自由曲面五坐标数控加工干涉检查

提出了一种新方法，用于环刀五坐标数控加工的干涉检查。该方法将干涉检查分为刀轴及侧刃干涉检查和端面干涉检查。首先将加工曲面分片，选取合适的初始点。然后利用自由曲面的微分特性，确定跟踪方向和步长，迅速计算出工件和刀具的最短距离，从而判断是否发生干涉。实验仿真表明，达到同样精度时，该算法计算效率远高于常规的三角面片法。     

二维多孔数控钻床加工路径的生成及优化

印刷电路板 PCB的加工是二维多孔数控钻的典型。实践表明加工同一零件不同的走刀路径其长度相差极大。为提高生产率 ,应使刀具的走刀路径尽量短 ,这其实是大型的 TSP问题。本文提出了几种路径的生成方法 ,分析了各自的适用场合。并用实例验证所提出的路径生成方法可极大地提高实际钻孔的加工效率。     

网络化制造中基于STEP-NC的编程方法

STEP-NC是由欧美提出的新的数控接口标准，目的是取代旧的数控标准ISO6983。本文首先分析了STEP-NC的两种应用标准：ISO14649（ARM）和STEPAP238（AIM），并且分析了Part21和Part28的应用领域及Part21文件格式和其中的信息产生方法。然後介绍了ST-Developer环境下ROSEC＋＋颠库编程接口及其应用程序的早、晚编联方式，并且以此为基础设计了整个程序的编程流程，重点介绍了工艺规划设计。最后给出了在C＋＋编程环境下利用ROSE库函数写入形成STEP AP238文件的方法。     

数控加工的基本坐标系和对刀问题

数控加工中的对刀问题影响机械加工的各个方面。这里从介绍数控机床的基本坐标系出发，重点阐述了对刀的基本原理和方法以及常见数控机床对刀问题的处理。     

Instability of zeolite Y supported cobalt sulfide hydrotreating catalysts in the absence of H2S

Ion exchanged CoNaY was sulfided at 473 and 673 K and subsequently heated in He at 673 and 773 K. The resulting samples were characterized by means of overall sulfur analysis, temperature programmed Ar treatment and Fourier transform infrared spectroscopy. It was shown that during He flushing at sufficiently high temperature a protolysis reaction occurs resulting in the decomposition of Co sulfide into Co²⁺ ions and H₂S.     

多功能滚齿机的数字控制系统

本文叙述了以ＳＴＤＰＣ／ＸＴ（或ＰＣ／ＡＴ）机为主要核心构成的滚齿机数字控制系统的结构，软件设计和特点，系统采用混合语言编程，极大地提高了软件设计的灵活性与快速性，也分析了ＣＮＣ系统的加工过程，提出了加工中的软件预处理控制方法，并给出了轴伺服控制的并行算法分析与实现。     

应用并行技术实现CAD／CAM的高度集成

传统的CAD/CAM系统由于设计思想本身的局限性,其内部只能达到一种松散的基于数据交换的低水平的集成,产品的设计方法也不符合工程技术人员的设计思路。本文提出了基于全耦合的单一数据模型的并行CAD/CAM系统设计思想,使得CAD/CAM系统内部达到以数据共享为基础的高度集成。并行CAD/CAM系统充分体现了工程技术人员的思维方式及产品设计过程的反复性和协调性。此外,文中还提出广义参数化设计的新概念,它与特征设计方法的有机结合保证了产品模型的完整性和产品设计过程的同步性。特征共享是实现CAD和CAM集成的关键因素。并行CAD/CAM系统应用面向对象软件设计思想,实现了复杂数据模型的内部封装,并为数据模型和功能模块之间提供简单直观的界面。面向对象设计方法是开发并行CAD/CAM系统的有效手段。     

Understanding chemical reactions between carbons and NaOH and KOH: An insight into the chemical activation mechanism

Direct mixing of an anthracite with hydroxides (KOH or NaOH) and heat treatment up to 730 °C has shown to be a very good activation procedure to obtain activated carbons with very high surface areas and high micropore volumes. The reactions involved during the heat treatment of these hydroxide/anthracite mixtures have been analysed to deep into the fundamental of the knowledge of this chemical activation process, that has not been studied before. For this purpose, the present paper analyses the drying process, the atmosphere during the carbonisation, the chemical state of the activating agents (NaOH, KOH and Na₂CO₃) and the chemical reactions occurring during the heat treatment which have been followed by FTIR and TPD. The analysis of our results allows us to conclude that steam is a good atmosphere for the carbonisation process, alone or joined with nitrogen, but not as good as pure nitrogen. On the other hand, during the activation process, the presence of CO₂ should be avoided because it does not develop porosity. The reactions, and chemical changes, involved during this chemical process are discussed both from a thermodynamical point of view as well as identifying the reaction products (H₂ by TPD and Na₂CO₃ by FTIR). As a result, this paper helps to cover the present lack of understanding of the fundamentals of the reactions of an anthracite with hydroxides which are necessary to understand the activation of the material.     

Characterization of supported Pd-Pt catalysts by chemical probes

The temperature programmed (palladium) hydride decomposition appeared very effective method for diagnosing the extent of alloying in Pd-Pt/SiO₂ catalysts. Introduction of Pt to Pd catalysts moves the TPHD peak gradually towards lower temperatures and the shift in hydride decomposition peak is accompanied by a decrease in the amount of released hydrogen. The catalysts prepared the direct redox method showed much better alloy homogeneity than the samples prepared by coimpregnation. The results of probing with other techniques, i.e. catalytic probing with hydrodechlorination of CCl₂F₂ and XRD, were in line with TPHD data. The catalytic probing showed the presence of synergistic effect, a clear indication of Pd-Pt mixing. XRD data of post-reaction samples showed carbon incorporation into Pd-rich phase, whereas separate Pt-rich phase did not experience any bulk carbiding.     

用热分析法研究硝化棉的熔化过程

用ＭＤＳＣ，显微镜温台熔点测定仪和固体原位反应池／快速扫描傅立叶变换红外光谱联用装置考察了硝化棉的熔化过程。ＭＤＳＣ曲线表明吸热过程是可逆的，它系由ＮＣ和部分分解凝聚相产物的混合物的固液相变所引起。由ＮＣ的ＭＤＳＣ曲线得到的熔点，熔化含，熔化熵，分解含和分解反应热温熵分别为４７６．８４Ｋ，２０５．６Ｊ．ｇ＾－１，０．４３１２Ｊ．ｇ＾－１．Ｋ＾－１，－２４７５．０Ｊ．ｇ＾－１，－５．２４２Ｊ．ｇ＾－