An apparatus and a method for determining the slip resistance of shoes and floors by simulation of human foot motions

An apparatus to measure the coefficient of kinetic friction (μ_k) between the shoe sole and the underfoot surface was constructed, and a method including criteria to evaluate the risk of slipping during walking was developed. The apparatus is a prototype stationary step simulator capable of simulating the movements of a human foot and the forces applied to the underfoot surface during an actual slip, and the drainage capability of the contact surface between the shoe sole and the flooring when different lubricants or contaminants are used.

The apparatus consists of a movable artificial foot controlled by a computer with the aid of three hydraulic cylinders. The frictional force (F_μ), the normal force (F_N) and their ratio (μ_k = F_μ/F_N) are measured with a two-way force platform when the foot slides along its surface. Two separate gait patterns, heel-slide (μ_k1) and sole-slide (μ_k2) gait pattern, are used for the evaluations. The method classifies studied shoe, lubricant and underfoot surface combinations into five slip resistance classes according to the measured μ_k1 The slip resistance assessments are specified with some complementary safety criteria, e.g., the ratio μ_k1/ μ_k2 The reliability of the developed measurement method was assessed in an international comparison test. According to available results discussed in this paper, our method seems to be valid and the slip resistance measurements seem to be repeatable.     

Lewis Base Additives Improve the Zeolite Ferrierite‐Catalyzed Synthesis of Isostearic Acids

Isostearic acids (IA) are highly utilized for industrial purposes especially in the area of biolubricants, such as cosmetics and slip additives for polyolefin and related copolymer films. This study was designed to develop a zeolitic catalysis process for efficient IA production through isomerization of fatty acids. The process utilized zeolite protonated Ferrierite with a small amount of base additive to neutralize (i.e., poison) the acidic sites on the external surfaces of the zeolite particles to prevent side reactions. Of the six base additives examined, the proton sponge combined with the zeolite protonated Ferrierite was found to be the most effective for this isomerization. With only 0.5 wt% proton sponge additive to 5.0 wt% Ferrierite, the dimers were successfully suppressed from 20.6 wt% yield to 2.42 wt% with an IA yield of 83.4 wt% and a 98 % conversion.     

Surface Films and Soluble Degradation Products Formed in a PFPAE Fluid and Their Implications to the Wear of Steel

The soluble degradation products were generated in a linear perfluoropolyalkylether (PFPAE) fluid in boundary lubrication. Perfluoropolyalkylether carboxylic acid species were found in the residual fluids from the sliding tests by vibration spectroscopy. Surface-bound organic and inorganic reaction products were identified by vibration microspectroscopy with a grazing angle objective attachment and X-ray photoelectron spectroscopy (XPS), respectively. Inorganic surface films were found to be composed primarily of FeF₃. A monodentate perfluorocarboxylate surface species was found on the sliding surfaces in 50° and 100°C tests but not found in 150°C tests. The higher friction and wear in 150°C tests as compared to 50° and 100°C tests were attributed to the absence of the perfluorocarboxylate species over the sliding surfaces at high temperatures.     

环境友好润滑剂的特点及发展

阐述了绿色友好润滑剂的生物降解性和摩擦化学特点，提出了环境友好润滑剂在发展过程中存在的主要问题，并对未来的发展趋势进行了预测。     

Tribological behavior of vegetable oil-based lubricants with nanoparticles of oxides in boundary lubrication conditions

This work studied the development of vegetable based lubricants and the addition of oxides nanoparticles (ZnO and CuO) as additive for extreme pressure (EP), exploring the EP and oil base influence in tribological behavior. The results showed that with the addition of nanoparticles to conventional lubricant, the tribological properties can be significantly improved. A smoother and more compact tribofilm has formed on the worn surface, which is responsible for the further reduced friction and wear. Also, lubricants developed from modified vegetable oil can replace mineral oil, improving the tribological and environmental characteristics. However, the addition of nanoparticles in vegetable base lubricants is not beneficial to wear reduction.     

A Study of the Properties of Compacts from Silicified Microcrystalline Celluloses

ABSTRACT

The paper deals with a study of tensile strength and disintegration time of compacts made from silicified microcrystalline celluloses, Prosolv SMCC 90, and Prosolv HD 90, in dependence on compression force, addition of two types of lubricants, and two active ingredients. The lubricants were magnesium stearate and sodium stearyl fumarate in a concentration of 0.5%, the active ingredients being ascorbic acid and acetylsalicylic acid in a concentration of 50%.

Prosolv SMCC 90 proved to be better compatible than Prosolv HD 90; the compacts were of higher strength, which was markedly increased with increasing compression force. Prosolv HD 90 was more sensitive to additions of lubricants, and a greater decrease in strength was recorded due to the influence of sodium stearyl fumarate. The effect of lubricants on the strength of compacts in the presence of active ingredients was not identical. The disintegration time of compacts from Prosolv HD 90 without as well as with lubricants was shorter than from Prosolv SMCC 90 and was increasing with increasing compression force. Disintegration time was increased with added lubricants, and it was markedly shortened by addition of active ingredients. Compacts containing ascorbic acid possessed a shorter disintegration time than those containing acetylsalicylic acid, and it was not markedly influenced by the presence of lubricants.     

Relationship of Endurance to Microstructure of IBAD MoS2 Coatings

The endurance of ion-beam-assist-deposited (IBAD) MoS₂ is correlated with coating structure and orientation. Structure and orientation are determined by X-ray diffraction, while endurance is measured with a ball-on-disk tribometer operating in dry air. The IBAD MoS₂ coatings contain both crystalline and non-crystalline components. Only two orientations of the crystalline component are observed: the (001) planes parallel (basal orientation) and perpendicular (edge orientation) to the surface. Endurance of the coating is not related to coating thickness or substrate chemistry, but is related to the relative amount of the two MoS₂ crystal orientations. Coating endurance decreases with increasing edge (100) intensity. Furthermore, MoS₂ coatings with poor crystallinity exhibit good endurance. These results are discussed in terms of a possible oxidative wear mechanism and stress-induced basal re-orientation of the non-crystalline IBAD MoS₂.     

Surface Roughness Effects in Journal Bearings with Non-Newtonian Lubricants

The static performance of finite journal bearings lubricated with non-Newtonian power law fluids is analyzed by using a control volume method with an Elrod algorithm to solve the average Reynolds equation and determine the cavitation region accurately. The results show that the flow behavior index of power law fluids has an insignificant affect on the load ratios, side flow ratios and cavitation regions, while it significantly affects load capacities and side flow rates. Furthermore, the effects of film thickness ratios, pressure flow factors, shear flow factors, slenderness ratios, eccentricities and inlet pressures on the variations of cavitation regions are also discussed.     

A Rough Shear-Thinning Correction for EHD Film Thickness

A film thickness correction for shear-thinning in elastohydrodynamic contacts has been available that requires parameters obtained from flow curves generated for the specific liquid. For instances for which reduced accuracy is acceptable, a new rough film thickness correction has been formulated for pure rolling and a moderate amount of sliding based on Van Krevelen's graphical technique of estimating shear-thinning from the molecular weight. It has been shown to be useful for high-molecular-weight base oils, when lubricant specific shear-thinning data is absent, although it should most often overestimate the film thinning.