Dependence of mechanical and tribological performance on the microstructure of (CrAlTiNbV)Nx high-entropy nitride coatings in aviation lubricant

The (CrAlTiNbV)N_x coatings are fabricated by controlling the substrate bias via magnetron sputtering method. Under low substrate bias, the coating tends to form a loose columnar crystal structure with (200) preferred orientation. However, when the substrate bias increases, the coating transforms into a dense nanocrystalline structure, and the (111) orientation is enhanced. As the substrate bias increases, the residual stress and hardness of the coating gradually increase, while the adhesion strength decreases slightly. Friction tests show that the coating possesses the lowest average friction coefficient (about 0.06) and wear rate (8.7 × 10^-9 mm³/N·m) in 4050# aviation lubricant, which is achieved under the substrate bias of -96 V and -126 V, respectively.     

新型着色材料——速溶色浆粉的测试与应用

介绍了通过初级颜料的润湿、研磨与分散、稳定处理技术,使助剂和树脂均匀地包裹在颜料表面,并通过特殊工艺制得水性和油性色浆粉,并赋予了很好的速溶性和分散性。     

The effect of a solid additive on rolling fatigue life

Behaviour of a series of lubricant oils and the effect of a non stoichiometric inorganic compound, as solid extreme pressure additive, on rolling fatigue life are studied using the rolling four-ball accelerated service simulation test proposed by Barwell and Scott. The results show, in all tested cases, the remarkable efficacy of this type of additive. The Total Acidity Number (tan) was found to increase with performance time for the case of the base lubricant, while for the oils with additives, it remained at its constant low value. This led to a proposal of a possible mechanism of the additive performance in the rolling process.     

未增塑聚氯乙烯(PVC-U)异型材配方基础

PVC-U异型材配方十分复杂,常用原料通常在10种以上。根据大连实德集团实际生产情况,这10多种原料通常以7大组分的方式进行配料和生产。文中就该配方中7大组分的分类、特点及应用情况分别进行了详细介绍。     

Complementary effects of solid lubricants in the automotive brake lining

An experimental investigation was carried out to examine the tribological behavior of NAO (non-asbestos organic) type brake linings containing different volume ratios of graphite and antimony trisulfide (Sb₂S₃). A scale dynamometer was used for friction tests and particular emphases were given to the effect of applied pressure, sliding speed, and temperature on the coefficient of friction according to the relative amounts of the two solid lubricants. Results showed that the brake linings with both solid lubricants exhibited better friction stability and less speed sensitivity than the friction materials containing a single solid lubricant. In particular, the brake lining containing higher concentrations of graphite showed better fade resistance than others during high-temperature friction test.     

石油一厂东蒸馏装置的技术改造

介绍抚顺石油化工公司石油一厂东蒸馏装置的改造情况，通过技术改造，使减压蒸馏塔由生产燃料型改造成生产石蜡－润滑油型，满足了该厂对石蜡和润滑油料的质量要求。     

2-巯基苯并噻唑衍生物摩擦学性能的研究

合成了S—(1—(2—苯并噻唑基巯基)—2—羟基)—丙基N，N—二烷基二硫代氨基甲酸酯和S—(1—(2—苯并噻唑基巯基)—2—乙酰基)—丙基N，N—二烷基二硫代氨基甲酸酯两种化合物。运用IR、MS、HNMR和元素分析等分析方法对其结构进行表征。用四球试验、HQ—l环块试验分别考察了其对润滑油的极压承载能力及抗磨减摩性能的影响。结果表明：在350SN中性油中添加所合成的化合物后可以显著降低四球长磨后磨斑直径、有效地降低摩擦副之间的摩擦系数，拥有优良的摩擦学性能。     

润滑油基础油的现状及发展趋势

叙述了内燃机油的发展对基础油的要求，并对传统工艺和加氢工艺生产的基础油质量状况进行了分析，指出润滑油加氢工艺是提高基础油质量的有效途径。加氢工艺生产基础油是润滑油的发展趋势。     

砂岩气藏水基欠平衡钻井逆流自吸效应实验研究

采用水基钻井液欠平衡钻开砂岩气层时，欠平衡压差往往并不能完全抵消岩石的自吸毛细管力，从而产生逆流自吸效应。这种自吸效应可能对砂岩气藏水基欠平衡钻井的储层保护效果产生影响，但目前与之有关的实验研究还很缺乏。为此，设计了一套实验装置，模拟水基欠平衡条件，研究了砂岩基块孔隙逆流自吸规律及其影响因素。结果表明，水基欠平衡钻井过程的逆流自吸效应引起岩石气相渗透率降低，削弱欠平衡钻井的储层保护效果；欠平衡压差越小，逆流自吸作用越强，过小的欠压值不能起到欠平衡钻井保护储层的作用；随着逆流自吸时间延长、围压增加和黏土矿物膨胀，逆流自吸导致气相渗透率下降的程度加剧；逆流自吸引起的气相渗透率下降速率可以表示成时间的幂函数。     

New intramolecular effect observed for polyesters: An anomeric effect

A series of polyesters was prepared to evaluate hydrolytic stability as a function of cyclohexyl dibasic acid content. The three cyclohexyl dibasic acids: 1,2; 1,3; and 1,4 were formulated into polyesters with two glycols. The proportion of cis and trans isomers was evaluated via ¹H NMR. The hydrolytic stability of short chain polyesters was evaluated in an acetone/water mixture which solubilized the polyesters to mimic oligoester behavior within a thermosetting polyester coating environment. The rate of hydrolysis was monitored by acid titration and corroborated by GPC. Surprisingly, 1,2-cylohexyl diacid-based polyesters were robust, and 1,3-cyclohexyl diacid-based polyesters were the most susceptible to hydrolysis. Evidently, a 1,2-anchimeric effect for cyclohexyl dibasic acid polyesters was not an important consideration, while the 1,3-cyclohexyl ester interaction was. Consequently, an anomeric effect was proposed. Presented at the 81st Annual Meeting of the Federation of Societies for Coatings Technology, November 12–14, 2003, in Philadelphia, PA.