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排序方式: 共有3703条查询结果,搜索用时 15 毫秒
1.
Diphenylzinc, alone or in combination with water and butanone as coinitiators, was used as a polymerization initiator system for a variety of lactones at varying temperatures. The resulting data indicate that the course of the polymerization is greatly influenced by the lactone structure, as well as by the molar ratio of coinitiator to diphenylzinc. When used alone, diphenylzinc exhibited high activity as an initiator in δ‐valerolactone polymerizations, although it was less efficient when used in the β‐butyrolactone and the β‐propiolactone polymerizations. Activity in the polymerization of β‐lactones was increased by adding small amounts of butanone or water. It was also observed that the diphenylzinc–butanone combination was more effective than the diphenylzinc–water mixture in the polymerizations of β‐butyrolactone and β‐propiolactone. Copyright © 2003 Society of Chemical Industry 相似文献
2.
Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)3) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)3 exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 104 g mol?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)3 has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)3 is 69.6 kJ mol?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry 相似文献
3.
火焰图像特征在火灾数字图像识别中的运用 总被引:1,自引:0,他引:1
火焰尖角数目和圆形度是早期火灾火焰的主要特征,本文主要论述了如何在数学形态学基础上,利用火灾火焰的两个特点判断和识别早期火情。实验中,对火焰的二值图像进行开运算,即先腐蚀,再膨胀,目的是为了对火焰图像进行形态学滤波,去噪。从实验结果可以看出,该算法可以很好的识别火焰和干扰源。 相似文献
4.
苯并口恶嗪-环氧化合物-胺类催化剂体系开环聚合反应的研究 总被引:9,自引:0,他引:9
采用TLC,GPC,1H-NMR及IR等分析方法,对苯并恶嗪-环氧化合物-胺类催化剂体系的聚合反应进行了研究,表征了产物结构,并探讨了聚合反应机理,结果表明,苯并恶唪-环氧化合物体系在胺类催化剂如苄胺,咪唑的作用下,能发生开环聚合反应,生成低分子量的聚合物。 相似文献
5.
The main purpose of this paper is to find the mixed-mode stress intensity factors of composite materials using the crack opening displacement (COD). First, a series solution of the composite material with a crack was used to evaluate COD values. Then, the least-squares method was used to calculate mixed-mode stress intensity factors. This algorithm can be applied to any method that generates or measures COD values. The major advantage of this method is that COD values very near the crack tip are not necessary. Both finite element simulations and laboratory experiments were applied to validate this least-squares method with acceptable accuracy if the even terms of the series solution are removed. 相似文献
6.
7.
G.P. Potirniche 《Engineering Fracture Mechanics》2003,70(13):1623-1643
Crack tip plastic zone sizes and crack tip opening displacements (CTOD) for stationary microstructurally small cracks are calculated using the finite element method. To simulate the plastic deformation occurring at the crack tip, a two-dimensional small strain constitutive relationship from single crystal plasticity theory is implemented in the finite element code ANSYS as a user-defined plasticity subroutine. Small cracks are modeled in both single grains and multiple grains, and different crystallographic conditions are considered. The computed plastic zone sizes and CTOD are compared with those found using conventional isotropic plasticity theory, and significant differences are observed. 相似文献
8.
9.
An investigation of crack closure and the propagation of semi-elliptical fatigue cracks in Q1N (HY80) pressure vessel steel 总被引:1,自引:0,他引:1
The results of an experimental investigation of the effect of crack closure on the propagation of semi-elliptical fatigue cracks are presented. Load-shedding fatigue threshold tests were carried out at stress ratios of 0.2, 0.35, 0.5 and 0.7. Crack closure was measured at the surface and depth positions using backface strain gauges, near-tip gauges, and a clip gauge. Differences between the surface and depth growth behaviour are explained by considerations of the effects of the transition from plane stress conditions at the surface to plane strain conditions at the depth. The effects of stress ratios are attributed largely to differences in the crack opening displacement, which result in asperities coming into contact to induce roughness-induced crack closure. 相似文献
10.
空调系统中风阀开度对声学房间噪声的影响 总被引:1,自引:1,他引:0
李传胜 《制冷空调与电力机械》2004,25(3):48-50
阐述了在一个全空气空调系统服务于多间较小面积声学房间的情况下,风阀开度对声学房间噪声的影响,并用工程实例加以说明,认为风阀开度对录音室和直播室的房间噪声影响很大.此外,对单独控制声学房间温度的几种方法和它们的优缺点也作了阐述. 相似文献