Revealing Electrical-Poling-Induced Polarization Potential in Hybrid Perovskite Photodetectors

Despite recent rapid advances in metal halide perovskites for use in optoelectronics, the fundamental understanding of the electrical-poling-induced ion migration, accounting for many unusual attributes and thus performance in perovskite-based devices, remain comparatively elusive. Herein, the electrical-poling-promoted polarization potential is reported for rendering hybrid organic–inorganic perovskite photodetectors with high photocurrent and fast response time, displaying a tenfold enhancement in the photocurrent and a twofold decrease in the response time after an external electric field poling. First, a robust meniscus-assisted solution-printing strategy is employed to facilitate the oriented perovskite crystals over a large area. Subsequently, the electrical poling invokes the ion migration within perovskite crystals, thus inducing a polarization potential, as substantiated by the surface potential change assessed by Kelvin probe force microscopy. Such electrical-poling-induced polarization potential is responsible for the markedly enhanced photocurrent and largely shortened response time. This work presents new insights into the electrical-poling-triggered ion migration and, in turn, polarization potential as well as into the implication of the latter for optoelectronic devices with greater performance. As such, the utilization of ion-migration-produced polarization potential may represent an important endeavor toward a wide range of high-performance perovskite-based photodetectors, solar cells, transistors, scintillators, etc.     

Behaviour of Surface Defects in Wire Rod Rolling

Defects are often present in rolled products, such as wire rod. The market demand for wire rod without any defects has increased. In the final wire rod products, defects originating from steel making, casting, pre‐rolling of billets and during wire rod rolling can appear. In this work, artificial V‐shaped longitudinal surface cracks have been analysed experimentally and by means of FEM. The results indicate that the experiments and FEM calculations show the same tendency except in two cases, where instability due to fairly “round” false round bars disturbed the experiment. FE studies in combination with practical experiments are necessary in order to understand the behaviour of the material flows in the groove and to explain whether the crack will open up as a V‐shape or if it will be closed as an I‐shape.     

Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopic studies on the ferroelectric behavior of poly(vinylidene fluoride–trifluoroethylene) ultrathin films

Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopy was used to characterize the ferroelectric behavior of a thin poly(vinylidene fluoride–trifluoroethylene) P(VDF–TrFE) copolymer. The lab-built GIRA-FTIR apparatus allowed the heating and corona poling process to be carried out whilst collecting the GIRA spectra of the thin polymer film. The Curie transition from the ferroelectric to paraelectric phase was confirmed from the abrupt change in intensity of the 849 cm⁻¹ band in the RA-FTIR spectrum. It was found that the Curie temperature dropped dramatically when the film thickness was lowered to below a certain critical value of approximately 100 nm. The switching of the CF₂ dipoles in the ferroelectric crystals after applying the external electric field could be determined by monitoring the change in the 849 cm⁻¹ band intensity. For the 600 nm thick P(VDF–TrFE) film, the switching of the dipoles appears to occur almost instantaneously, while the kinetics of dipole switching of the 75 nm thick film were significantly retarded. The repeated switchability of the CF₂ dipoles upon the application of a bipolar cyclic electric field was also confirmed. The bistability of the film due to remnant polarization was also confirmed from the absorbance of the 849 cm⁻¹ band after removing the applied voltage during corona poling.     

制备单根大重量喷涂钼丝的生产研究

全面系统地介绍了“大坯料轧制开坯-大加工率变形-长线拉伸”制造喷涂钼丝的工艺。重点阐述了Y370、Y250型三辊连轧机实现一火轧制开坯和长线拉伸增加在线碱洗工序对提高喷涂钼丝内部组织结构和外部表面质量的影响。分析了工艺中出现的问题，提出了相应的解决办法。     

浅谈托辊的开发与实践

本钢１７００连轧机应用的托辊原由外企业制作，为了减少公司资金外流，公司技术人员和工人结合现有的生产条件，先后攻克了辊身铸造和加工，托辊装配等工艺方面的难关，研制成功了合格的产品，年创经济效益８０万元。     

Centrifugal Casting of High Speed Steel/Nodular Cast Iron Compound Roll Collar

Ｈｉｇｈ ｓｐｅｅｄｓｔｅｅｌ (ＨＳＳ) ,ｉｓｃｈａｒａｃｔｅｒｉｚｅｄｂｙｅｘ ｃｅｌｌｅｎｔｈａｒｄｎｅｓｓ ,ｗｅａｒｒｅｓｉｓｔａｎｃｅ ,ａｎｄ ｇｏｏｄｒｅｄｈａｒｄｎｅｓｓ .Ｒｅｃｅｎｔｌｙ ,ＨＳＳｉｓａｐｐｌｉｅｄｔｏｍａｎｕｆａｃｔｕｒｅｈｏｔｒｏｌｌｉｎｇｒｏｌｌｓｔｏｐｒｏｄｕｃｅｓｔｒｉｐｓｏｆｇｏｏｄｓｈａｐｅａｎｄｓｍａｌｌｃｒｏｗｎｗｉｔｈｅｘｔｅｎｄｅｄｒｏｌｌｓｅｒｖｉｃｅｌｉｆｅ[1,2 ] .ＴｈｅＨＳＳｉｓａｐｐｌｉｅｄｔｏｍａｎｕｆａｃｔｕｒｅｒｏｌｌｃｏｌｌａｒｆｏｒ…     

热轧高强钢平整机辊径参数设计技术研究

基于高强钢平整机的生产工艺特点,结合板形与辊耗问题,将带材的出口前张力与辊间压力横向分布都均匀作为目标函数,把保证所有被平整高强钢产品的机械性能满足产品大纲要求作为约束条件,提出了一套针对热轧高强钢平整机的工作辊与支承辊辊径参数设计模型.其研究结果对指导宝钢分公司1880 mm热轧平整机的工艺参数的确定与技术谈判发挥了重要作用,并具有进一步的推广价值.     

磨料高压水除鳞系统设计研究

磨料高压水除鳞系统取代酸洗线，原机械部分和磨料高压水部分都作了较大改进，才能保证除鳞彻底。     

在线磨辊辊面粗糙度的实验研究

影响轧辊表面粗糙度的因素很多，为此对影响辊面粗糙度的因素进行了系统分析和实验研究，得出了轧辊和砂轮的速度、砂轮粒度、砂轮直径及磨削液等主要因素对轧辊表面粗糙度影响的一般规律。利用回归分析的方法建立了轧辊表面粗糙度的数学模型，并将计算值与实测值进行了比较，发现两者基本一致。此项研究为适时控制冷轧带钢在线磨辊辊面粗糙度提供了计算模型。     

酚醛树脂复合板在热连轧机中的应用

重点分析了现有F7机架出口导卫装置的情况。原导卫材料是由铸钢制造 ,由于摩擦和高温常常引起热连轧带钢表面划伤 ,根据现场实际情况用酚醛树脂复合板替代铸钢导卫装置。实践表明 ,这种改造即可行又可靠 ,并取得了好的效果