全文获取类型
收费全文 | 9934篇 |
免费 | 662篇 |
国内免费 | 269篇 |
专业分类
电工技术 | 969篇 |
综合类 | 453篇 |
化学工业 | 548篇 |
金属工艺 | 1713篇 |
机械仪表 | 792篇 |
建筑科学 | 437篇 |
矿业工程 | 541篇 |
能源动力 | 286篇 |
轻工业 | 1605篇 |
水利工程 | 95篇 |
石油天然气 | 192篇 |
武器工业 | 67篇 |
无线电 | 616篇 |
一般工业技术 | 773篇 |
冶金工业 | 1420篇 |
原子能技术 | 76篇 |
自动化技术 | 282篇 |
出版年
2024年 | 18篇 |
2023年 | 91篇 |
2022年 | 159篇 |
2021年 | 171篇 |
2020年 | 198篇 |
2019年 | 148篇 |
2018年 | 142篇 |
2017年 | 223篇 |
2016年 | 231篇 |
2015年 | 260篇 |
2014年 | 530篇 |
2013年 | 506篇 |
2012年 | 655篇 |
2011年 | 766篇 |
2010年 | 565篇 |
2009年 | 623篇 |
2008年 | 485篇 |
2007年 | 610篇 |
2006年 | 609篇 |
2005年 | 527篇 |
2004年 | 390篇 |
2003年 | 447篇 |
2002年 | 394篇 |
2001年 | 416篇 |
2000年 | 340篇 |
1999年 | 295篇 |
1998年 | 215篇 |
1997年 | 228篇 |
1996年 | 158篇 |
1995年 | 160篇 |
1994年 | 113篇 |
1993年 | 52篇 |
1992年 | 42篇 |
1991年 | 28篇 |
1990年 | 16篇 |
1989年 | 15篇 |
1988年 | 6篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1959年 | 1篇 |
1957年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Alinda Samsuri Mohd Nor Latif Mohd Razali Shamsuddin Fairous Salleh Maratun Najiha Abu Tahari Tengku Shafazila Tengku Saharuddin Norliza Dzakaria Mohd Ambar Yarmo 《International Journal of Hydrogen Energy》2021,46(48):24831-24844
Temperature programmed reduction (TPR) analysis was applied to investigate the chemical reduction progression behavior of molybdenum oxide (MoO3) catalyst. The composition and morphology of the reduced phases were characterized by X-ray diffraction spectroscopy (XRD), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (FE-SEM). The reduction progression of MoO3 catalyst was attained with different reductant types and concentration (10% H2/N2, 10% and 20% CO/N2 (%, v/v)). Two different modes of reduction process were applied. The first approach of reduction involved non-isothermal mode reduction up to 700 °C, while the second approach of reduction involved the isothermal mode reduction for 60 min at 700 °C. Hydrogen temperature programmed reduction (H2-TPR) results showed the reduction progression of three-stage reduction of MoO3 (Mo6+ → Mo5+ → Mo4+ → Mo0) with Mo5+ and Mo4+. XRD analysis confirmed the formation of Mo4O11 phase as an intermediate phase followed by MoO2 phase. After 60 min of isothermal reduction, peaks of metallic molybdenum (Mo) appeared. Whereas, FESEM analysis showed porous crater-like structure on the surface cracks of MoO2 layer which led to the growth of Mo phase. Meanwhile, the reduction of MoO3 catalyst in 10% carbon monoxide (CO) showed the formation of unstable intermediate phase of Mo9O26 at the early stage of reduction. Furthermore, by increasing 20% CO led to the carburization of MoO2 phase, resulted in the formation of Mo2C rather than the formation of metallic Mo, as confirmed by XPS analysis. Therefore, the presented study shows that hydrogen gave better reducibility due to smaller molecular size, which contributed to high diffusion rate and achieved deeper penetration into the MoO3 catalyst compared to carbon monoxide reductant. Hence, the reduction of MoO3 in carbon monoxide atmosphere promoted the formation of Mo2C which was in agreement with the thermodynamic assessment. 相似文献
2.
