Monomer casting nylon-6-b-polyether amine copolymers: Synthesis and properties

MC nylon-6-b-polyether amine copolymers were prepared with macro-initiator based on amino-terminated polyether amine functionalized with isocyanate via in-situ polymerization. It was found that the introduction of polyether amine delayed the polymerization process of caprolactam by increasing apparent activation energy and pre-exponential factor, resulting in the decrease of molecular weight of nylon-6. The motion of molecular chain of the copolymers was easy because of the decreased hydrogen bonds and weakened inter-molecular forces. The physical entanglement of molecular chains of the copolymers was significant and strong which increased the entanglement density. Only the nylon-6 phase crystallized in the copolymers and the crystal grain size, spherulite size and crystallinity of the copolymers decreased. A small amount of γ crystal formed at high polyether amine content. The copolymers presented obvious strain hardening behavior in stress-strain curves and the loss factor dramatically increased while the glass transition temperature and storage module decreased. The fracture surface of the copolymers became rough and presented hairy structure, indicating that the toughening mechanism of the copolymers corresponded to the multi-layer crack extension mechanism.     

焊膏工艺性要求及性能检测方法

焊膏是SMT工艺中不可缺少的钎焊材料,广泛应用于再流焊中;它是由一定的合金粉末和助焊剂均匀混合而成的膏状体。主要对SMT中焊膏的组成及焊膏性能检测方法进行了简要分析。     

基于Lab VIEW的小型汽油机磁电机点火提前角的测量

本文介绍了磁电机点火系统的点火提前角测量原理。对点火系统的点火信号和触发信号进行采集、调理，再用单片机进行处理，最后用LabVIEW进行点火提前角数据存储和显示。     

糖厂现用连续离心机的研究及生产实践

在各糖厂现用连续离心机原有生产实践基础上，对其机械吸震、加温、布温、机索结构、物料密封、机座等部件做了进一步改进，并取得可观的实效。     

Preparation and Properties of Sintering Additives Coated Si3N4 from Heterogeneous Nucleation Processing

The sintering additives such as Al2O3 and /or Y2O3 were coated on the surfaces of Si3N4 particles via heterogeneous nucleation processing using a buffered pH solution as the precipitation reagent .They nucleated and grew only on the surfaces of Si3N4 and did not form sol particles in solution by TEM observation .The isoelectric point(IEP) of coated Si3N4 was different from that of as-received Si3N4.The IEP of Al(OH)3-coated Si3N4 occurred at pH8.4, which is close to that of alumina .When Al(OH)3-coated Si3N4 particles were coated with Y(OH)3,the IEP of coated Si3N4 powder shifted from pH8.4 to pH9.2 ,similar to that of yttria.In addition ,the rheological data showed that Al2O3 and /or Y2O3 coated Si3N4 suspension is nearly Newtonian and that added Si3N4 suspension shows a shear rate thinning behavior.     

Rheological behaviour of concentrated yeast suspension

The effect of yeast cell volumetric concentration on the rheological properties of the suspensions was measured in a pipe-flow viscometer at 30°C: at low microbial concentrations the suspensions were Newtonian; however, non-Newtonian behaviour, which could be described by the power-law equation, was observed with suspensions at high microbial volumetric concentrations. At conditions of constant microbial morphology and growth rate, the results also indicated that a relationship could be developed between the power-law constants and the microbial volumetric concentration.     

Effect of fluoropolymer antidripping agent on the microstructure and properties of polyesters

Poly(ethylene terephthalate) (PET) is of excellent mechanical properties and melt processability and is widely used as raw material for textile fibers. However, the flame retardant properties of PET were rather poor, and both reactive and additive phosphorus- and halogen-containing compounds have been employed to enhance the reaction-to-fire properties while the meltdripping behaviour during burning hasn’t been handled properly with the flame retardants. In this work, fluoropolymer was blended with both pure PET (pPET) and reactive phosphorus-containing flame retarded copolyester (fPET), and the flame retardance and char formation and mechanical properties of the resulted pPET and fPET blends were investigated. The tensile strengths of modified pPET samples were worsen whereas those of modified fPET samples were improved at low concentrations. The initial thermal degradation in nitrogen was accelerated remarkably for the two polyesters with fluoropolymer. The oxygen indices of the all modified samples were reduced while char formation and meltdripping suppression were encouraged. The apparent melt viscosity and elasticity for the two polyesters were gained much with antidripping agent. Therefore, fluoropolymer improved char formation of the two polyesters based on the gaseous phase mechanism while the partial suppression of meltdripping behavior and the decrease of mechanical properties mainly originated from the increase of melt viscosity via fibrillation for pPET.     

飞行器火工装置的冲击隔离结构方案实验研究

飞行器由于采用了××炸药索作为级间分离及壁板减重的火工装置，当火工品引炸时，对周围的仪器支架和脱拔插头产生高达３００００ｇ的冲击加速度。为保护仪器支架和脱拔插头，本文，总结了多种隔冲击结构方案的试验结果，选出了一种最佳方案，即二级硅橡胶缓冲器与阻尼复合结构的结合形式。该方案可使冲击加速度衰减至１６０ｇ以下。测的是周向过载。４结语粘弹阻尼复合结构用于高频响、高过载的冲击衰减系统尚是一种新的尝试。由于本课题所设计的缓冲支架采用了多级隔冲方式，冲击载荷传递的环节多，而且是三维冲击响应，载荷的波形复杂，不确定因素多，无法采用理论分析的方法进行研究。虽然如此，缓冲器的隔冲特性以及粘弹阻尼复合结构的减振性能还是可以估算的。这方面的理论问题有待于进一步研究。从试验角度而言，本次试验已解决了飞行器的仪器盒及脱拔插头的隔冲击振动问题，证明所设计的隔冲击支架满足使用要求。通过对不同支承界面联接方式的研究，选出了较佳的支承结构形式，即文中的标准状态。该结构形式隔冲击性能好，衰减倍数大，安装和更换方便，防热性能好。试验数据表明，仪器架的衰减倍数大于４００倍，脱拔插头支架大于２９０倍；在最大过载约３００００ｇ，最大响应频率约２２．４     

粘合剂流变特性的研究(待续)

本文从流变学的观点出发,分析粘合剂在配制及粘结过程中,反映出不同的流变特性,而粘合剂本身的流动、粘度、触变性与涂胶及其粘合的质量关系重大。     

高含水油包水乳化液稳定性机理及实验研究

本文在对油包水乳化液的微观机构进行分析的基础上，对高含水油包水乳化液的稳定性机理进行了实验研究，初步分析了它的流变性质。本文的研究对于油包水乳化液降低成本，提高性能的发展具有重要的理论意义。