

秦山核电厂燃耗深度对DNBR限值的影响分析

本文研究了在秦山核电厂批平均卸料燃耗深度超过原定限值的情况下，为保证电厂的安全运行对DNBR限值进行重新确认的问题。研究过程中，综合考虑了由燃耗加深所引起的核焓升因子的变化和棒弯曲这两种效应对DNBR限值的影响。结果表明，对秦山核电厂而言，在批平均卸料燃耗超过原定限值的情况下，维持原DNBR限值不变仍是安全可行的。     

关于变压器二次额定电压的计算

推导了变压器二次负载电压的计算公式,建议由此公式代替以往原理书中惯用的近似公式。利用此公式绘制和分析了不同功率因数额定负载时的相量轨迹图。     

27例乙型血友病患者Ⅸ因子基因突变研究

采用ＰＣＲ（聚合酶链反应）及ＧＡＷＴＳ（ＧｅｎｏｍｉｃＡｍｐｌｉｆｉｃａｔｉｏｎｗｉｔｈＴｒａｎｓｃｒｉｐｔｓＳｅｑｕｅｎｃｉｎｇ）技术，研究了江苏、湖北、山东、广东、福建、宁夏六省区２７例乙型血友病患者及其家系成员ＦⅨ（九因子）基因各２．２Ｋｂ　ＤＮＡ序列。在２ｌ例中发现２０种不同类型的突变。其中１２种是未曾报道的新突变。３８％的突变发生在ＣｐＧ二核苷致序列上，进一步证实了ＣｐＧ确系突变热点。同时检出６例女性为致病基因携带者。对开展基因产前诊断及优生优育等，具有重要意义。     

大面积1.54μm波长测距用InGaAs雪崩光电二极管

设计并研制成功适合人的眼睛安全测距应用的ＩｎＧａＡｓ雪崩光电二极管（ＡＰＤ）。器件直径为２００μｍ，工作在２１℃，１５４０ｎｍ波长时响应为０．６４Ａ／Ｗ，典型暗电流和噪声因子分别为３０ｎＡ和６．５。介绍了该器件的工作原理，设计和制作工艺。     

柴油添加剂功效影响因素的灰色关联分析

提出了一种柴油添加剂非台架实验的功效判断方法——灰色关联分析法。应用这个方法分析待测功效的柴油添加剂，可通过测定加入它后的柴油样品的物理性质和加入已知功效较好的柴油添加剂的柴油样品的物理性质，再作灰色关联分析，综合关联顺序以评定其功效好坏。应用这个方法还可推断柴油样品的表面张力是影响燃烧好坏的主要因素，其次是粘度、十六烷值和燃点。