全文获取类型
收费全文 | 1163篇 |
免费 | 82篇 |
国内免费 | 35篇 |
专业分类
电工技术 | 8篇 |
综合类 | 39篇 |
化学工业 | 241篇 |
金属工艺 | 21篇 |
机械仪表 | 59篇 |
建筑科学 | 263篇 |
矿业工程 | 88篇 |
能源动力 | 29篇 |
轻工业 | 203篇 |
水利工程 | 17篇 |
石油天然气 | 11篇 |
无线电 | 25篇 |
一般工业技术 | 95篇 |
冶金工业 | 126篇 |
原子能技术 | 38篇 |
自动化技术 | 17篇 |
出版年
2024年 | 1篇 |
2023年 | 11篇 |
2022年 | 18篇 |
2021年 | 21篇 |
2020年 | 27篇 |
2019年 | 27篇 |
2018年 | 31篇 |
2017年 | 30篇 |
2016年 | 37篇 |
2015年 | 27篇 |
2014年 | 52篇 |
2013年 | 68篇 |
2012年 | 73篇 |
2011年 | 114篇 |
2010年 | 95篇 |
2009年 | 110篇 |
2008年 | 80篇 |
2007年 | 75篇 |
2006年 | 44篇 |
2005年 | 46篇 |
2004年 | 47篇 |
2003年 | 39篇 |
2002年 | 33篇 |
2001年 | 22篇 |
2000年 | 18篇 |
1999年 | 27篇 |
1998年 | 18篇 |
1997年 | 12篇 |
1996年 | 10篇 |
1995年 | 8篇 |
1994年 | 1篇 |
1993年 | 9篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 1篇 |
1985年 | 7篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1981年 | 2篇 |
1977年 | 1篇 |
排序方式: 共有1280条查询结果,搜索用时 109 毫秒
1.
Marthe Jordbrekk Blikra Sigrun Henjum Inger Aakre 《Comprehensive Reviews in Food Science and Food Safety》2022,21(2):1517-1536
Brown algae are becoming increasingly popular as a food source and dietary supplement in Europe and other Western countries. As they are highly rich in iodine, they represent a potential new dietary iodine source. Iodine deficiency has been re-emerging in Europe, and it is important to ensure adequate intake through one's diet. However, macroalgae, and especially brown algae, may contain very high amounts of iodine, and both iodine deficiency and excessive iodine may increase the risk of negative health effects. The iodine content of algae or foods containing algae is currently not regulated in the European Union. The aim of this paper is to review the literature to determine the chemical species of iodine in brown algae, the loss of iodine during processing, and the bioavailability and bioaccessibility of iodine. A systematic search of the literature was performed in April 2021, via the databases Web of Science and PubMed. The review includes studies of iodine in brown macroalgae in relation to bioavailability, bioaccessibility, processing and speciation. A meta-analysis was conducted in relation to the following topics: (i) the correlation between total iodine and iodide (I–) content in brown algae; (ii) the correlation between the loss of iodine during processing and the I– content; and (iii) the correlation between bioavailability and the I– content. The bioavailability of iodine from brown algae was generally high, with in vivo bioavailability ranging from 31% to 90%. The in vitro bioavailability of iodine (2%–28%) was systematically lower than in vivo bioavailability (31%–90%), indicating an inadequate in vitro methodology. Processing may reduce the iodine content of brown algae, and a higher I– content was positively correlated with increased iodine loss during processing. Although processing strategies may reduce the iodine content of brown algae significantly, the iodine content may still be high after processing. These findings may be used in food safety evaluations of brown algae as well as in the development of macroalgae-containing foods with iodine contents suitable for human consumption. Further research on processing techniques to reduce the iodine content in brown macroalgae are warranted. 相似文献
2.
Yu-Jiao Liu Xiao-Yang Fan Dr. Dong-Dong Zhang Yin-Zheng Xia Dr. Yan-Jun Hu Feng-Lei Jiang Prof. Fu-Ling Zhou Prof. Yi Liu 《ChemMedChem》2020,15(6):552-558
Based on the potential therapeutic value in targeting mitochondria and the fluorophore tracing ability, a fluorescent mitochondria-targeted organic arsenical PDT-PAO-F16 was fabricated, which not only visualized the cellular distribution, but also exerted anti-cancer activity in vitro and in vivo via targeting pyruvate dehydrogenase complex (PDHC) and respiratory chain complexes in mitochondria. In details, PDT-PAO-F16 mainly accumulated into mitochondria within hours and suppressed the activity of PDHC resulting in the inhibition of ATP synthesis and thermogenesis disorder. Moreover, the suppression of respiratory chain complex I and IV accelerated the mitochondrial dysfunction leading to caspase family-dependent apoptosis. In vivo, the acute promyelocytic leukemia was greatly alleviated in the PDT-PAO-F16 treated group in APL mice model. Our results demonstrated the organic arsenical precursor with fluorescence imaging and target-anticancer efficacy is a promising anticancer drug. 相似文献
3.
Study on Adsorption Behavior of Rare Earth Complexes on Nanometer-Size Titanium Dioxide with ICP-AES
Inrecentyears ,rareearthelements (REEs)havebeenwidelyusedinfunctionalmaterials ,cata lystsandotherproductsinindustry ,diagnosisreagentsofmagneticresonanceimaging (MRI)inmedicineandsomefertilizersinagricultureespeciallyinChina .However,asaresultoftheirusage ,moreandmoreREEsaregettingintotheenvironment,andalsointohumanbodyviafoodchain[1,2 ] .Itisnotclearwhetherrareearthelementsareessentialforman ,soitisveryurgenttostudythebiologicaleffectofrareearthelementsinhumanhealthandenvironment .Inthes… 相似文献
4.
