Magnetic properties and magnetoresistance effect of SnFe2O4 spinel nanoparticles: Experimental,ab initio and Monte Carlo simulation

In this contribution, SnFe₂O₄ nanoparticles were prepared by the solvothermal method, the structural properties were performed using X-Ray Diffraction (DRX) to prove the success of tin ferrite formation and to determine de crystals parameters. The size and morphological study were build using Scanning Electron Microscopy (SEM) and Transmission Electron microscopy (TEM), the results showed that the size of particles is uniform with a range of particles (5–7 nm). The magnetic properties were carried out using the SQUID device, the SnFe2O4 nanoparticles have a magnetic transition at 750 K. In addition, the hysteresis loops at low temperature displayed Ms and Mr equals to 23 emu/g and 6 emu/g, respectively. The magnetoresistance properties were investigated, the SnFe₂O₄ nanoparticles present a large magnetoresistance effect (80%). The experimental results are supplemented by model calculations utilizing density functional theory and Monte-Carlo simulations.     

Influence of Al3+ doping for V5+ on the structural,optical, thermal and electrical properties of V2-xAlxO5-δ (x=0–0.20) ceramics

This paper reports an investigation on the structure-properties correlation of trivalent metal oxide (Al₂O₃)-doped V₂O₅ ceramics synthesized by the melt-quench technique. XRD patterns confirmed a single orthorhombic V₂O₅ phase formation with increasing strain on the doping of Al₂O₃ in place of V₂O₅ in the samples estimated by Williamson-Hall analysis. FTIR and Raman investigations revealed a structural change as [VO₅] polyhedra converts into [VO₄] polyhedra on the doping of Al₂O₃ into V₂O₅. The optical band gap was found in a wide semiconductor range as confirmed by UV–visible spectroscopy analysis. The thermal and conductivity behavior of the prepared samples were studied using thermal gravimetric analysis (TGA) and impedance analyzer, respectively. All the prepared ceramics exhibit good DC conductivity (0.22–0.36 Sm^-1) at 400 ?C. These materials can be considered for intermediate temperature solid oxide fuel cell (IT-SOFC)/battery applications due to their good conductivity and good thermal stability.     

A grounded theory examination of project managers' accountability

26 interviews were conducted with a snowball sample of project managers to explore how project managers were influenced by accountability arrangements and how they responded to accountability demands. Using a grounded theory approach to code the interview data, this study revealed that project managers develop new skills to respond to accountability demands. These effects are facilitated by the interaction of resource-based mechanisms and reflexivity that interact with the contextual factors of the project. The study broadens the understanding of accountability in project management and suggests a model for further empirical examination.     

Effect of microstructure on the fatigue crack growth behaviour of a near-α Ti alloy

Fatigue crack growth behaviour of Ti–6Al–2Zr–1.5Mo–1.5V (VT-20 a near-α Ti alloy) was studied in lamellar, bimodal and acicular microstructural conditions. Fatigue crack growth tests at both increasing and decreasing stress intensity factor range values were performed at ambient temperature and a loading ratio of 0.3 using compact tension samples. Lamellar and acicular microstructures showed lower fatigue crack growth rates as compared to the bimodal microstructure due to the tortuous nature of cracks in the former and the cleavage of primary α in the latter. The threshold stress intensity factor range was highest for acicular microstructure.     

石油沥青60℃动力粘度测定影响因素的探讨

粘度是表征沥青稠度的一个重要指标。通过论述石油沥青粘度测定法(真空毛细管法)中毛细管的选择、温度、真空度、取样量等对试验结果的影响及试验过程中的其它注意事项,表明了在测定石油沥青的60℃动力粘度时,必须严格按照试验方法的要求进行测定,以保证试验结果的准确性。     

夯扩挤密水泥土桩用于高层建筑地基处理的尝试

水泥土桩已普遍用于多层住宅的地基处理，根据水泥土和夯扩挤密施工法的特点，在对夯扩挤密水泥土桩用于高层建筑地基处理进行研究、阐明其经济合理且安全可行的基础上，在高层住宅工程中进行了尝试，已取得令人满意的效果。     

A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron

A simple mathematical model was proposed to analyze the enhancement of Cr(VI) reduction when sand materials are added to the zero valent iron (ZVI). Natural decay of Cr(VI) in a control experiment was analyzed by using a zero-order decay reaction. Adsorption kinetics of Cr(VI) to sand was modeled as a first-order reversible process, and the reduction rate by ZVI was treated as a first-order reaction. Natural decay of Cr(VI) was also included in other experiments, i.e., the adsorption to sand, the reduction by ZVI, and both adsorption and reduction when sand and ZVI are present together. The model parameters were estimated by fitting the solution of each model to the corresponding experimental data. To observe the effect of sand addition to ZVI, both adsorption and reduction rate models were considered simultaneously including the natural decay. The solution of the combined model was fitted to the experimental data to determine the first-order adsorption and reduction rate constants when sand as well as ZVI is present. The first-order reduction rate constant in the presence of sand was about 35 times higher than that with ZVI only.     

对一起氮压机燃爆事故的原因分析

SVK8 3S型氮气压缩机是由沈阳鼓风机厂制造、为义马煤气配套的低压氮气压缩机 ,共两套 ,于 2 0 0 0年 1 2月开始调试。为节约工程基建资金 ,取消原设计两台中压氮气压缩机 ,由杭氧产两台3TYS89+2TYS60型氧气透平压缩机临时压送氮气 ,向外供中压氮 ,来取代中压氮气压缩机 ,流程示意图如图 1所示。图 1　氧、氮压机工艺流程配置图1　事故情况2 0 0 0年 1 2月 2 7日中午 1 1∶3 5 ,接总调度室通知 ,要求中午 1 2∶0 0向长输管线供中压氮气。当时 ,一台氮压机试车完毕正在运行 ,一台氧压机试车完毕压氧正在运行 ,将由氧压机临时压送氮气外供…     

异质谷间转移电子器件的计算机模拟

使用弛豫时间近似求出了描述两能谷间电子交换的方程。在此基础上建立了双能谷电子的连续性方程和油松方程。对具体的ＧａＡｓ／ＡｌｘＧａ１－ｘＡｓ异质谷间转移电子器件结构求解了这些方程组，得到了直流工作时器件内的电场分布、双能谷中载流子的布居以及两个能谷的电流分布。这些结果正好和常规Ｇｕｎｎ器件相反，说明了两种器件的不同工作机理。最后通过对低Ａｌ组份势垒结构的计算说明了Ｘ谷电子注入对器件工作的重要作用。     

消费品说明中警示信息有效性的工效学研究(Ⅰ)——警示信息对消费者危险感受与商品危险性之间关系的影响

该研究采用问卷法，通过对３０种消费品的调查，分析了消费者对消费品说明中警示信息的阅读倾向性，消费者的危险感受、消费者安全使用商品的自信度、遵守警示信息的可能性、主观危险估计和客观危险性这几项因素之间的关系。结果表明：消费者的危险感受与阅读警示信息的倾向性、遵守警告的要求之间存在高度的一致性；且与自信度呈负相关，所以可以通过研究消费者的危险感受来研究警示信息的有效性；消费者的危险感受、主观危险估计常与商品的客观危险性不一致，所以必须采取一些措施来矫正消费者的危险感受，以确保警示信息发挥应有的安全保障作用