《International Journal of Hydrogen Energy》2020,45(3):1435-1443
The size-controlled preparation of Mo powders is always a challenge and important task in the molybdenum metallurgy. In the current study, Mo powders with controllable sizes are synthesized by hydrogen reduction of MoO2 powders with the assistance of Mo nuclei in the range of 900–1100 °C. The influences of the particle sizes of Mo nuclei, the additive amount as well as reaction temperature on the morphology and particle sizes of the final products are studied. For the hydrogen reduction of MoO2 without any additive, the obtained Mo powders always have large particle sizes. However, the addition of small amounts of nuclei in MoO2 can help Mo nucleate dispersedly, and the growth of Mo could be also controlled by adjusting the sizes of added nuclei, amount of addition and the reaction temperature. With the addition of Mo nuclei, the different sizes of Mo powders with the good dispersity can be prepared. As adding commercial Mo powders with the particle size of about 2.03 μm, the micron-sized Mo powders ranged from 2.11 μm to 3.25 μm could be prepared. While for the case of adding ultrafine Mo nuclei of about 170 nm, Mo powders from 0.28 μm to 0.88 μm can be obtained. Moreover, the more the amounts of nuclei added and the lower the reaction temperature (in the range of 900–1100 °C) is, the smaller the particle size of the prepared Mo powder will be. The current method is a facile and feasible method, and is potential to be used for industrial production of Mo powder with controllable particle sizes. 相似文献
3.
Defects are often present in rolled products, such as wire rod. The market demand for wire rod without any defects has increased. In the final wire rod products, defects originating from steel making, casting, pre‐rolling of billets and during wire rod rolling can appear. In this work, artificial V‐shaped longitudinal surface cracks have been analysed experimentally and by means of FEM. The results indicate that the experiments and FEM calculations show the same tendency except in two cases, where instability due to fairly “round” false round bars disturbed the experiment. FE studies in combination with practical experiments are necessary in order to understand the behaviour of the material flows in the groove and to explain whether the crack will open up as a V‐shape or if it will be closed as an I‐shape. 相似文献
4.
钻井钢丝绳对于钻井平台安全可靠性有直接影响。采用磁性检测方法对钻井钢丝绳进行检测,并对钻井钢丝绳的励磁方式、聚磁方法及传感器与钢丝绳的配合间隙问题进行分析。在此基础上,研制了钻井钢丝绳检测仪器,能够实现对钻井钢丝绳断丝、磨损等缺陷的定性、定量检测,并能够对缺陷进行定位,为钻井钢丝绳的寿命评估提供了依据,对提高钻井平台的安全性具有重要意义。 相似文献
5.
6.
丝网气液分离器分离性能和压力损失分析 总被引:3,自引:0,他引:3
对丝网气液分离器的分离机理进行了详细分析,在此基础上给出了丝网气液分离器的分离效率和压降计算公式。与HG/T 21618-1998《丝网除沫器》中的公式相比,此公式可以用于任意组合的丝网结构,更具普适性,并且能定量分析各种分离机理对分离的贡献。对丝网式空气过滤器计算的结果表明,此公式具有很好的精度,可以用于工程设计。 相似文献
7.
This article presents a method that can be applied to molten AA-6101 alloy to improve electrical properties of the aluminium part of the optical ground wire (OPGW) used in overhead transmission lines to protect phase conductors from lightning strike and to transmit signals and data. AA-6101 alloy in casting of the log as 6 m length and 178 mm diameter for extrusion has been inoculated by AlB2 to decrease detrimental effects of Cr, Ti, V, and Zr on the conductivity of the material. After inoculation, improved billets were extruded as 9.5 mm diameter feedstock. Required wires drawn from the feedstock according to the construction types of OPGW to be tested were exposed to aging at 175°C, 6 h (T-8). Upon completion of the back-twist and performing-type stranding process, resistance, and short-circuit current capacity and breaking load of the OPGW 88/44 constructions with other metal combinations have been examined and tested to show improvement. Results are summarized in tables and graphically. 相似文献
8.
9.
10.
在介绍“铝丝印”概念的基础上,从金属腐蚀学的观点出发,分析了“铝丝印”形成的电化学腐蚀机理,并提出了具体的解决措施。 相似文献