Modeling mercury speciation is an important requirement for estimating harmful emissions from coal-fired power plants and developing strategies to reduce them. First-principle models based on chemical, kinetic, and thermodynamic aspects exist, but these are complex and difficult to develop. The use of modern data-based machine learning techniques has been recently introduced, including neural networks. Here we propose an alternative approach using abductive networks based on the group method of data handling (GMDH) algorithm, with the advantages of simplified and more automated model synthesis, automatic selection of significant inputs, and more transparent input–output model relationships. Models were developed for predicting three types of mercury speciation (elemental, oxidized, and particulate) using a small dataset containing six inputs parameters on the composition of the coal used and boiler operating conditions. Prediction performance compares favourably with neural network models developed using the same dataset, with correlation coefficients as high as 0.97 for training data. Network committees (ensembles) are proposed as a means of improving prediction accuracy, and suggestions are made for future work to further improve performance. 相似文献
5.
Speciation of the semivolatile hydrocarbon engine emissions from sunflower biodiesel 总被引:1,自引:0,他引:1
Biodiesel fuel is a very attractive alternative to conventional fuel and its effects in the engine performance and regulated emissions have been widely studied. However, the impact on unregulated individual compounds or chemical characteristics of exhaust emissions is not fully characterized. In this paper, the semivolatile fractions of the exhaust emissions of biodiesel blends and conventional fuel have been speciated. The results show great differences between the compounds emitted, especially regarding oxygenated and aromatic species. Likewise, there is a clear relationship between speciated hydrocarbons and other important emissions such as total hydrocarbons (HC), particulate matter (PM), volatile organic fraction (VOF) and mean particle diameter (Dm) of PM. 相似文献
6.
工矿企业产生的铬渣、含铬废水由于管理不善导致土壤铬污染严重,迫切需要寻求低成本铬污染土壤修复技术。提出腐解稻草中溶解性有机质(Dissolved Organic Matter, DOM)提取液洗脱铬污染土壤的技术,通过实验室模拟试验,以2种铬污染土壤(总铬含量为分别为121.54、941.90 mg/kg,六价铬含量分别为119.90、856.90 mg/kg)为研究目标,采用振荡淋洗法考察了固液比、淋洗时间、淋洗次数等因素对土壤中总铬、六价铬洗脱效果的影响,并探讨了淋洗前后铬形态变化及淋洗后土壤残留六价铬的持续钝化能力。研究结果表明:稻草经35 d腐解后的DOM提取液洗脱土壤中铬效果最佳,确定为最佳淋洗剂;固液比1:15、淋洗4h/次、淋洗2次为最佳淋洗工艺条件,该条件下,2种铬污染土壤总铬分别洗脱了47.79%、85.92%,六价铬含量分别削减了51.76%、95.09%;DOM提取液呈弱碱性,包含大量羧基、羟基及酚类物质,对水溶态、弱酸提取态和残渣态铬有较好的洗脱效果,有效降低了土壤环境风险,且能持续钝化淋洗后土壤中残余的六价铬。 相似文献
7.
This work is an experimental and theoretical study of antimony speciation and the solubility of Sb2O5, Sb2O3 and Sb2(SO4)3 at 298 K in aqueous sulphuric acid solutions (0 to 6 kmol/m3). A thermodynamic model was developed to quantify the solubility products and aqueous metal speciation. Main dissolved species were H3SbO3(aq) and H3SbO4(aq). The solubility of antimony increases with increasing solution acidity and with the presence of hydrogen peroxide in the solution. The following standard equilibrium constants at 298 K were obtained: Log K0(Sb2O5) = 11.7±0.5, Log K0(Sb2O3) = 32±1, and Log K0(Sb2(SO4)3) = 55±2. 相似文献
8.
Effect of operating conditions in removal of arsenic from water by nanofiltration membrane 总被引:2,自引:0,他引:2
The removal of arsenic from synthetic waters and surface water by nanofiltration (NF) membrane was investigated. In synthetic solutions, arsenic rejection experiments included variation of arsenic retentate concentration, transmembrane pressure, crossflow velocity and temperature. Arsenic rejection increased with arsenic retentate concentration. Arsenic was removed 93-99% from synthetic feed waters containing between 100 and 382 μg/L as V, resulting in permeate arsenic concentrations of about 5 μg/L. Under studied conditions, arsenic rejection was independent of transmembrane pressure, crossflow velocity and temperature. In surface water, the mean rejection of As V was 95% while the rejection of sulfate was 97%. The co-occurrence of dissolved inorganics does not significantly influence arsenic rejection. The mean concentration of As in collected permeated was 8 μg/L. The mean rejection of TDS, total hardness and conductivity were 75, 88 and 75% respectively. 相似文献
9.
10.
This paper is a critical review and summary of the analytical procedures currently used by operating water utilities to control ozone treatment processes, considering disinfection as well as the many oxidative applications of ozone in water treatment applications. The role of common interferences in the various methods is described.
In operating U S., Canadian, European, and Japanese water treatment plants currently employing ozone as a primary disinfectant, ozone nearly always is followed by the addition of small quantities of chlorine, chlorine dioxide, or chloramine to provide the residual in the distribution system and to act as a secondary disinfectant. Clearly, the analytical procedures used must distinguish between the various species. This review critically presents these various factors and their implication with respect to “true values” of ozone determined under widely varying conditions. 相似文献