A novel Ag–CuAlO2 sealant for reactive air brazing of 3YSZ and AISI 310S

Based on reactive air brazing (RAB), we designed a new type of sealant (Ag–xCuAlO₂) for joining 3 mol.% yttria-stabilized zirconia (YSZ) ceramics and AISI 310S stainless steel. The CuAlO₂ content affected the wettability of the sealant on the YSZ surface, and the joints had a high shear strength when Ag–2 wt.%CuAlO₂, which had a small contact angle on the YSZ substrate, was used as the sealant. In addition, the thickness of the oxide layer was reduced compared to that for the Ag–CuO sealant. The effects of the processing parameters on the microstructure and shear strength of the joints were investigated, and the as-brazed joints reached their highest shear strength (93.7 MPa) when brazed at 1040 °C for 30 min. After high-temperature oxidation at 800 °C for 200 h, the shear strength of the joints remained at 50 MPa, and no apparent change in the microstructure was observed, proving that the joints possessed excellent oxidation resistance.     

40000m~3/h空分设备主换热器的设计及制造

通过对进口 4 0 0 0 0m3 /h空分设备主换热器进行结构分析及对比模拟计算 ,用国产传热翅片进行设计、采用真空钎焊工艺制造的主换热器 ,经并网运行 ,设计指标优于原空分设备 ,为今后成套大型空分设备板翅式换热器国产化设计、制造创造了条件。     

高温钎料PdCu-Ti在氧化铝陶瓷上的润湿性及界面反应

本文采用座滴法试验研究了合金系统ＰｄＣｕ－Ｔｉ在Ａｌ２Ｏ３上润湿性的变化规律，探讨了界面冶金及结合等行为，运用热力学理论对结果进行了分析，随Ｔｉ含量的增加及Ｐｄ含量的减少润湿角逐渐降低，Ｔｉ的加入使界面发生了一个双重变化；液相侧富氧，钛吸收层的生成及随后的固相侧氧化钛的生成，只有界面上生成一氧化钛，才能有较好的润湿行为和较强的结合力。     

LD2铝合金的钎焊工艺

对LD2的铝合金零件进行了钎焊工艺分析，采取合理的措施及相关对策，成功地进行了钎焊，并达到了相应的技术要求。     

电子束钎焊温度模糊控制系统

将被焊工件温度模糊控制技术应用于电子束扫描钎焊中,所研发的系统集成了电子束焊接过程控制、电子束扫描轨迹控制、工件温度模糊控制、焊接数据高速采集与存储等多项功能.通过扫描轨迹的编辑与控制,可以适应各种形状曲线钎焊缝的温度场要求;在电子束对工件进行扫描加热的同时,通过温度采集装置实时得到被焊工件的温度信号并与设定值进行对比从而得到温度偏差及偏差的变化率作为模糊控制器的两个输入变量,以模糊控制器输出控制量调节电子束流大小,从而实现钎焊温度的闭环控制.控制系统具有响应速度快、稳定时间短、稳态误差小、超调量小等特点,表明在电子束钎焊过程中采用模糊控制技术可以得到非常理想的控制效果.     

Joining of metal bars by a new process of transformation-diffusion brazing

Within the bonded interface of metal bars joint produced by conventional solid state bonding process （ such as flash welding, resistance butt welding, friction welding and so on）, the inclusions are often present, which degrade the ductility of joint. A new process of transformation-diffusion brazing is proposed, in which an amorphous foil containing melting point depressant is preplaced between the interfaces to be joined, and the assembly is repeatedly heated/cooled without holding time at peak temperature. A low carbon steel bars, BNi-2 amorphous foil and resistance butt welding machine were used. The results show that surfuce contamination can be disrupted by the dissolution of base metal into molten interlayer in comparison with conventional process, and the ductility of joint can be improved by increasing the times of temperature cycles on line. In addition, transformation-diffusion brazing can be done with relatively simple and inexpensive system in comparison with transient liquid phase bonding.     

热处理工艺对截齿钎焊接头强度的影响

为获得采煤机用截齿钎焊接头的优良性能，作者研究了钎焊后热处理工艺参数对钎缝抗剪强度的影响。试验表明，高温区停留时间在保证钎焊时钎料充分熔化的前提下越短越好；冷却速度对接头的强度有较大影响，一般情况下，钎焊后由880℃冷却到200℃的时间应控制在5～20min之间；回火温度在350～450℃之间抗剪强度有低谷区。截齿钎焊采用HL105钎料，配以合适的钎剂能获得较理想的接头性能。     

陶瓷/金属钎焊与扩散连接的研究现状

工程陶瓷由于具有优异的综合性能,在许多领域得到广泛应用,但其加工性能差,通常需要与金属组成复合结构.实现陶瓷与金属之间的可靠连接是推进陶瓷材料应用的关键,钎焊和扩散连接被认为是陶瓷/金属连接中较为适合的方法.文中对近年来国内外陶瓷/金属钎焊和扩散连接技术领域的研究现状进行了综述,认为活性金属钎焊和部分瞬间液相连接发展比较成熟,部分瞬间液相连接充分结合了活性钎焊和固相扩散连接两者的优点,将成为未来陶瓷/金属连接的发展方向.     

LY12铝合金中温钎焊技术

采用改进的KF—CsF—A1F3中温无腐蚀钎剂与Ag—A1—Cu—Zn中温钎料实现了对LYl2铝合金的中温钎焊，钎焊接头的抗剪强度可达到母材强度的80％，对接接头钎缝的抗拉强度可达到母材强度的70％，突破了”热处理强化铝合金通常不能钎焊”的传统论断。     

高频焊管用464-H14铝复合带材力学性能的研究

结合工业生产研究了高频焊管用464－H14铝合金复合带材的退火工艺和加工工艺对材料力学性能的影响。结果表明：成品材料冷轧前的软化退火温度应选择在既能使材料完全软化而又不发生Si原子扩散的350－400℃之间，冷加工率应控制在20％－40％，这样可使材料获得较好的力学性能，能够满足产品的技术标准和使用要求。